Article
  • Study on the Mechanical Properties and Crystallization Behavior of Compatibilized Poly(lactic acid)/Poly(3HB-co-4HB) Blends
  • In Gyu Choi, Se Jun Yang, Tae Min Lee, Jae Uk Yoon, Jin Woo Bae  , and Byeong Uk Nam 

  • Department of Applied Chemical Enginnering, Korea University of Technology and Education

  • 상용화제가 도입된 Poly(lactic acid)/Poly(3HB-co-4HB) 블렌드의 기계적 물성 및 결정화 거동 연구
  • 최인규 · 양세준 · 이태민 · 윤재욱 · 배진우  · 남병욱 

  • 한국기술교육대학교 에너지신소재화학공학부 응용화학공학전공

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Burzic, I.; Pretschuh, C.; Kaineder, D.; Eder, G.; Smilek, J.; Impact Modification of PLA Using Biobased Biodegradable PHA Biopolymers, Europ. Polym. J. 2019, 114, 32-38.
  •  
  • 2. Ecker, J. V.; Burzic, I.; Haider, A.; Hild, S. Rennhofer, H.; Improving the Impact strength of PLA and its Blends with PHA in Fused Layer Modelling, Polym. Test. 2019, 78, 105929.
  •  
  • 3. Garlotta, D.; A Literature Review of Poly(Lactic Acid), J. Polym. Environ. 2001, 9, 63-84.
  •  
  • 4. Swetha, T. A.; Bora, A.; Mohanrasu, K.; Balaji, P.; Raja, R.; Ponnuchamy, K.; Muthusamy, G. Arum, A.; A Comprehensive Review on Polylactic acid(PLA)-Synthesis, Processing and Application in Food Packaging, Int. J. Biological Macromol. 2023, 234, 123715.
  •  
  • 5. Zech, J.; Mader, M.; Gündel, D.; Metz, H.; Odparlik, A.; Agarwal, S.; Mäder, K.; Greiner, A.; Noninvasive Characterization (EPR, µCT, NMR) of 3D PLA Electrospun Fiber Sponges for Controlled Drug Delivery, Int. J. Pharmaceutics X 2020, 2, 100055.
  •  
  • 6. Tábi, T.; Ageyeva, T.; Kovács, J. G. The Influence of Nucleating Agents, Plasticizers, and Molding Conditions on the Properties of Injection Molded PLA Products, Mater. Today Commun. 2022, 32, 103936.
  •  
  • 7. Choochottiros, C.; Chin, I. J. Potential Transparent PLA impact modifiers based on PMMA copolymers, Eur. Polym. J. 2013, 49, 957-966.
  •  
  • 8. Chang, F. L.; Hu, B.; Huang, W. T.; Chen, L.; Yin, X. C.; Cao, X. W.; He, G. J.; Improvement of Rheology and Mechanical Properties of PLA/PBS Blends by in-situ UV-induced Reactive Extrusion, Polymer 2022, 259, 125336.
  •  
  • 9. Nofa, M.; Tabatabaei, A.; Sojoudiasli, H.; Park, C. B.; Carreau, P. J.; Heuzey, M. C.; Kamal, M. R. Mechanical and Bead Foaming Behavior of PLA-PBAT and PLA-PBSA Blends with Different Morphologies, Eur. Polym. J. 2017, 90, 231-244.
  •  
  • 10. Relinque, J. J.; Leon, A. S.; Hernandez-Saz, J.; Garcia-Romero, M. G.; Navas-Martos, F. J.; Morales-Cid, G.; Molina, S. I.; Development of Surface-Coated Polylactic Acid/Polyhydroxyalkanoate(PLA/PHA) Nanocomposites, Polymers 2019, 11, 400.
  •  
  • 11. Sun, J.; Shen, J.;Chen, S.; Cooper, M. A.; Fu, H.; Wu, D.; Yang, Z.; Nanofiller Reinforced Biodegradable PLA/PHA Composites: Current Status and Future Trends, Polymers 2018, 10, 505.
  •  
  • 12. Vernaez, O.; Neubert, K. J.; Kopitzky, R.; Kabasci, S.; Compatibility of Chitosan in Polymer Blends by Chemical Modification of Bio-based Polyesters, Polymers 2019, 11, 1939.
  •  
  • 13. Nam, B.U.; Kim, S.J.; A Study on the Commercialization of Polyamide 66/Polypropylene Blend, Elastomer 2003, 38, 262-272.
  •  
  • 14. Ma, P.; Cai, X.; Lou, X.; Dong, W.; Chen, M. Lemstra, P. J.; Styrene-assisted Melt Free-radical Grafting of Maleic Anhydride Onto Poly(b-hydroxybutyrate), Polymer Degrad. Stab. 2014, 100, 93-100.
  •  
  • 15. Hwang, S. W.; Lee, S. S.; Lee, C. K.; Lee, J. Y.; Shim, J. K.; Selke, S. E.; Soto-Valdez H.; Matuana, L.; Rubino, M.; Auras, R.; Grafting of Maleic Anhydride on Poly(L-lactic acid). Effects on Physical and Mechanical Properties, Polym. Test. 2012, 31, 333-344.
  •  
  • 16. Hassouna, F.; Raquez, J. M.; Addiego, F.; Toniazzo, V.; Dubois, P.; Ruch, D. New Development on Plasticized Poly(lactide): Chemical Grafting of Citrate on PLA by Reactive Extrusion, Eur. Polym. J. 2012, 48, 404-415.
  •  
  • 17. Detyothin, S.; Selke, S. E.; Narayan, R.; Rubino, M.; Auras, R.; Reactive Functionalization of Poly(lactic acid), PLA: Effects of the Reactive Modifier, Initiator and Processing Conditions on the Final Grafted Maleic Anhydride Content and Molecular Weight of PLA, Polym. Degrad. Stab. 2013, 12, 2697-2708.
  •  
  • 18. Sclavons, M.; Carlier, V.; De Roover, B.; Franquinet, P.; Devaux, J.; Legras, R. The Anhydride Content of Some Commercial PP g MA: FTIR and Titration. J. Appl. Polym. Sci. 1996, 62, 1205-1210.
  •  
  • 19. Han, G. H.; Yoon, J. H.; Lee, C. S.; Lee, E. H.; Yoon, K. C.; Biodegradation Behavior of Amorphous Polyhydroxyalkanoate-Incorporated Poly(L-lactic acid) under Modulated Home-composting Conditions, Polym. Test. 2023, 126, 108155.
  •  
  • 20. Wagner, A.; Poursorkhabi, V.; Mohanty, A. K.; Misra, M.; Analysis of Porous Electrospun Fibers from Poly(L-lactic acid)/Poly(3-hydroxybutyrate-co-3hydroxyvalerate) Blends, ACS Sustainable Chem. Eng. 2014, 2, 1976-1982.
  •  
  • 21. Khoo, R. Z.; Ismail, H.; Chow, W. S.; Thermal and Morphological Properties of Poly(lactic acid)/Nanocellulose Nanocomposites, Procedia Chem. 2016, 19, 788-794.
  •  
  • 22. Yang, J.; McCoy B. J.; Distribution Kinetics of Polymer Crystallization and the Avrami Equation, J. Chem. Phys. 2005, 122, 064901.
  •  
  • 23. Toda, A.; Effect of a Nucleating Agent on Polymer Crystallization Analyzed Using the Original Avrami Model, Marcromolecules 2022, 55, 2202-2209.
  •  
  • 24. Han, J. G.; Park, S. J.; Fanzhu, L.; Park, H. W. ; Effects on the Tensile Strength and Discharge Volume of the White Biodegradable Plastic film added Compatibilizer, Korean J. Packaging Sci. Technol. 2021, 27, 169-174.
  •  
  • 25. Lee, J. B.; Kim, D. Y.; Nam, K. B.; Seo, K. H.; Lee, D. Y.; Compatibility and Impact Properties of Poly(lactic acid)/Poly(butylene adipate-co-terephthalate) Blend Using Poly(butyl acrylate), Polym. Korea 2020, 44, 689-694.
  •  
  • 26. Cho, Y. H.; Crystallization Behavior of Polymer Nanocomposite Thin Film, Polym. Korea 2019, 43, 224-234.
  •  
  • 27. Lee, K. M.; Kim, K. J.; Kim, Y. H.; Isothermal Crystallization Behavior and Some Physical Parameters of Poly(trimethylene terephthalate), Polym. Korea 1999, 23, 56-65.
  •  
  • 28. Jung, H. Y.; Ko, Y. S.; Synthesis of Star-Shaped PLLA in Bulk and Solution Polymerizations with Multifunctional Amine Initiators and Comparison of Their Crystallinity. Polym. Korea 2019, 43, 123-131.
  •  
  • 29. Kim, K. R.; Han, J. W.; Kang, H. J.; Crystallization Characteristics of Metallocene Low Density Polyethylene/Low Density Polyethylene Blends, Polym. Korea 2001, 25, 840-847.
  •  
  • 30. Zhou, K. Y.; Lia, J. B.; Wang, H. X. Rena, J.; Effect of Star-shaped Chain Architectures on the Polylactide Stereo complex Crystallization Behaviors, Chinese J. Polym. Sci. 2017, 35, 974-991.
  •  
  • 31. Kim, Y. C.; Study on the Non-isothermal Crystallization Behavior of Polypropylene/Corn Starch-MB Blends, J. Korea Academia-Industrial Cooperation Soc. 2008, 9, 1125-1129.
  •  
  • 32. Wu, T.; Liu, Y.; Li, N.; Huang, G. W.; Qu, C. B.; Xiao, H. M.; Cryogenic Mechanical Properties of Epoxy Resin Toughened by Hydroxyl-terminated Polyurethane, Polymer Test. 2019, 74, 45-56.
  •  
  • 33. Mao, Z.; Jiang, T.; Zhang, X.; Jiang, G.; Zhang, J.; Co-continuous Phase Structure Formed in Melt Processing Induc ing Shear Bands to Prevent Crack Propagation: Significant Imp Rovement in Impact Toughness of PMMA, Polym. Test. 2020, 85, 106425.
  •  
  • 34. Lee, S. M.; Characteristics of Epoxy Nanocomposites for Outdoor Use with Improved Mechanical Properties, Polym. Korea 2020, 44, 186-191.
  •  
  • 35. Li, X.; Zhu, C.; Wang, H.; Xiao, Y.; Lu, X.; Li, I.; Liu, Z.; Tong, Y.; Qu, J.; A Novel PLA/P(3HB-co-4HB)/MWCNT Composite Featureing Enhanced Mechanical Properties and Excellent Thermal Stability Based on Elongational Rheology. Polym. Test. 2022, 114, 107700.
  •  
  • 36. Wang, L.; Dong, C. M.; Synthesis, Crystallization Kine tics, and Spherulitic Growth of Linear and Star-Shaped Poly (L-lactide)s with Different Numbers of Arms, J. Polym. Sci. Part A: Polym. Chem. 2005, 44, 2226-2236.
  •  
  • 37. Park, Y. J.; Lee, J. W.; Thermal Properties of Poly(lactic acid) Film Containing Antibacterial Quercetin. Polym. Korea 2022, 46, 223-228.
  •  
  • 38. Park, E. J.; Park, H. J.; Kim, D. H.; Effects of Nucleating Agents and Plasticizers on the Crystallinity and Crystal Structure of PLA (PolyLacitc Acid), J. Korea Academia-Industrial Cooperation Soc. 2015, 16, 914-920.
  •  
  • 39. Lee, K. M.; Kim, K, J.; Kim, Y. H.; Isothermal Crysta Llization Behavior and Some Physical Parameters of Poly(trimethylene terephthalate), Polym. Korea 1999, 23, 56-65.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2024; 48(5): 475-484

    Published online Sep 25, 2024

  • 10.7317/pk.2024.48.5.475
  • Received on Feb 1, 2024
  • Revised on Jun 6, 2024
  • Accepted on Jun 7, 2024

Correspondence to

  • Jin Woo Bae , and Byeong Uk Nam
  • Department of Applied Chemical Enginnering, Korea University of Technology and Education

  • E-mail: jwbae@koreatech.ac.kr, bunam@koreatech.ac.kr