Article
  • Physical Properties of Polyurethane Sheets Prepared with Synthesized Soybean Oil Polyol
  • Ha Eun Lee and Dae Su Kim

  • Department of Chemical Engineering, Chungbuk National University, 1 Chungdaero, Seowongu, Cheongju, Chungbuk 28644, Korea

  • 대두유 폴리올 합성 및 이를 활용한 폴리우레탄 시트의 물성
  • 이하은 · 김대수

  • 충북대학교 공과대학 화학공학과

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Akindoyo, J. O.; Beg, M. D.; Ghazali, H. S.; lslam, M. R.; Jeyaratnam, N.; Yuvaraj, A.R. Polyurethane Types, Synthesis and Applications-a Review. RSC Adv. 2016,6, 114453-114482.
  •  
  • 2. Szycher,M. Szychers Handbook of Polyurethanes; CRC Press: New York, 2012.
  •  
  • 3. Petrovic, Z. S. Polyurethanes from Vegetable Oils. Polymer Reviews 2008, 48, 109-155.
  •  
  • 4. Xu, Q.; Lin J.; Jiang G. Synthesis, Characterization and Properties of Soybean Oil-Based Polyurethane. Polymers 2022, 14, 2201.
  •  
  • 5. Chen, R.; Zhang, C.; Kessler, M. R. Polyols and Polyurethanes Prepared from Epoxidized Soybean Oil Ring-Opened by Polyhydroxy Fatty Acids with Varying OH Numbers. J. Appl. Polym. Sci. 2015, 132, 41213.
  •  
  • 6. Garrison, T. F.; Larock, R. C.; Kessler, M. R. Effects of Unsaturation and Different Ring Opening Methods on the Properties of Vegetable Oil-Based Polyurethane Coatings. Polymer 2014, 55, 1004-1011.
  •  
  • 7. Multu H.; Meier, M. A. R. Castor Oil as a Renewable Resource for the Chemical Industry. Eur. J. Lipid Sci. Technol. 2010, 112, 10-30.
  •  
  • 8. Tu, Y.; Kiatsimkul, P.; Suppes, G.; Hsieh, F. Physical Properties of Water-Blown Rigid Polyurethane Foams from Vegetable Oil-Based Polyols. J. Appl. Polym. Sci. 2007, 105, 453-459.
  •  
  • 9. Guo, A.; Zhang, W.; Petrovic, Z. S. Structure–Property Relationships in Polyurethanes Derived from Soybean Oil. J. Mater. Sci. 2006, 41, 4914-4920.
  •  
  • 10. Petrovic, Z. S.; Zhang, W.; I. Javni, Structure and Properties of Polyurethanes Prepared from Triglyceride Polyols by Ozonolysis. Biomacromolecules 2005, 6, 713-719.
  •  
  • 11. Veronese, V. B.; Menger, R. K.; Forte, M. M. D. C.; Petzhold, C. L, Rigid Polyurethane Foam Based on Modified Vegetable Oil. J. Appl. Polym. Sci. 2011, 120, 530-537.
  •  
  • 12. Mosiewicki, M. A.; Dell'Arciprete, G. A.; Aranguren, M. I.; Marcovich, N. E. Polyurethane Foams Obtained from Castor Oil-based Polyol and Filled with Wood Flour. J. Compos. Mater. 2009, 43, 3057-3072.
  •  
  • 13. Guo, A.; Demydov, D.; Zhang, W.; Petrovic, Z. S. Polyols and Polyurethanes from Hydroformylation of Soybean Oil, J. Polym. Environ. 2002, 10, 49-52.
  •  
  • 14. Guo, A.; Cho, Y.; Petrovic, Z. S. Structure and Properties of Halogenated and Non-halogenated Soy-Based Polyols. J. Polym. Sci. A: Polym. Chem. 2000, 38, 3900-3910.
  •  
  • 15. Kiatsimkul, P.; Suppes, G. J.; Sutterlin, W. R. Production of New Soy-Based Polyols by Enzyme Hydrolysis of Bodied Soybean Oil. Ind. Crops Prod. 2007, 25, 202-209.
  •  
  • 16. Ji, D.; Fang, Z.; He, W.; Luo, Z.; Jiang, X.; Wang, T.; Guo, K. Polyurethane Rigid Foams Formed from Different Soy-Based Polyols by the Ring Opening of Epoxidised Soybean Oil with Methanol, Phenol, and Cyclohexanol. Ind. Crops Prod. 2015, 74, 76-82.
  •  
  • 17. Favero, D.; Marcon, V. R. R.; Barcellos, T.; Gómez, C. M.; Sanchis, M. J.; Carsí, M.; Figueroa, C. A.; Bianchi, O. Renewable Polyol Obtained by Microwave-Assisted Alcoholysis of Epoxidized Soybean Oil: Preparation, Thermal Properties and Relaxation Process. J. Mol. Liq. 2019, 285, 136-145.
  •  
  • 18. Ziatanic, A.; Lava, C.; Zhang, W.; Petrovic, Z. S. Effect of Structure on Properties of Polyols and Polyurethanes Based on Different Vegetable Oils. J. Polym. Sci. Part B: Polym. Phys. 2004, 42, 809-819.
  •  
  • 19. Woo Y. J.; Kim, D. S. Physical Properties of a DGEBA Epoxy Resin System Modified with Epoxidized Soybean Oil. Polym. Korea 2019, 43, 359-364.
  •  
  • 20. Pandya, M. V.; Deshpande, D. D.; Hundiwale, D. G. Effect of Diisocyanate Structure on Viscoelastic, Thermal, Mechanical and Electrical Properties of Cast Polyurethanes. J. Appl. Polym. Sci. 1986, 32, 4959-4969.
  •  
  • 21. Swamy, B. K. K.; Siddaramaiah; Somashekar R. Structure-Property Relationship of Castor Oil Based Diol Chain Extended Polyurethanes (PUs). J. Mater. Sci. 2003, 38, 451-460.
  •  
  • 22. Simon, J.; Barla F.; Kelemen-Haller A.; Farkas F.; Kraxner M. Thermal Stability of Polyurethanes. Chromatographia, 1988, 25, 99-106.
  •  
  • 23. Javni, I.; Petrovic, Z. S.; Guo A.; Fuller, R. Thermal Stability of Polyurethanes Based on Vegetable Oils. J. Appl. Polym. Sci., 2000, 77, 1723-1734.
  •  
  • 24. Macalino, A. D., Salen, V. A. and Reyes, L. Q. Castor Oil Based Polyurethanes: Synthesis and Characterization. IOP Conf. Series: Materials Science and Engineering, 2017, 229, 012016.
  •  
  • 25. Saunders, J. H. The Reactions of Isocyanates and Isocyanate Derivatives at Elevated Temperatures. Rubber Chem. Tech. 1959, 32, 337-345.
  •  
  • 26. Lu, Y.; Larock, R. C. Soybean-oil-based Waterborne Polyurethane Dispersions: Effects of Polyol Functionality and Hard Segment Content on Properties. Biomacromolecules, 2008, 9, 3332-3340.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2024; 48(2): 127-132

    Published online Mar 25, 2024

  • 10.7317/pk.2024.48.2.127
  • Received on Jul 4, 2023
  • Revised on Aug 1, 2023
  • Accepted on Aug 24, 2023

Correspondence to

  • ae Su Kim
  • Department of Chemical Engineering, Chungbuk National University, 1 Chungdaero, Seowongu, Cheongju, Chungbuk 28644, Korea

  • E-mail: dskim@cbnu.ac.kr