Article
  • Preparation of Flexible and Transparent Electrode Embedded Silver Grid into Acrylic Polymer Substrate
  • Baek SS, Yoon DG, Hwang GS, Jang SH, Chin BD, Hwang SH
  • 투명 아크릴 기판에 실버그리드(Silver Grid)를 함몰시킨 유연 투명전극 제조
  • 백승석, 윤대건, 황경석, 장수희, 진병두, 황석호
Abstract
Using the UV-curable acrylate formulations consisting of methyl methacrylate, 2-hydroxyethyl acrylate and poly(ethylene glycol) diacrylate), flexible and transparent electrode embedded silver grid into the polymer substrate was fabricated through ink-jetting technique and transfer process. The profile morphologies and surface characteristics of silver grid in the polymer substrate were estimated by interferometer. Furthermore, the optical properties as well as electrical- resistance changes during bending test of the electrode were also measured. As one of utilitarian applications for the electrode, the optimized organic solar cell was constructed on the electrode by using poly(3-hexylthiophene):[6,6]- phenyl-C61-butyric acid methyl ester (P3HT:PCBM) system and then power conversion efficiency of the device was 2.53%.

본 연구에서 광경화성 아크릴 단량체 조성물(methyl methacrylate, 2-hydroxyethyl acrylate, poly(ethylene glycol) diacrylate)을 이용한 고분자 기판 내부에 실버그리드(silver grid)를 잉크젯공정(ink-jet)과 전사공정(transfer process)으로 함몰시킨 유연 투명전극 기판을 제조하였다. 인터페로미터를 사용하여 광경화된 고분자 기판 내부에 실 버그리드의 함몰된 형태 및 표면을 확인하였으며, 그것의 광학적 특성과 밴딩테스트 후 전기적 특성으로 제조된 유연 투명전극 기판의 물성을 고찰하였다. 유연 투명전극 기판으로서의 유용성을 확인하기 위해 poly(3-hexylthiophene): P3HT:[6,6]-phenyl-C61-butyric acid methyl ester(P3HT:PCBM)으로 유기 태양전지 소자를 제작하여 2.52%의 효율 특성을 얻었다.

Keywords: flexible electrode; transparent; silver grid; ink-jet; acrylate; UV-curing

References
  • 1. Tahar RBH, Ban T, Ohya Y, Takahashi Y, J. Appl. Phys., 83, 2631 (1998)
  •  
  • 2. Ohta H, Orita M, Hirano M, Tanji H, Kawazoe H, Hosono H, Appl. Phys. Lett., 76, 2740 (2000)
  •  
  • 3. Wassei JK, Kaner RB, Mater. Today, 13, 52 (2010)
  •  
  • 4. Liu J, Wu D, Zeng S, J. Mater. Process. Technol., 209, 3943 (2009)
  •  
  • 5. Galagan Y, Rubingh JEJM, Andriessen R, Fan CC, Blom PWM, Veenstra SC, Kroon JM, Sol. Energy Mater. Sol. Cells, 95(5), 1339 (2011)
  •  
  • 6. Lee MY, Kim JS, Seo JH, Thin Solid Films, 521(-), 60 (2012)
  •  
  • 7. Kim YH, Sachse C, Machala ML, May C, Muller-Meskamp L, Leo K, Adv. Funct. Mater., 21(6), 1076 (2011)
  •  
  • 8. Tvingstedt K, Inganas O, Adv. Mater., 19(19), 2893 (2007)
  •  
  • 9. Emmott CJM, Urbina A, Nelson J, Sol. Energy Mater. Sol. Cells, 97(-), 14 (2012)
  •  
  • 10. Wu J, Becerril HA, Bao Z, Liu Z, Chen Y, Peumans P, Appl. Phys. Lett., 92, 263302 (2008)
  •  
  • 11. Salvatierra RV, Cava CE, Roman LS, Zarbin AJG, Adv. Funct. Mater., 23(12), 1490 (2013)
  •  
  • 12. Leem DS, Edwards A, Faist M, Nelson J, Bradley DD, de Mello JC, Adv. Mater., 23, 4317 (2011)
  •  
  • 13. Angmo D, Krebs FC, J. Appl. Polym. Sci., 129(1), 1 (2013)
  •  
  • 14. Yu JS, Jung GH, Jo J, Kim JS, Kim JW, Kwak SW, Lee JL, Kim I, Kim D, Sol. Energy Mater. Sol. Cells, 109(-), 142 (2013)
  •  
  • 15. Burgues-Ceballos I, Kehagias N, Sotomayor-Torres CM, Campoy-Quiles M, Lacharmoise PD, Sol. Energy Mater. Sol. Cells, 127(-), 50 (2014)
  •  
  • 16. Layani M , Kamyshny A, Magdassi S, Nanoscale, 6, 5581 (2014)
  •  
  • 17. Kim BC, Jeong HT, Raj CJ, Kim YR, Cho BB, Yu KH, Synth. Met., 207, 116 (2015)
  •  
  • 18. Nakatani K, Suzuki K, Okaniwa H, Sol. Energy Mater. Sol. Cells, 17, 265 (1988)
  •  
  • 19. De S, Higgins TM, Lyons PE, Doherty EM, Nirmalraj PN, Blau WJ, Boland JJ, Coleman JN, ACS Nano, 3, 1767 (2009)
  •  
  • 20. Mehnert R, Pincus A, Janorsky I, Stowe R, Berejka A, UV & EB Curing Technology & Equipment, John Wiley & Sons, NY, p 1 (1998).
  •  
  • 21. Baek SS, Jang SJ, Lee JH, Kho DH, Lee SH, Hwang SH, Polym. Korea, 38(2), 199 (2014)
  •  
  • 22. Nakazawa M, J. Adhes. Soc. Jpn., 36, 28 (2000)
  •  
  • 23. Baek SS, Lee SW, Hwang SH, Polym. Korea, 37(1), 121 (2013)
  •  
  • 24. Piglowski J, Kozlowski M, Rheol. Acta, 24, 519 (1985)
  •  
  • 25. Neophytou M, Hermerschmidt F, Savva A, Georgiou E, Choulis SA, Appl. Phys. Lett., 101, 193302 (2012)
  •  
  • 26. Bae SK, Kim SJ, Shin D, Ahn JH, Hong BH, Phys. Scr., 2012, 014024 (2012)
  •  
  • 27. Choi KH, Kim J, Noh YJ, Na SI, Kim HK, Sol. Energy Mater. Sol. Cells, 110(-), 147 (2013)
  •  
  • 28. Yu JS, Jung GH, Jo J, Kim JS, Kim JW, Kwak SW, Lee JL, Kim I, Kim D, Sol. Energy Mater. Sol. Cells, 109(-), 142 (2013)
  •  
  • 29. Kaduwal D, Zimmermann B, Wurfel U, Sol. Energy Mater. Sol. Cells, 120(-), 449 (2014)
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2017; 41(3): 465-470

    Published online May 25, 2017

  • 10.7317/pk.2017.41.3.465
  • Received on Oct 26, 2016
  • Accepted on Dec 30, 2016