Article
  • Synthesis of Novel Silicone Containing Vinylic Monomer and Its Uses in the Waterborne Polyurethane-Veova/Vinyl Acetate Hybrid Emulsion Copolymers
  • Naghash HJ, Naeni EK
  • 비닐단량체를 함유한 새로운 실리콘의 합성과 수성 Polyurethane-Veova/Vinyl Acetate 하이브리드 에멀젼 공중합체 내에서 사용
  • Naghash HJ, Naeni EK
Abstract
A novel silicone (Si) containing vinylic monomer, N-(3-(triethoxysilyl)propyl) methacrylamide (TESPMA), based on 3-aminopropyltriethoxysilane (APTES) and methacryloyl chloride (MCl) has been synthesized for formulation of waterborne polyurethane (WPU). Two types of vinyl group containing Si, methacryloxypropyltriethoxysilane (MPTES) and triethoxyvinylsilane(TEVS), have been used as coupling reagents for comparison of the effects of Si kinds with TESPMA on the WPU. A series of new siliconized WPU, vinyl acetate/vinyl ester of versatic acid (VAc-Veova), TESPMA, MPTES and TEVS hybrid latexes have been successfully prepared by emulsion polymerization in the presence of WPU dispersion.

Keywords: N-(3-(triethoxysilyl)propyl) methacrylamide; silicones; polyurethanes; polymer synthesis and characterization; glass transition; coatings.

References
  • 1. Kwak YS, Kim EY, Kim HD, Lee JB, Colloid Polym. Sci., 283, 880 (2005)
  •  
  • 2. Geurink PJA, Scherer T, Buter R, Steenbergen A, Henderiks HA, Prog. Org. Coat., 55, 119 (2006)
  •  
  • 3. Fekete E, Lengyel B, Prog. Org. Coat., 54, 211 (2005)
  •  
  • 4. Davis J, Mater. Performance., 42, 24 (2003)
  •  
  • 5. Huang L, Nabar S, Adhes. Age, 45(12), 19 (2002)
  •  
  • 6. Landfester K, Pawelzik U, Antonietti M, Polymer, 46(23), 9892 (2005)
  •  
  • 7. Vuillequez A, Moreau J, Garda MR, Youssef B, Saiter JM, J. Polym. Res., 15, 89 (2008)
  •  
  • 8. Kim EH, Myoung SW, Jung YG, Paik U, Prog. Org. Coat., 64, 205 (2009)
  •  
  • 9. Pieper RJ, Ekin A, Webster DC, Casse F, Callow JA, Callow ME, J. Coat. Technol. Res., 4, 453 (2007)
  •  
  • 10. Zhang FA, Yu CL, J. Coat. Technol. Res., 4, 289 (2007)
  •  
  • 11. Yang J, Zhou S, You B, Wu L, J. Coat. Technol. Res., 3, 4 (2006)
  •  
  • 12. Zhang C, Zhang X, Dai J, Bai C, Prog. Org. Coat., 63, 238 (2008)
  •  
  • 13. Tsai MF, Lee YD, Long YC, J. Polym. Res., 7, 73 (2000)
  •  
  • 14. Lu YS, Larock RC, Biomacromolecules, 8(10), 3108 (2007)
  •  
  • 15. Shaffie KA, Moustafa AB, Mohamed ES, Badran AS, J. Polym. Sci. A: Polym. Chem., 35(15), 3141 (1997)
  •  
  • 16. Pokhriyal NK, Sanghvi PG, Shah DO, Devi S, Langmuir, 16(14), 5864 (2000)
  •  
  • 17. Badran AS, Moustafa AB, Yehia AA, Shendy SMM, J. Polym. Sci. Part A: Polym. Chem., 28, 411 (1990)
  •  
  • 18. Lambourne R, Paint and Surface Coatings Theory and Practice, Ellis Horwood market Cross House, Editor, Chichester, West Sussex, England, Ch. 9, pp 59-363 (1987)
  •  
  • 19. Chen L, Chen S, Prog. Org. Coat., 49, 252 (2004)
  •  
  • 20. Okamoto Y, Hasegawa Y, Yoshino F, Prog. Org. Coat., 29, 175 (1996)
  •  
  • 21. Ba Y, Ratcliffe CI, Ripmeester JA, Adv. Mater., 12(8), 603 (2000)
  •  
  • 22. Jun Y, Shuxue Z, Bo Y, Limin W, J. Coat. Technol. Res., 3, 333 (2006)
  •  
  • 23. Wang LF, Ji Q, Glass TE, Ward TC, McGrath JE, Muggli M, Burns G, Sorathia U, Polymer, 41(13), 5083 (2000)
  •  
  • 24. Chen X, Gardella JA, Ho T, Wynne KJ, Macromolecules., 28, 635 (1995)
  •  
  • 25. Cho G, Natansohn A, Ho T, Wynne KJ, Macromolecules, 29(7), 2563 (1996)
  •  
  • 26. Pike JK, Ho T, Wynne KJ, Chem. Mater., 8, 856 (1996)
  •  
  • 27. Gardella JA, Ho T, Wynne KJ, Zhuang HZ, J. Colloid Interface Sci., 176(1), 277 (1995)
  •  
  • 28. Ho T, Wynne KJ, Nissan RA, Macromolecules., 26, 7029 (1993)
  •  
  • 29. Rochery M, Vroman I, Lam TM, J. Macromol. Sci. Pure Appl. Chem., 40, 321 (2003)
  •  
  • 30. Wang HH, Shen YD, Fei GQ, Li XR, Liang Y, J. Colloid Interface Sci., 324(1-2), 36 (2008)
  •  
  • 31. Zhang FA, Yu CL, J. Coat. Technol. Res., 4, 289 (2007)
  •  
  • 32. Zhang C, Zhang X, Jiabing D, Bai C, Prog. Org. Coat., 63, 238 (2008)
  •  
  • 33. Jiang HM, Zheng Z, Song WH, Li ZM, Wang XL, Polym. Bull., 59(1), 53 (2007)
  •  
  • 34. Naghash HJ, Karimzadeh A, Massah AR, J. Appl. Polym. Sci., 112(2), 1037 (2009)
  •  
  • 35. Naghash HJ, Mallakpour S, Forushani PY, Uyanik N, Polym.(Korea), 32(2), 95 (2008)
  •  
  • 36. Naghash HJ, Karimzadeh A, Momeni AR, Massah AR, Alian H, Turk. J. Chem., 31, 257 (2007)
  •  
  • 37. Naghash HJ, Mallakpour S, Mokhtarian N, Prog. Org. Coat., 55, 375 (2006)
  •  
  • 38. Naghash HJ, Mallakpour S, Kayhan N, Iran. Polym. J., 14, 211 (2005)
  •  
  • 39. Wang C, Chu F, Graillat B, Guyot A, Gauthier C, Chapel JP, Polymer, 46(4), 1113 (2005)
  •  
  • 40. Otts DB, Dutta S, Zhang P, Smith OW, Thames SF, Urban MW, Polymer, 45(18), 6235 (2004)
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2011; 35(5): 409-418

    Published online Sep 25, 2011

  • Received on Feb 7, 2011
  • Accepted on Apr 26, 2011