Article
  • Effects of Surface Modification of Silica Nanoparticles on the Mechanical Properties of UV-curable Silica/Polyurethane Acrylate Nanocomposite
  • Seo B, Park S, Ha KR
  • 실리카 나노입자 표면 개질이 UV 경화형 실리카/폴리우레탄 아크릴레이트 나노복합체의 기계적 성질에 미치는 영향
  • 서보경, 박성환, 하기룡
Abstract
In this study, we prepared silica nanoparticles with methacrylate groups on the silica surface using a two-step modification process. First, silica particles were silanized with (3-trimethoxysilylpropyl)diethylenetriamine(TPDT), and then a Michael addition reaction was performed between the N-H groups from the TPDT modified silica surface and the acrylate groups of 3-(acryloyloxy)-2-hydroxypropylmethacrylate(AHM). UV-curable urethane acrylate nanocomposites were subsequently prepared by incorporating (0-5 wt%) pristine silica, TPDT modified silica or TPDT/AHM modified silica as fillers. The incorporation of only 3.0 wt% of TPDT/AHM modified silica particles increased Young's modulus to 333.1MPa which represents a 30.8% improvement over UV-cured urethane acrylates and the best performance of all three fillers.

본 연구에서는 실리카 입자 표면을 (3-trimethoxysilylpropyl)diethylenetriamine(TPDT)로 처리하여 아미노기를 도입한 후, 마이클 부가 반응이 가능한 3-(acryloyloxy)-2-hydroxypropylmethacrylate(AHM)과 반응시켜 자유 라디칼 중합이 가능한 methacrylate기를 도입하였다. 순수 실리카, TPDT 혹은 TPDT/AHM으로 개질된 실리카를 충전제로 사용하여 urethane acrylate계 수지와 광중합법으로 나노복합체를 제조하였다. UV 수지 중합체와 순수 실리카, TPDT 로 개질된 실리카 및 TPDT/AHM으로 개질된 실리카를 각각 3.0 wt% 포함하는 나노복합체의 탄성률을 측정한 결과, TPDT/AHM으로 개질된 실리카 나노복합체의 탄성률이 333.1MPa으로 UV 수지 중합체보다 30.8% 증가하였음을 확인하였다.

Keywords: silica; surface modification; Michael addition reaction; UV-curing; mechanical property

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  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2016; 40(6): 907-914

    Published online Nov 25, 2016

  • 10.7317/pk.2016.40.6.907
  • Received on May 21, 2016
  • Accepted on Jun 20, 2016