Article
  • Characteristic Variation of Ultraviolet-Cured Films on Structures and Molecular Weights of Photo-Reactive Acrylate and Methacrylate Monomers

  • Yunjeh Ko, Jong-Woo Won*, Jin-Sang Hwang*, and Oh Hyeong Kwon†

  • Department of Polymer Science and Engineering, Kumoh National Institute of Technology, Gumi, Gyeongbuk 39177, Korea
    *BNTM Corporation, Chilgok, Gyeongbuk 39850, Korea

  • 광반응성 아크릴레이트 및 메타아크릴레이트 단량체의 구조와 분자량에 따른 자외선 경화 필름의 특성 변화

  • 고윤제 · 원종우* · 황진상* · 권오형†

  • 금오공과대학교 고분자공학과, *비엔티엠

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Liang, H.; Ding J.; Shi, W. Kinetics and Mechanism of Thermal Oxidative Degradation of UV Cured Epoxy Acrylate/Phosphate Triacrylate Blends. Polym. Degrad. Stab. 2004, 86, 217-223.
  •  
  • 2. Khudyakov, I. V.; Swiderski, K. W.; Greer, R. W. Structure-Property Relations in UV-Curable Urethane Acrylate Oligomers. J. Appl. Polym. Sci. 2006, 99, 489-494.
  •  
  • 3. Hwang, J.-S.; Kim, M.-H.; Seo, D.-S.; Won, J.-W.; Moon, D.-K. Effects of Soft Segment Mixtures with Different Molecular Weight on the Properties and Reliability of UV Curable Adhesives for Electrodes Protection of Plasma Display Panel (PDP). Microelectron. Reliab. 2009, 49, 517-522.
  •  
  • 4. Dzunuzovic, E.; Tasic, S.; Bozic, B.; Babic, D.; Dunjic, B. UV-Curable Hyperbranched Urethane Acrylate Oligomers Containing Soybean Fatty Acids. Prog. Org. Coat. 2005, 52, 136-143.
  •  
  • 5. Patel, M. M.; Patel, C. J.; Patel, N. K. Study of Thermal Properties on UV-Curable Coatings Derived from Oleochemical Polyols. Chem. Sci. Trans. 2012, 1, 289-296.
  •  
  • 6. Cho, M.-J.; Kang, H.-J.; Kim, D.-B. Effects of the Rheological Properties of UV Cured Acrylic Pressure Sensitive Adhesive with Nano-particles on the Silk Screen Printing and Adhesion. J. Adhes. Interface 2017, 18, 25-32.
  •  
  • 7. Won, J.-W.; Kim, J.-Y.; Jang, K.-D.; Park, M.-C.; Chun, J. H.; Kwon, O. H.; Hwang, J.-S. Effects of Tri-Functional Monomers on the Properties of UV-Curable Pressure Sensitive Adhesives (PSAs), J. Adhes. Interface 2019, 20, 15-22.
  •  
  • 8. Hua, F. J.; Hu, C. P. Morphology and Mechanical Properties of Urethane Acrylate Resin Networks. J. Appl. Polym. Sci. 2000, 77, 1532-1537.
  •  
  • 9. Moon, B. J.; Hwang, S. H. Synthesis of UV-Curable Six-Functional Urethane Acrylates Using Pentaerytritol Triacrylate and Their Cured Film Properties. Polym. Korea 2011, 35, 183-188.
  •  
  • 10. Kwon, Y.; Cho, U. R. Study on the Improvement of Film Shrinkage in UV-Curing Process. Polym. Korea 2011, 35, 320-324.
  •  
  • 11. Yoo J. W.; Kim, D. S. UV Curing and Mechanical Properties of Urethane-Acrylate Resins, Polym. Korea 1999, 23, 376-383.
  •  
  • 12. Matynia, T.; Kutyłkea, R.; Bukat, K.; Pieńkowska, B. The Properties of Soldering Mask Hardened by Means of UV Using Acrylate and Methacrylate Oligomers. J. Appl. Polym. Sci. 1995, 55, 1583-1588.
  •  
  • 13. Bajpai, M.; Shukla, V.; Kumar, K. Film Performance and UV Curing of Epoxy Acrylate Resins. Prog. Org. Coat. 2002, 44, 271-278.
  •  
  • 14. Maruno, T.; Nakamura, K. Fluorine-Containing Optical Adhesives for Optical Communications Systems. J. Appl. Polym. Sci. 1991, 42, 2141-2148.
  •  
  • 15. Williams, T. R. Preparation and Morphology of a Silicone-Acrylate Copolymer System. J. Appl. Polym. Sci. 1986, 31, 1293-1308.
  •  
  • 16. Choi, M. J.; Jeong, B. Y.; Cheon, J. M.; Park, K.; Chun, J. H. Synthesis and Characterization of Waterborne Polyurethane for Water Resistance. J. Adhes. Interface 2017, 18, 8-12.
  •  
  • 17. Lee, J. H.; Hong, S.; Kim, Y. H. Synthesis and Characterization of Waterborne Polyurethanes Based on Isophorone Diisocyanate and Mixed Polyols of Poly(tetramethylene glycol)/Polydimethylsiloxane Diol. Polym. Korea 2013, 37, 167-176.
  •  
  • 18. Park, E.-S.; Hwang, H.-D.; Park, C.-H.; Lee, Y.-H.; Moon, J.-I.; Kim, H.-J. Synthesis and Curing Behavior of UV-Curable Polycarbonate-Based Polyurethane Methacrylate: Effect of Polyol Molecular Weight, Contents of Photoinitiator and Monomers on the Flexibility and Properties. J. Adhes. Interface 2011, 12, 47-55.
  •  
  • 19. Wang, H. S.; Lee, S. H.; Bu S. H.; Kim, H. D.; Song, K. Effect of Reactivity Ratio of Photoreactive Acrylate Monomers on Mechanical Properties of Cured Film. Polym. Korea 2020, 44, 384-390.
  •  
  • 20. Fang, Z. H.; Shang, J. J.; Huang, Y. X.; Wang, J.; Li, D. Q.; Liu, Z. Y. Preparation and Characterization of the Heat-Resistant UV Curable Waterborne Polyurethane Coating Modified by Bisphenol A. Express Polym. Lett. 2010, 4, 704-711.
  •  
  • 21. Noh, J.; Byeon, M.; Cho, T. Y.; Ham, D. S.; Cho, S.-K. Effect of Silane Coupling Agent on Adhesion Properties between Hydrophobic UV-Curable Urethane Acrylate and Acrylic PSA. Appl. Chem. Eng. 2020, 31, 230-236.
  •  
  • 22. Mun, S. Y.; Jung, M. C.; Kim, Y. H. Property Changes of the Waterborne Polyurethane Films Synthesized from Polytetramethylene Ether Glycol and Polycarbonate Diol Due to Hydrolysis. Polym. Korea 2017, 41, 546-553.
  •  
  • 23. Luo, Q.; Wen, X.; Xu, R.; Liu, Z.; Xiang, H.; Li, Z.; Liu, X. Preparation and Properties of Novel Modified Waterborne Polyurethane Acrylate, Coatings 2022, 12, 1135.
  •  
  • 24. Thiher, N. L. K.; Schissel, S. M.; Jessop, J. L. P. The Influence of Monomer Chemistry on Radical Formation and Secondary Reactions During Electron-Beam Polymerization. J. Polym. Sci. 2020, 58, 1011-1021.
  •  
  • 25. Takács, E.; Wojnárovits, L. Comparison of the Reactivity of Acrylate and Methacrylate Monomers. Radiat. Phys. Chem. 1995, 46, 1007-1010.
  •  
  • 26. Choe, Y.; Ryu, B. K. Photopolymerization of Reactive Oligomers and Methacrylate/SBS Blends. Polym. Korea 2003, 27, 421-428.
  •  
  • 27. Kim, B.; Seo, D. H.; Chae, H.-S.; Shin, S. Determination of Processing Parameters Affecting the Conversion and Thermal Stability of Photocurable Acrylate-Based Binder, Appl. Chem. Eng. 2012, 23, 18-22.
  •  
  • 28. Shan, L.; Verghese, K. N. E.; Robertson, C. G.; Reifsnider, K. L. Effect of Network Structure of Epoxy DGEBA-Poly(oxypropylene) Diamines on Tensile Behavior, J. Polym. Sci. B Polym. Phys. 1999, 37, 2815-2819.
  •  
  • 29. Hwang, J. S.; Yim, M. J.; Paik, K. W. Effects of Epoxy Functionality on the Properties and Reliability of the Anisotropic Conductive Films for Flip Chips on Organic Substrates. J. Electron. Mater. 2006, 35, 1722-1727.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2023; 47(3): 332-339

    Published online May 25, 2023

  • 10.7317/pk.2023.47.3.332
  • Received on Jan 7, 2023
  • Revised on Feb 2, 2023
  • Accepted on Feb 5, 2023

Correspondence to

  • Oh Hyeong Kwon

  • Department of Polymer Science and Engineering, Kumoh National Institute of Technology, Gumi, Gyeongbuk 39177, Korea

  • E-mail: ohkwon@kumoh.ac.kr