Article
  • Studies on Optimizing Properties of Self-Healing Polyurethane Resins for Automotive Plastic Parts

  • Choonho Lee, Woochul Jung, Hakjune Rhee*, **,† , and Yongchul Lee*,†

  • Materials Research & Engineering Center, Hyundai Motor Company, Hwaseong-si, Gyeonggi-do, 18278, Korea
    *Department of Applied Chemistry, Hanyang University, Ansan, Gyeonggi-do, 15588, Korea
    **Department of Chemical and Molecular Engineering, Hanyang University, Ansan, Gyeonggi-do, 15588, Korea

  • 자동차 플라스틱 부품용 자가복원 폴리우레탄 수지의 물성 최적화 연구

  • 이춘호 · 정우철 · 이학준*, **,† · 이용철*,†

  • 현대자동차 기초소재연구센터, *한양대학교 응용화학과, **한양대학교 화학분자공학과

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Feng, L.; Benhamida, N.; Sung, L.; Morel, P. Fundamentals and Characterizations of Scratch Resistance on Automotive Clearcoats. Prog. Org. Coat. 2018, 125, 339-347.
  •  
  • 2. Jeon, H.; Jeong, K.; Jang, S.; Jung, S. A Study on the Scratch Self-healing Coating for Automobile Interior Parts. KSAE. 2012, 13, 1165-1166.
  •  
  • 3. Linossier, F.; Langlois, I.; Haras, V.; ValleeRehel, D. Two Powerful Techniques for the Study of Antifouling Paints. Prog. Org. Coat. 2012, 54, 216-223.
  •  
  • 4. Cho, S.; White, S.; Braun, P. Healing Polymer Coatings. Adv. Mater. 2009, 21, 645-649.
  •  
  • 5. White, S.; Sottos, N.; Geubelle, P.; Moore, J.; Kessler, M.; Sriram, S.; Brown, E.; Viswanathan, S. Autonomic Healing of Polymer Composition. Nature 2001, 409, 794-797.
  •  
  • 6. Edwin, A.; Pedro, P.; Ligia, S. Characterization of Hyperbranched Polyol Polyesters Based on 2,2-bis(methylol propionic acid)and Pentaerythritol. App. Polym. Sci. 2009, 112, 200-207.
  •  
  • 7. Liang, Z.; Huang, D.; Zhao, L.; Nie, Y.; Hao, T.; Li, S. Self‑healing Polyurethane Elastomer Based on Molecular Design: Combination of Reversible Hydrogen Bonds and High Segment Mobility. Org. Polym. Mat. 2021, 31, 683-694.
  •  
  • 8. Liua, N.; Yuhua, B.; Kanga, M.; Wanga, J.; Fenga, Y.; Yina, N. The Effects of the Molecular Weight and Structure of Polycarbonatediols on the Properties of Waterborne Polyurethanes. Prog. Org. Coat. 2015, 82, 46-56.
  •  
  • 9. Son, H.; Jeon, D.; Park, S.; Kim, Y.; Kwon, K.; Kim, K. The Influence of Soft/Hard Segment Composition and Content on the Abrasion Resistance of Polyurethane Coating Agents. TRANS. KSAE. 2014, 22, 5-12.
  •  
  • 10. Ghoreishy, M.; Razavi-Nouri, M.; Naderi, G. Finite Element Analysis of a Thermoplastic Elastomer Melt Flow in the Metering Region of a Single Screw Extruder. Computat. Mater. Sci. 2005, 34, 389-396.
  •  
  • 11. Koerner, H.; Koerner, J.; Kelley, J.; Vaia, R. Transient Microstructure of Low Hard Segment Thermoplastic Polyurethane Under Uniaxial Deformation. Macromolecules 2008, 41, 4709-4716.
  •  
  • 12. Furukawa, M.; Hamada, Y.; Kojio, K. Aggregation Structure and Mechanical Properties of Functionally Graded Polyurethane Elastomers. J. Polym. 2003, 41, 2355–2364.
  •  
  • 13. Kojio, K.; Nonaka, Y.; Masubuchi, T.; Furukawa, M. Effect of the Composition Ratio of Copolymerized Poly(carbonate) Glycol on the Microphase-separated Structures and Mechanical Properties of Polyurethane Elastomers. J. Polym. Sci. Part B. 2004, 42, 4448-4458.
  •  
  • 14. Sheikhy, H.; Shahidzadeh, M.; Ramezanzadeh, B.; Noroozi, F. Studying the Effects of Chain Extenders Chemical Structures on the Adhesion and Mechanical Properties of a Polyurethane Adhesive. J. Ind. Eng. Chem. 2013, 19, 1949-1955.
  •  
  • 15. Lee,W.; Oh, H.; Cha, S. A Brief Review of Self-Healing Polyurethane Based on Dynamic Chemistry Macromolecular Research. Macro. Res. 2021, 29, 649-664.
  •  
  • 16. Lee, Y.; Lee, H. Studies on the Optimizing the Properties of Thermoset Polyurethane Resin for In-mold Coating. Polym. Korea 2022, 46, 484-490.
  •  
  • 17. Junrui, Z.; Tua, W.; Zilin, D. Synthesis and Characterization of Transparent and High Impact Resistance Polyurethane Coatings Based on Polyester Polyols and Isocyanate Trimers. Prog. Org. Coat. 2012,75, 579-583.
  •  
  • 18. Gite, V.; Kapadi, W. Polyurethane Coatings an Overview. Hund. Paintindia. 2003, 53, 47-58.
  •  
  • 19. Kachan, A.; Kargan, N.; Kulik, N.; Boyarskii G. Two-photon Heterogeneous Photodegra-deation of an Aromatic Polyurethane. Theor. Exp. Chem. 1971,4, 314-317.
  •  
  • 20. Kim, H.; Lee, T.; Huh, J.; Lee, D. Preparation and Properties of Segmented Thermoplastic Polyurethane Elastomers with Two Different Soft Segments. Appl. Polym. Sci. 1999, 73, 345-352.
  •  
  • 21. Chen, T.; Chui, J.; Shieh, T. Glass Transition Behaviors of a Polyurethane Hard Segment based on 4,4’-Diisocyanatodip- henylmethane and 1,4-Butanediol and the Calculation of Microdomain Composition. Macromolecules 1997, 30, 5068-5074.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2024; 48(1): 60-67

    Published online Jan 25, 2024

  • 10.7317/pk.2024.48.1.60
  • Received on Sep 6, 2023
  • Revised on Nov 7, 2023
  • Accepted on Nov 25, 2023

Correspondence to

  • Hakjune Rhee*, ** , and Yongchul Lee*

  • *Department of Applied Chemistry, Hanyang University, Ansan, Gyeonggi-do, 15588, Korea
    **Department of Chemical and Molecular Engineering, Hanyang University, Ansan, Gyeonggi-do, 15588, Korea

  • E-mail: hrhee@hanyang.ac.kr, cjohnny@hanyang.ac.kr