Article
  • Effect of Halloysite Nanotubes (HNTs) on Mechanical Properties of EPDM/NBR Blend-Nanocomposites
  • Raj Kishor Das, K. Ragupathy*,† , T. Senthil Kumar**, and S. Vishvanathperumal***

  • Department of Mechanical Engineering, Hi-Tech Institute of Technology, Khurda, Odisha 752057, India
    *Department of Mechanical and Automation Engineering, Agni College of Technology, Chennai - 600130, India
    **Department of English, S.A. Engineering College, Thiruverkadu, Chennai, Tamilnadu - 600077, India
    ***Department of Mechanical Engineering, S.A. Engineering College, Thiruverkadu, Chennai, Tamilnadu - 600077, India

  • EPMD/NBR 나노복합체의 기계적 물성에 Halloysite Nanotube(HNT)가 미치는 영향 연구
  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Vishvanathperumal, S.; Gopalakannan, S. Reinforcement of Ethylene Vinyl Acetate with Carbon Black/silica Hybrid Filler Composites. Appl. Mechanics Mater. 2016, 852, 16-22.
  •  
  • 2. Nugay, N.; Erman, B. Property Optimization in Nitrile Rubber Composites via Hybrid Filler Systems. J. Appl. Polym. Sci. 2001, 79, 366-371.
  •  
  • 3. Vishvanathperumal, S.; Gopalakannan, S. Effects of the Nanoclay and Crosslinking Systems on the Mechanical Properties of Ethylene-propylene-diene Monomer/styrene Butadiene Rubber Blends Nanocomposite. Silicon, 2019, 11, 117-135.
  •  
  • 4. Usuki, A.; Kawasumi, M.; Kojima, Y.; Okada, A.; Kurauchi, T.; Kamigaito, O. Swelling Behavior of Montmorillonite Cation Exchanged for ω-amino Acids by ϵ-caprolactam. J. Mater. Res. 1993, 8, 1174-1178.
  •  
  • 5. Munusamy, Y.; Ismail, H.; Mariatti, M.; Ratnam, C. T. Ethylene Vinyl Acetate/natural Rubber/organoclay Nanocomposites: Effect of Sulfur and Peroxide Vulcanization. J. Reinf. Plast. Compos. 2008, 27, 1925-1945.
  •  
  • 6. Vishvanathperumal, S.; Navaneethakrishnan, V.; Gopalakannan, S. The Effect of Nanoclay and Hybrid Filler on Curing Characteristics, Mechanical Properties and Swelling Resistance of Ethylene-vinyl Acetate/styrene Butadiene Rubber Blend Composite. J. Adv. Microsc. Res. 2018, 13, 469-476.
  •  
  • 7. Shanmugharaj, A. M.; Bae, J. H.; Lee, K. Y.; Noh, W. H.; Lee, S. H.; Ryu, S. H. Physical and Chemical Characteristics of Multiwalled Carbon Nanotubes Functionalized with Aminosilane and Its Influence on the Properties of Natural Rubber Composites. Compos. Sci. Technol. 2007, 67, 1813-1822.
  •  
  • 8. Ismail, H.; Salleh, S. Z.; Ahmad, Z. Properties of Halloysite Nanotubes-filled Natural Rubber Prepared Using Different Mixing Methods. Mater. Des. 2013, 50, 790-797.
  •  
  • 9. Zhong, B.; Jia, Z.; Hu, D.; Luo, Y.; Guo, B.; Jia, D. Surface Modification of Halloysite Nanotubes by Vulcanization Accelerator and Properties of Styrene-butadiene Rubber Nanocomposites with Modified Halloysite Nanotubes. Appl. Surf. Sci. 2016, 366, 193-201.
  •  
  • 10. Guo, B.; Lei, Y.; Chen, F.; Liu, X.; Du, M.; Jia, D. Styrene-butadiene Rubber/halloysite Nanotubes Nanocomposites Modified by Methacrylic Acid. Appl. Surf. Sci. 2008, 5, 2715-2722.
  •  
  • 11. Yang, S.; Zhou, Y.; Zhang, P.; Cai, Z.; Li, Y.; Fan, H. Preparation of High Performance NBR/HNTs Nanocomposites Using an Electron Transferring Interaction Method. Appl. Surf. Sci. 2017, 425, 758-764.
  •  
  • 12. Pasbakhsh, P.; Ismail, H.; Fauzi, M. N. A.; Abu Bakar, A. EPDM/Modified Halloysite Nanocomposites. Appl. Clay Sci. 2010, 48, 405-413.
  •  
  • 13. Ismail, H.; Pasbakhsh, P.; Fauzi, M. N. A.; Abu Bakar, A. Morphological, Thermal and Tensile Properties of Halloysite Nanotubes Filled Ethylene Propylene Diene Monomer (EPDM) Nanocomposites. Polym. Test. 2008, 27, 841-850.
  •  
  • 14. Berahman, R.; Raiati, M.; Mazidi, M. M.; Paran, S. M. R. Preparation and Characterization of Vulcanized Silicone Rubber/halloysite Nanotube Nanocomposites: Effect of Matrix Hardness and HNT Content. Mater. Des. 2016, 104, 333-345.
  •  
  • 15. Liu, M.; Guo, B.; Du, M.; Jia, D. Drying Induced Aggregation of Halloysite Nanotubes in Polyvinyl Alcohol/halloysite Nanotubes Solution and its Effect on Properties of Composite Film. Appl. Phys. A 2007, 88, 391-395.
  •  
  • 16. Joussein, E.; Petit, S.; Churchman, G. J.; Theng, B. K. G.; Righi, D.; Delvaux, B. Halloysite Clay Minerals - A Review. Clay Miner. 2005, 40, 383-426.
  •  
  • 17. Levis, S. R.; Deasy, P. B. Characterisation of Halloysite for Use as a Microtubular Drug Delivery System. Int. J. Pharm. 2007, 243, 125-134.
  •  
  • 18. Ye, Y.; Chen, H.; Wu, J.; Ye, L. High Impact Strength Epoxy Nanocomposites with Natural Nanotubes. Polym. 2007, 48, 6426-6433.
  •  
  • 19. Liu, M.; Jia, Z.; Jia, D.; Zhou, C. Recent Advance in Research on Halloysite Nanotubes-polymer Nanocomposite. Prog. Polym. Sci. 2014, 39, 1498-1525.
  •  
  • 20. Yuan, P.; Tan, D.; Annabi-Bergaya, F. Properties and Applications of Halloysite Nanotubes: Recent Research Advances and Future Prospects. Appl. Clay Sci. 2015, 112, 75-93.
  •  
  • 21. Tan, D.; Yuan, P.; Liu, D.; Du, P. Surface Modifications of Halloysite. Dev. Clay Sci. 2016, 7, 167-201.
  •  
  • 22. Lvov, Y.; Abdullayev, E. Functional Polymer–clay Nanotube Composites with Sustained Release of Chemical Agents. Prog. Polym. Sci. 2013, 38, 1690-1719.
  •  
  • 23. Duce, C.; Ciprioti, S. V.; Ghezzi, L.; Ierardi, V.; Tinè, M. R. Thermal Behavior Study of Pristine and Modified Halloysite Nanotubes. J. Therm. Anal. Calorim. 2015, 121, 1011-1019.
  •  
  • 24. Rawtani, D.; Agrawal, Y. K. Halloysite as Support Matrices: A Review. Emerg. Mater. Res. 2012, 1, 212-220.
  •  
  • 25. Findik, F.; Yilmaz, R.; Koksal, T. Investigation of Mechanical and Physical Properties of Several Industrial Rubbers. Mater. Des. 2004, 25, 269-276.
  •  
  • 26. Vishvanathperumal, S.; Anand, G. Effect of Nanosilica and Crosslinking System on the Mechanical Properties and Swelling Resistance of EPDM/SBR Nanocomposites with and Without TESPT. Silicon, 2021, 13, 3473-3497.
  •  
  • 27. Shokri, A. A.; Bakhshandeh, G.; Farahani, T. G. An Investigation of Mechanical and Rheological Properties of NBR/PVC Blends: Influence of Anhydride Additives, Mixing Procedure and NBR Form. Iran. Polym. J. 2006, 15, 227-237.
  •  
  • 28. Vishvanathperumal, S.; Navaneethakrishnan, V.; Anand, G.; Gopalakannan, S. Evaluation of Crosslink Density Using Material Constants of Ethylene-Propylene-Diene Monomer/Styrene-Butadiene Rubber with Different Nanoclay Loading: Finite Element Analysis-Simulation and Experimental. Advanced Science, Eng. Medicine, 2020, 12, 632-642.
  •  
  • 29. Ismail, H.; Jaffri, R. M.; Rozman, H. D. The Effects of Filler Loading and Vulcanization System on Properties of Oil Palm Wood Flour-Natural Rubber Composites. J. Elastom. Plast. 2003, 35, 181-192.
  •  
  • 30. Mohamed, G. M.; Abd-El-Messieh, S. L.; El-Sabbagh, S. H.; Younan, A. F. Electrical and Mechanical Properties of Polyethylene Rubber Blends. J. Appl. Polym. Sci. 1998, 69, 775-783.
  •  
  • 31. El-Nashar, D. E.; Turky, G. Effect of Mixing Conditions and Chemical Cross Linking Agents on the Physicomechanical and Electrical Properties of NR/NBR Blends. Polym. Plast. Technol. Eng. 2003, 42, 269-284.
  •  
  • 32. Jovanovic, V.; Jovanovic, S. S.; Simendic, J. B.; Markovic, G.; Cincovic, M. M. Composites Based on Carbon Black Reinforced NBR/EPDM Rubber Blends. Compos. B 2013, 45, 333-340.
  •  
  • 33. Kucukpinar, E.; Doruker, P. Molecular Simulations of Gas Transport in Nitrile Rubber and Styrene Butadiene Rubber. Polymer, 2006, 47, 7835-7845.
  •  
  • 34. Botros, S. H.; Tawfic, M. L. Synthesis and Characteristics of MAH-g-EPDM Compatibilized EPDM/NBR Rubber Blends. J. Elastomers & Plastics, 2006, 38, 349-365.
  •  
  • 35. Jovanović, V.; Samaržija-Jovanović, S.; Budinski-Simendić, J.; Marković, G.; Marinović-Cincović, M. Composites Based on Carbon Black Reinforced NBR/EPDM Rubber Blends. Compos. Part B: Eng., 2013, 45, 333-340.
  •  
  • 36. Manoj, K. C.; Unnikrishnan, G. Cure Characteristics, Morphology and Mechanical Properties of Ethylene–propylene–diene–monomer Rubber/Acrylonitrile Butadiene Rubber Blends. J. Appl. Polym. Sci. 2007, 105, 908-914.
  •  
  • 37. El-Gamal, A. A.; Alsuhaiqi, H. M.; Hassan, H. H. Effect of Compression Pressure on the Ethylene Propylene Diene Terpolymer (EPDM)/acrylonitrile Butadiene Copolymer (NBR) Rubber Blends Filled with Different Types of Carbon Black. J. Macromol. Sci. B: Phys. 2017, 56, 697-708.
  •  
  • 38. Ashok, N.; Webert, D.; Suneesh, P. V.; Balachandran, M. Mechanical and Sorption Behaviour of Organo-modified Montmorillonite Nanocomposites Based on EPDM - NBR Blends. Materials Today: Proceedings 2018, 5, 16132-16140.
  •  
  • 39. Basha, S. K. T.; Divya, R.; Menon, A. U.; Ashok, N.; Balachandran, M. Cure and Degradation Kinetics of Sulfur Cured Nanocomposites of EPDM-NBR Rubber Blends. Materials Today: Proceedings, 2018, 5, 23586-23595.
  •  
  • 40. Ersali, M.; Fazeli, N.; Gh. Naderi, Preparation and Properties of EPDM/NBR/Organoclay Nanocomposites. Int. Polym. Process. 2012, 27, 187-195.
  •  
  • 41. Jovanović, S. S.; Jovanović, V.; Marković, G.; Konstantinović, S.; Cincović, M. M. Nanocomposites Based on Silica-reinforced Ethylene–propylene–diene–monomer/acrylonitrile–butadiene Rubber Blends. Compos. B: Eng. 2011, 42, 1244-1250.
  •  
  • 42. Hoikkanen, M.; Poikelispää, M.; Das, A.; Honkanen, M.; Dierkes, W.; Vuorinen, J. Effect of Multiwalled Carbon Nanotubes on the Properties of EPDM/NBR Dissimilar Elastomer Blends. Polym. Plast. Technol. Eng. 2015, 54, 402-410.
  •  
  • 43. Sundar, R.; Mohan, S. K.; Vishvanathperumal, S. Effect of Surface Modified Halloysite Nanotubes (mHNTs) on the Mechanical Properties and Swelling Resistance of EPDM/NBR Nanocomposites. Polymer Korea, 2022, 46, 728-743.
  •  
  • 44. Prasertsri, S.; Saehan, E.; Nuinu, P. Mechanical Properties, Oil and Ozone Resistance of EPDM/NBR Blends Filled with Hybrid Fillers for Fuel Tank Rubber-Cover Applications. Burapha Sci. J., 2021, 26, 71-89.
  •  
  • 45. Manoj, K. C.; Unnikrishnan, G. Cure Characteristics, Morphology, and Mechanical Properties of Ethylene–propylene–diene–monomer Rubber/acrylonitrile Butadiene Rubber Blends. J. Appl. Polym. Sci. 2007, 105, 908-914.
  •  
  • 46. Manoj, K. C.; Kumari, P.; Rajesh, C.; Unnikrishnan, G. Aromatic Liquid Transport Through Filled EPDM/NBR Blends. J. Polym. Res. 2010, 17, 1-9.
  •  
  • 47. Manoj, K. C.; Kumari, P.; Unnikrishnan, G. Cure Characteristics, Swelling Behaviors, and Mechanical Properties of Carbon Black Filler Reinforced EPDM/NBR Blend System. J. Appl.Polym. Sci. 2011, 120, 2654-2662.
  •  
  • 48. Ersali, M.; Fazeli, N.; Naderi, G. Preparation and Properties of EPDM/NBR/organoclay Nanocomposites. Int. Polym. Proc., 2012, 27, 187-195.
  •  
  • 49. Oliveira, M. G.; Gomes, A. C.; Almeida, M. S.; Soares, B. G. Reactive Compatibilization of NBR/EPDM Blends by the Combination of Mercapto and Oxazoline Groups. Macromol. Chem. Phys. 2004, 205, 465-475.
  •  
  • 50. Theja, R.; Kilari, N.; Vishvanathperumal, S.; Navaneethakrishnan, V. Modeling Tensile Modulus of Nanoclay-filled Ethylene–propylene–diene Monomer/styrene–butadiene Rubber Using Composite Theories. J. Rubber Res. 2021, 24, 847-856.
  •  
  • 51. Anand, G.; Vishvanathperumal, S. Properties of SBR/NR Blend: The Effects of Carbon Black/Silica (CB/SiO2) Hybrid Filler and Silane Coupling Agent. Silicon, 2022, 14, 9051-9060.
  •  
  • 52. Vishvanathperumal, S.; Anand, G. Effect of Nanosilica on the Mechanical Properties, Compression Set, Morphology, Abrasion and Swelling Resistance of Sulphur Cured EPDM/SBR Composites. Silicon, 2022, 14, 3523-3534.
  •  
  • 53. Manoj, K. C.; Kumari, P.; Rajesh, C.; Unnikrishnan, G. Aromatic Liquid Transport Through Filled EPDM/NBR Blends. J. Polym. Res. 2010, 17, 1-9.
  •  
  • 54. Flory, P. J.; Rehner, J. Statistical Mechanics of Cross-Linked Polymer Networks I. Rubberlike Elasticity. J. Chem. Phys. 1943, 11, 512.
  •  
  • 55. Sujith, A.; Unnikrishnan, G. Molecular Sorption by Heterogeneous Natural Rubber/poly(ethylene-co-vinylacetate) Blend Systems. J. Polym. Res. 2006, 13, 171-180.
  •  
  • 56. Thomas, P. C.; Tomlal, J. E.; Selvin T. P.; Thomas, S.; Joseph, K. High-performance Nanocomposites Based on Arcylonitrile-butadiene Rubber with Fillers of Different Particle Size: Mechanical and Morphological Studies. Polym. Compos. 2010, 31, 1515-1524.
  •  
  • 57. Vishvanathperumal, S.; Anand, G. Effect of Nanoclay/nanosilica on the Mechanical Properties, Abrasion and Swelling Resistance of EPDM/SBR Composites. Silicon, 2020, 12, 1925-1941.
  •  
  • 58. Frohlich, J.; Niedermeir, W.; Luginsland, H. D. The Effect of Filler–filler and Filler–elastomer Interaction on Rubber Reinforcement. Compos. A: Appl. Sci. Manuf. 2005, 36, 449-460.
  •  
  • 59. Wang, M. Toughness Characteristics of Synthetic Fibre-reinforced Cementitious Composites. Fatigue Fract. Eng. M. 1998, 21, 521-532.
  •  
  • 60. Vishvanathperumal, S.; Gopalakannan, S. Swelling Properties, Compression Set Behavior and Abrasion Resistance of Ethylene-propylene-diene Rubber/styrene-butadiene Rubber Blend Nanocomposites. Polym. Korea 2017, 41, 433-442.
  •  
  • 61. Jacques, J. E. Rubber Technology and Manufacture. In Rubber Compounding, 2nd ed.; Blow, C. M.; Hepburn, C., Eds.; Butterworths: London, 1985; pp 386-387.
  •  
  • 62. Ganeche, P. S.; Balasubramanian, P.; Vishvanathperumal, S. Halloysite Nanotubes (HNTs)-filled Ethylene-propylene-diene Monomer/styrene-butadiene Rubber (EPDM/SBR) Composites: Mechanical, Swelling, and Morphological Properties. Silicon, 2022, 14, 6611-6620.
  •  
  • 63. Rooj, S.; Das, A.; Thakur, V.; Mahaling, R. N.; Bhowmick, A. K.; Heinrich, G. Preparation and Properties of Natural Nanocomposites Based on Natural Rubber and Naturally Occurring Halloysite Nanotubes, Mater. Des. 2010, 31, 2151-2156.
  •  
  • 64. Zhong, B.; Dong, H.; Lin, J.; Jia, Z.; Luo, Y.; Jia, D.; Liu, F. Preparation of Halloysite Nanotubes-Silica Hybrid Supported Vulcanization Accelerator for Enhancing Interfacial and Mechanical Strength of Rubber Composites. Ind. Eng. Chem. Res. 2017, 56, 9135-9142.
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  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2023; 47(2): 221-232

    Published online Mar 25, 2023

  • 10.7317/pk.2023.47.2.221
  • Received on Dec 2, 2022
  • Revised on Jan 25, 2023
  • Accepted on Jan 30, 2023

Correspondence to

  • K. Ragupathy
  • Department of Mechanical and Automation Engineering, Agni College of Technology, Chennai - 600130, India

  • E-mail: ragupathy86@gmail.com