Article
  • Enhanced Thermomechanical Properties of Stereo-complexed PLA Copoymer via In-situ Polymerization

  • Sang-Ha Hwang, Young Sil Lee*, and Kwan Han Yoon**,†

  • Materials Science and Chemical Engineering Center, Institute for Advanced Engineering, 175-28 Goan-ro 51, Baegam-myeon, Cheoin-gu, Yongin-si, Gyeonggi-do 17180, Korea
    *Industry-Academic Cooperation Foundation, Kumoh National Institute of Technology, 1 Yangho-dong, Gumi 39177, Korea
    **Department of Chemical Engineering, Kumoh National Institute of Technology, 1 Yangho-dong, Gumi 39177, Korea

  • In-situ 중합법에 의한 입체복합 PLA 공중합체의 열변형 특성

  • 황상하 ·이영실* ·윤관한**,†

  • 고등기술연구원, *금오공과대학교 산학협력단, **금오공과대학교 화학공학과

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Rasal, R. M.; Janorkar, A. V.; Hirt, D. E. Poly(lactic acid) modifications. Prog. Polym. Sci. 2010, 35, 338-356.
  •  
  • 2. Song, R.; Murphy, M.; Li, C.; Ting, K.; Soo, C.; Zheng, Z. Current Development of Biodegradable Polymeric Materials for Biomedical Applications. Drug Des. Devel. Ther. 2018, 12, 3117-3145.
  •  
  • 3. Ikada, Y.; Jamshidi, K.; Tsuji, H.; Hyon, S. H. Stereocomplex Formation Between Enantiomeric Poly(lactides). Macromolecules. 1987, 20, 904-906.
  •  
  • 4. Tsuji, H. Poly(lactide) Stereocomplexes: Formation, Structure, Properties, Degradation, and Applications. Macromol Biosci. 2005, 5, 569-597.
  •  
  • 5. Fukushima, K.; Kimura, Y. Stereocomplexed Polylactides (Neo-PLA) as High-performance Bio-based Polymers: Their Formation, Properties, and Application. Polym. Int. 2006, 55, 626-642.
  •  
  • 6. Li, Z.; Tan, B. H.; Lin, T.; He, C. Recent Advances in Stereocomplexation of Enantiomeric PLA-based Copolymers and Applications. Prog. Polym. Sci. 2016, 62, 22-72.
  •  
  • 7. Jing, Y.; Quan, C.; Liu, B.; Jiang, Q.; Zhang, C. A Mini Review on the Functional Biomaterials Based on Poly(lactic acid) Stereocomplex. Polym. Rev. 2016, 56, 262-286.
  •  
  • 8. Tan, B. H.; Muiruri, J. K.; Li, Z.; He, C. Recent Progress in Using Stereocomplexation for Enhancement of Thermal and Mechanical Property of Polylactide. ACS Sustain. Chem. Eng. 2016, 4, 5370-5391.
  •  
  • 9. Saravanan, M.; Domb, A. J. A Contemporary Review on - Polymer Stereocomplexes and Its Biomedical Application. Eur. J. Nanomed. 2013, 5, 81-96.
  •  
  • 10. Rahaman, M. H.; Tsuji, H. Synthesis and Characterization of Stereo Multiblock Poly(lactic acid)s with Different Block Lengths by Melt Polycondensation of Poly(L-lactic acid)/Poly(D-lactic acid) Blends, Macromol. React. Eng. 2012, 6, 446-457.
  •  
  • 11. Yamane, H., Sasai, K. Effect of the Addition of Poly(D-lactic acid) on the Thermal Property of Poly(L-lactic acid), Polymer 2003, 44, 2569-2575.
  •  
  • 12. Anderson, K.; Hillmyer, M. Melt Preparation and Nucleation Efficiency of Polylactide Stereocomplex Crystallites. Polymer 2006, 47, 2030-2035.
  •  
  • 13. Yui, N.; Dijkstra, P. J.; Feijen, J. Stereo Block Copolymers of Land D-Lactides. Makromol. Chem. 1990, 191, 481-488.
  •  
  • 14. Hirata, M.; Kobayashi, K.; Kimura, Y. Synthesis and Properties of High-Molecular-Weight Stereo Di-Block Polylactides with Nonequivalent D/L Ratios. J. Polym. Sci., Part A: Polym. Chem. 2010, 48, 794-801.
  •  
  • 15. Karidi, K.; Mantourlias, T.; Seretis, A.; Pladis, P.; Kiparissides, C. Synthesis of High Molecular Weight Linear and Branched Polylactides: A Comprehensive Kinetic Investigation. Eur. Polym. J. 2015, 72, 114-128.
  •  
  • 16. Noda, M. Organotin(IV) Compounds as Intramolecular Transesterification Catalysts in Thermal Depolymerization of Poly(L-lactic acid) Oligomer to form Ll-lactide. Prep. Biochem. Biotechnol. 1999, 29, 333-338.
  •  
  • 17. Okihara, T.; Tsuji, M.; Kawaguchi, A.; Katayama, K.-I.; Tsuji, H.; Hyon, S.-H.; Ikada, Y. Crystal Structure of Stereocomplex of Poly(L-lactide) and Poly(D-lactide). J. Macromol. Sci. B. 1991, 30, 119-140.
  •  
  • 18. Bao, R.-Y.; Yang, W.; Jiang, W.-R.; Liu, Z.-Y.; Xie, B.-H.; Yang, M.-B.; Fu, Q. Stereocomplex Formation of High-molecular-weight Polylactide: A Low Temperature Approach. Polymer. 2012, 53, 5449-5454.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2023; 47(5): 643-649

    Published online Sep 25, 2023

  • 10.7317/pk.2023.47.5.643
  • Received on May 24, 2023
  • Revised on Jun 29, 2023
  • Accepted on Jun 29, 2023

Correspondence to

  • Kwan Han Yoon

  • **Department of Chemical Engineering, Kumoh National Institute of Technology, 1 Yangho-dong, Gumi 39177, Korea

  • E-mail: khyoon@kumoh.ac.kr