Article
  • Non-isothermal Crystallization of Poly(3-hydroxybutyrate-co-4-hydroxybutyrate)

  • Soomi Kwon, Tao Zhang, Yunjae Jang*, Minho Jung*, Eunhye Lee*, and Ho-Jong Kang†

  • Department of Polymer Science and Engineering, Dankook University, 152 Jukjeon-ro, Suji-gu, Yongin-si, Gyeonggi-do 16890, Korea
    *CJ Cheiljedang Corp. 55, Gwanggyo-ro 42beon-gil, Yeongtong-gu, Suwon-si, Gyeonggi-do 16495, Korea

  • Poly(3-hydroxybutyrate-co-4-hydroxybutyrate) 비등온 결정화 거동

  • 권수미 · 장타오 · 장윤재* · 정민호* · 이은혜* · 강호종†

  • 단국대학교 고분자공학과, *CJ 제일제당

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Chanprateep, S.; Buasri, K.; Muangwong, A.; Utiswannakul, U. Biosynthesis and Biocompatibility of Biodegradable Poly(3-hydroxybutyrate-co-4-hydroxybutyrate). Polym. Degrad. Stab. 2010, 95, 2003-2012.
  •  
  • 2. Ramachandran, H.; Amirul, A. A. Evaluation of Unrefined Glycerine Pitch as an Efficient Renewable Carbon Resource for the Biosynthesis of Novel Yellow-pigmented P(3HB-co-4HB) Copolymer Towards Green Technology. Biotechnol. Bioprocess Eng. 2013, 18, 1250-1257.
  •  
  • 3. Guerra-Blanco, P.; Cortes, O.; Poznyak, T.; Chairez, I.; García-Peñ, E. I. Polyhydroxyalkanoates (PHA) Production by Photo- heterotrophic Microbial Consortia: Effect of Culture Conditions Over Microbial Population and Biopolymer Yield and Composition. Eur. Polym. J. 2018, 98, 94-104.
  •  
  • 4. Conti, D. S.; Pezzin, S. H.; Ferreira, L. A.; Coelho, L. A. F. Mechanical and Morphological Properties of Poly(3-hydroxy- butyrate)/Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Blends. Macromol. Symp. 2006, 245-246, 491-500.
  •  
  • 5. Wellen, R. M. R.; Rabello, M. S.; Araufo Jr., I. C.; Fechine, G. J. M.; Canedo, E. Melting and Crystallization of Poly(3-hydroxy- butyrate): Effect of Heating/Cooling Rates on Phase Transformation. Polímeros 2015, 25, 296-304.
  •  
  • 6. Gopi, S.; Kontopoulou, M.; Ramsay, B. A.; Ramsay, A. J. Manipulating the Structure of Medium-chain-length Polyhydroxy- alkanoate (MCL-PHA) to Enhance Thermal Properties and Crystallization Kinetics. Int. J. Biol. Macromol. 2018, 119, 1248-1255.
  •  
  • 7. Lu, X. P.; Wen, X.; Yang, D. Isothermal Crystallization Kinetics and Morphology of Biodegradable Poly(3-hydroxybutyrate-co-4-hydroxybutyrate). J. Mater. Sci. 2011, 46, 1281-1288.
  •  
  • 8. Li, H. Y.; Lu, X. P.; Yang, H.; Hu, J. W. Non-isothermal Crystallization of P(3HB-co-4HB)/PLA Blends. J. Therm. Anal. Calorim. 2015, 122, 817-829.
  •  
  • 9. Volova, T. G.; Shumilova, A. A.; Nikolaeva, E. D.; Kirichenko, A. K.; Shishatskaya, E. I. Biotechnological Wound Dressings Based on Bacterial Cellulose and Degradable Copolymer P(3HB/4HB). Int. J. Biol. Macromol. 2019, 131, 230-240.
  •  
  • 10. Cai, Z. J.; Hou, C. W.; Yang, G. Poly(3-hydroxubutyrate-co-4-hydroxubutyrate)/Bacterial Cellulose Composite Porous Scaffold: Preparation, Characterization and Biocompatibility Evaluation. Carbohydr. Polym. 2012, 87, 1073-1080.
  •  
  • 11. García-Quiles, L.; Cuello, A. F.; Castell, P. Sustainable Materials with Enhanced Mechanical Properties Based on Industrial Polyhydroxyalkanoates Reinforced with Organomodified Sepiolite and Montmorillonite. Polymers 2019, 11, 696-714.
  •  
  • 12. Qian, J.; Zhu, L. Y.; Zhang, J. W.; Whitehouse, R. S. Comparison of Different Nucleating Agents on Crystallization of Poly(3-hydroxybutyrate-co-3-hydroxyvalerates). J. Polym. Sci. B: Polym. Phys. 2007,45, 1564-1577.
  •  
  • 13. Che, X. M.; Ye, H. M.; Chen, G. Q. Effects of Uracil on Crystallization and Rheological Property of Poly(R-3-hydroxy- butyrate-co-4-hydroxybutyrate). Composites A: Appl. Sci. Manuf. 2018, 109, 141-150.
  •  
  • 14. White, J. L. Structure Development in Polymer Processing. Pure Appl. Chem. 1983, 55, 765-776.
  •  
  • 15. Mandelkern, L. Crystallization of Polymers: Volume 2, Kinetics and Mechanisms, 2nd Edition Cambridge University Pressm 2004.
  •  
  • 16. Avrami, M. Kinetics of Phase Change. I General Theory. J. Chem. Phys. 1938, 7, 1103-1112.
  •  
  • 17. Jeziorny A. Parameters Characterizing the Kinetics of the Non-isothermal Crystallization of Poly(ethylene terephthalate) Determined by DSC. Polymer 1987, 19, 1142-1144.
  •  
  • 18. Ozawa, T. Kinetics of Non-isothermal Crystallization. Polymer 1971, 12, 150-158.
  •  
  • 19. Liu T. X.; Mo, Z. S.; Wang, S. G.; Zhang, H. F. Nonisothermal Melt and Cold Crystallization Kinetics of Poly(aryl ether ether ketone ketone). Polym. Eng. Sci. 1997, 37, 568-575.
  •  
  • 20. Flynn, J. H.; Wall, L. A. A Quick, Direct Method for the Determination of Activation Energy from Thermogravimetric Data. J. Polym. Sci. Part B: Polym. Lett. 1966, 4, 323-328.
  •  
  • 21. Evans, U. R. The Laws of Expanding Circles and Spheres in Relations to the Lateral Growth of Surface Films and the Grain-size of Metals. Trans. Faraday Soc. 1945, 41, 365-374.
  •  
  • 22. Kunioka, M.; Doi, Y. Thermal Degradation of Microbial Copolyesters: Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and Poly(3-hydroxybutyrate-co-4-hydroxybutyrate). Macromolecules 1990, 23, 1933-1936.
  •  
  • 23. Kim, K. J.; Doi, Y.; Abe, H.; Martin, D. P. Thermal Degradation Behavior of Poly(4-hydroxybutyric acid). Polym. Degrad. Stab. 2006, 91, 2333-2341.
  •  
  • 24. Omura, T.; Goto, T.; Maehara, A.; Kimura, S.; Abe, H.; Iwata, T. Thermal Degradation Behavior of Poly[(R)-3-hydroxybutyrate-co-4-hydroxybutyrate]. Polym. Degrad. Stab. 2021, 183, 109460-109468.
  •  
  • 25. Bian, Y. J.; Han, L. J.; Han, C. Y.; Lin, H. J.; Zhang, H. L.; Biana, J. J.; Dong, L. S. Intriguing Crystallization Behavior and Rheological Properties of Radical-based Crosslinked Biodegradable Poly(3-hydroxybutyrate-co-4-hydroxybutyrate). CrystEngComm 2014, 16, 2702-2714.
  •  
  • 26. Xu, P. X.; Zhang, C.; Qi, G. P.; Yang, W. J.; Ma, P. M. Morphology and Crystallization Kinetics of Regime Transition for Biosynthesized Polyhydroxyalkanoate. J. Polym. Res. 2022,29, 140-145.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2022; 46(5): 661-670

    Published online Sep 25, 2022

  • 10.7317/pk.2022.46.5.661
  • Received on May 28, 2022
  • Revised on Jun 29, 2022
  • Accepted on Jun 30, 2022

Correspondence to

  • Ho-Jong Kang

  • Department of Polymer Science and Engineering, Dankook University, 152 Jukjeon-ro, Suji-gu, Yongin-si, Gyeonggi-do 16890, Korea

  • E-mail: hjkang@dankook.ac.kr