Article
  • Synthesis and Properties of High Heat and Radiation Resistant Compound, Methylmethacrylate-EPDM-2-Vinylnaphthalene and Their Blends
  • Park JY, Son HH, Lee SW, Seo BD, Park DJ, Ha CS, Cho WJ
  • 내열성과 내방사성이 우수한 Methacrylate-EPDM-2-Vinyl Naphthalene으로 된 신소재의 합성과 이들을 포함하는 Blend물의 물성
  • 박주용, 손현희, 이승욱, 서범두, 박덕제, 하창식, 조원제
Abstract
The graft copolymerization of methyl methacrylate(MMA) and 2-vinylnaphthalene(2-VN) onto ethylene-propylene-diene terpolymer(EPDM) was carried out with benzoyl peroxide(BPO) as an initiator in tetrahydrofuran(THF) at 80℃ for 60 hrs. The synthesizwd graft copolymer, MMA-EPDM-2-VN(MEV2), was identified by IR spectrum. In order to investigate the radiation resistance of the MEV2 the light resistance, tensile properties and thermal stabilith of the graft copolymer before and after γ-ray radiation were investigated. Grafting efficiency was 47% and number average molecular weight(Mn) was 90,000. the light resistance, radiation resistance, and thermal stablilty of MEV2 were better than those of ABS. Three kinds of blends containing MEV2 with poly(vinylchloride)(PVC), Poly(methacrylate)(PMMA) and polycarbonate(PC) were prepared by casting from their THF and chloroform solutions, respectively. Miscibility of MEV2 with PC was shown better than that with PVC or PMMA from the differential scanning calorimeter(DSC) and fluorescence spectroscopic studies, even though all of the blends showed phase separation.

Ethylene-propylene-야

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  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 1993; 17(6): 720-728

    Published online Nov 25, 1993