Article
  • Effects of Hardener Type on Cure Behavior and Physical Properties of TMP Modified UF Resin and Its Composites with Bamboo Powder
  • Zhang YF, Lu MG, Liu H, Wu Y
  • 경화제 타입이 TMP 개질된 UF 수지 및 이를 대나무 파우더와 혼합한 복합재료의 경화 거동과 물리적 성질에 미치는 영향
Abstract
In this study, effects of mixed hardeners (ammonium chloride mixed with ammonium persulfate, oxalate and phosphoric acid) on the properties of 2,4,6-trimethylolphenate modified UF resin (TMPUF) were studied, and the potlife, gel time and curing temperature of TMPUF/hardeners were characterized. The results indicated that the hardeners used have critical influence on the pH value of TMPUF and some proton donor can be used to lower the pH value of TMPUF with low formaldehyde content. Besides, bamboo particleboards were made with TMPUF/hardeners, and tensile properties, water absorption ratio and the swelling ratio of bamboo particleboards were characterized. The study demonstrated that the tensile strength of bamboo particleboards increased when partial ammonium chloride was replaced by ammonium persulfate to cure the TMPUF adhesives in our experiment.

Keywords: mixed hardener; UF resin; bamboo particleboard; tensile strength

References
  • 1. Park BD, Kang EC, Park JY, J. Appl. Polym. Sci., 101(3), 1787 (2006)
  •  
  • 2. Mansouri HR, Thomas RR, Garnier S, Pizzi A, J. Appl. Polym. Sci., 106(3), 1683 (2007)
  •  
  • 3. Amirou S, Zhang J, Essawy HA, Pizzi A, Zerizer A, Li J, Delmotte L, Polym. Compos., 36, 2255 (2015)
  •  
  • 4. Li B, Zhang J, Ren X, Chang J, Gou J, Bioresources, 9, 5125 (2014)
  •  
  • 5. Cui HW, Du GB, Wood Sci. Technol., 47, 105 (2013)
  •  
  • 6. Duan H, Qiu T, Guo L, Ye J, Li X, Int. J. Adhes. Adhes., 66, 138 (2016)
  •  
  • 7. Zorba T, Papadopoulou E, Hatjiissaak A, Paraskevopoulos KM, Chrissafis K, J. Therm. Anal. Calorim., 92, 29 (2008)
  •  
  • 8. Liu Y, Tian Y, Zhao G, Sun Y, Zhu F, Cao Y, J. Polym. Res., 15, 501 (2008)
  •  
  • 9. Kordkheili HY, Najafi SK, Eshkiki RB, Pizzi A, J. Wood Wood Prod., 73, 77 (2015)
  •  
  • 10. Atar GNI, Nadir A, Mehmet BL, Bunyamin S, Selahattin B, Mater. Des., 56, 91 (2014)
  •  
  • 11. Ding R, Su CH, Yang YG, Li CF, Liu JC, Int. J. Adhes. Adhes., 41, 1 (2013)
  •  
  • 12. Moubarik A, Mansouri HR, Pizzi A, Charrier F, Allal A, Charrier B, Wood Sci. Technol., 47, 675 (2013)
  •  
  • 13. Que ZL, Furuno T, Katoh S, Nishino Y, Build. Environ., 42, 1257 (2007)
  •  
  • 14. Ferra JMM, Henriques A, Mendes AM, Costa MRN, Carvalho LH, Magalhaes FD, J. Appl. Polym. Sci., 123(3), 1764 (2012)
  •  
  • 15. Tohmura S, Inoue A, Sahari SH, J. Wood Sci., 47, 451 (2001)
  •  
  • 16. Halvarsson S, Edlund H, Norgren M, Ind. Crop. Prod., 28, 37 (2008)
  •  
  • 17. Paiva NT, Henriques A, Cruz P, Ferra JM, Carvalho LH, Magalhaes FD, J. Appl. Polym. Sci., 124(3), 2311 (2012)
  •  
  • 18. Li C, Zhang J, Yi Z, Yang H, Zhao B, Zhang W, Li J, Int. J. Adhes. Adhes., 66, 26 (2016)
  •  
  • 19. Duan HY, Qiu T, Guo LH, Ye J, Li XY, J. Hazard. Mater., 293(-), 46 (2015)
  •  
  • 20. Tomita B, Ohyama M, Hse CY, Holzforschung, 48, 522 (1994)
  •  
  • 21. He GB, Yan N, J. Appl. Polym. Sci., 95(6), 1368 (2005)
  •  
  • 22. Fan DB, Chang JM, Li JZ, Mao A, Zhang LT, J. Appl. Polym. Sci., 112(4), 2195 (2009)
  •  
  • 23. Costa N, Pereira J, Martins J, Ferra J, Cruz P, Magalhaes F, Int. J. Adhes. Adhes., 33, 56 (2012)
  •  
  • 24. Freeman JH, J. Am. Chem. Soc., 74, 6257 (1952)
  •  
  • 25. Tomita B, Hse CY, Int. J. Adhes. Adhes., 18, 69 (1998)
  •  
  • 26. Zhang YF, Zheng J, Guo HL, Li YW, Lu MG, J. Appl. Polym. Sci., 132, 42280 (2015)
  •  
  • 27. Akyuz KC, Nemli G, Baharoglu M, Zekovic E, Int. J. Adhes. Adhes., 30, 166 (2010)
  •  
  • 28. Xing C, Zhang SY, Deng J, Wang SQ, J. Appl. Polym. Sci., 103(3), 1566 (2007)
  •  
  • 29. Myers GE, J. Appl. Polym. Sci., 26, 747 (1981)
  •  
  • 30. Kandelbauer A, Despres A, Pizzi A, Taudes I, J. Appl. Polym. Sci., 106(4), 2192 (2007)
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2017; 41(2): 235-241

    Published online Mar 25, 2017

  • 10.7317/pk.2017.41.2.235
  • Received on Aug 26, 2016
  • Accepted on Oct 13, 2016