Article
  • Effects of Zeolites on Thermal Stability of Poly(vinyl chloride)
  • Xu J, Liang Q, Xian X, Li K, Liu J
  • 폴리염화비닐(PVC)의 열안정성에 제올라이트가 미치는 영향
Abstract
The effects of zeolite on the thermal stability of poly(vinyl chloride) (PVC) were investigated by the static thermal stability test, pyrolysis experiment and ultraviolet spectrum. The results showed that the porous zeolite could absorb hydrogen chloride (HCl), which suppressed the catalysis of HCl on thermal degradation of PVC, thus improved the thermal stability of PVC. The oxidizing acid which was loaded on zeolite had oxidated on the double bond that formed during the dehydrochlorination of PVC. This process could prohibit the growth of the conjugated polyene and improved the color of PVC. Hence, zeolite might be possible to come up with a high performance thermal stabilizer.

Keywords: zeolite; poly(vinyl chloride); stability; oxidizing acid; double bond.

References
  • 1. Mohamed NA, Yassin AA, Khalil KD, Polym. Degrad. Stab., 70, 5 (2000)
  •  
  • 2. Yan JL, Li DQ, Evans GD, Polym. Degrad. Stab., 88, 286 (2005)
  •  
  • 3. Sombatsompop N, Taptim K, Chaochanchaikul K, Thongpin C, Rosarpitak V, J. Macromol. Sci. Part A: Pure Appl. Chem., 45, 534 (2008)
  •  
  • 4. Thongpin C, Juntum J, Sa-Nguan-Moo R, J. Thermoplast. Compos. Mater., 23, 435 (2010)
  •  
  • 5. Gupta S, Agarwal DD, Banerjee S, J. Vinyl Add. Technol., 15, 164 (2009)
  •  
  • 6. Wen RJ, Yang ZH, Chen HY, J. Rare Earths, 30, 895 (2012)
  •  
  • 7. Smith JV, Chem. Rev., 88, 149 (1988)
  •  
  • 8. Gupta S, Agarwal DD, Banerjee S, J. Vinyl Add. Technol., 15, 164 (2009)
  •  
  • 9. Grossman RF, J. Vinyl Add. Technol., 6, 4 (2000)
  •  
  • 10. Yingjun Q, Senfang C, Qiliang Z, Kezhen Z, Wei T, Erjin G, Polyvinyl Chloride, 11, 36 (2011)
  •  
  • 11. Atakul S, Balkose D, Ulku S, J. Vinyl Add. Technol., 11, 47 (2005)
  •  
  • 12. Lepilleur AC, Mazany MA, Milenius LD, Backman AL, U.S. Patent 6,306,945 (2001)
  •  
  • 13. Pi H, Doctorate, Sichuan University, Chengdu, China (2013)
  •  
  • 14. Pimentel Real LE, Ferraria AM, Botelho do Rego AM, Polym. Test., 9, 743 (2008)
  •  
  • 15. Zhao X, Inner Mongolia Petrochemical Industry, 11, 171 (2007)
  •  
  • 16. Fernandez M, Tortajada J, Zeitschri LM, Physica D, 9, 243 (1988)
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2015; 39(1): 1-5

    Published online Jan 25, 2015

  • Received on Jan 17, 2014
  • Accepted on Aug 6, 2014