Article

Reproducible Green Radiation-based Synthesis of Poly(glycidyl methacrylate)-Grafted Non-woven Polypropylene Adsorbent for Removal of a Heavy Metal Ion
In-Tae Hwang^*, Tae-Yeon Kim^{*, **}, Joon-Yong Sohn^*, Kwanwoo Shin^**, Junhwa Shin^*, and Chan-Hee Jung^*,†
*Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, Jeongeup, Jeollabuk-do 56212, Korea
**Department of Chemistry, Sogang University, Mapo-gu, Seoul 04107, Korea
중금속 이온 제거를 위한 재현성 있는 친환경 방사선 기반의 폴리글리시딜메타크릴레이트 접목 폴리프로필렌 부직포 흡착제의 합성
황인태^* · 김태연^{*, **} · 손준용^* · 신관우^** · 신준화^* · 정찬희^*,†
*한국원자력연구원 첨단방사선연구소, **서강대학교 화학과
Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References

1. Pang, Y.; Zeng, G.; Tang, L.; Zhang, Y.; Liu, Y.; Lei, X.; Li, Z.; Zhang, J.; Xie, G. PEI-grafted Magnetic Porous Powder for Highly Effective Adsorption of Heavy Metal Ions. Desalination 2011,281, 278-284.
2. Kavakli, P. A.; Korpayev, S.; Kavakli, C.; Tilki, S. Novel Cotton Fabric Adsorbent for Efficient As (V) Adsorption. Environ. Sci. Pollut. Res. 2018, 25, 34610-34622.
3. Zhang, M.; Gao, Q.; Yang, C.; Pang, L.; Wang, H.; Li, H.; Li, R.; Xu, L.; Hu, J.; Wu, G. Preparation of Amidoxime-based Nylon-66 Fibers for Removing Uranium from Low-concentration Aqueous Solutions and Simulated Nuclear Industry Effluents. Ind. Eng. Chem. Res. 2016, 55, 10523-10532.
4. Cheballah, K.; Sahmoune, A.; Messaoudi, K.; Drouiche, N.; Lounici, H. Simultaneous Removal of Hexavalent Chromium and COD from Industrial Wastewater by Bipolar Electrocoagulation. Chem. Eng. Process. 2015, 96, 94-99.
5. Coelho, G. F.; Jr, A. C. G.; Tarley, C. R. T.; Casarin, J.; Nacke, H.; Francziskowski, M. A. Removal of Metal Ions Cd II, Pb II, and Cr III from Water by the Cashew Nut Shell Anacardium Occidentale L. Ecol. Eng. 2014, 73, 514-525.
6. Shannag, M. A.; Qodah, Z. A.; Melhem, K. B.; Otaishat, M. R.; Alkasrawi, M. Heavy Metal Ions Removal from Metal Plating Wastewater Using Electrocoagulation: Kinetic Study and Process Performance. Chem. Eng. J. 2015, 260, 749-756.
7. Salehizadeh, H.; Shojaosadati, S. A. Removal of Metal Ions from Aqueous Solution by Polysaccharide Produced from Bacillus Firmus. Water Res. 2003, 37, 4231-4235.
8. Anirudhan, T. S.; Nima, J.; Divya, P. L. Adsorption of Chromium VI from Aqueous Solutions by Glycidyl Methacrylate-grafted-densified Cellulose with Quaternary Ammonium Groups. Appl. Surf. Sci. 2013, 279, 441-449.
9. Yang, Y.; Ma, N.; Zhang, Q.; Chen, S. Adsorption of Hg²⁺ on a Novel Chelating Fiber Prepared by Preirradiation Grafting and Amination. J. Appl. Polym. Sci. 2009, 113, 3638-3645.
10. Neghlani, P. K.; Rafizadeh, M.; Taromi, F. A. Preparation of Aminated-polyacrylonitrile Nanofiber Membranes for the Ad- sorption of Metal Ions: Comparison with Microfibers. J. Hazard. Mater. 2011, 186, 182-189.
11. Dafader, N. C.; Rahman, N.; Majumdar, S. K.; Khan, M. M. R.; Rahman, M. M. Preparation and Characterization of Imino- diacetate Group Containing Nonwoven Polyethylene Fabrics and Its Application in Chromium Adsorption. J. Polym. Environ. 2018, 26, 740-748.
12. Chen, L.; Yang, G.; Zhang, J. A study on the Exchange Kinetics of Ion-exchange Fiber. React. Funct. Polym. 1996, 29, 139-144.
13. Zeng, Z.; Wei, Y.; Shen, L.; Hua, D. Cationically Charged Polyamidoxime-grafted Polypropylene Nonwoven Fabric for Potential Uranium Extraction from Seawater. Ind. Eng. Chem. Res. 2015, 54, 8699-8705.
14. Nasef, M. M.; Ting, T. M.; Abbasi, A.; Moghaddam, A. L.; Alinezhad, S. S.; Hashim, K. Radiation Grafted Adsorbents for Newly Emerging Environmental Applications. Radiat. Phys. Chem. 2016, 118, 55-60.
15. Zhu, Y.; Wei, J.; Zhang, H.; Liu, K.; Kong, Z.; Dong, Y.; Jin, G.; Tian, J.; Qin, Z. Fabrication of Composite Membrane with Adsorption Property and Its Application to the Removal of Endocrine Disrupting Compounds During Filtration Process. Chem. Eng. J. 2018, 352, 53-63.
16. Nasef, M. M.; Güven, O. Radiation-grafted Copolymers for Separation and Purification Purposes: Status, Challenges and Future Directions. Prog. Polym. Sci. 2012, 37, 1597-1656.
17. Kavakli, P. A.; Seko, N.; Tamada, M.; Guven, O. Radiation-induced Graft Polymerization of Glycidyl Methacrylate onto PE/PP Nonwoven Fabric and Its Modification toward Enhanced Amidoximation. J. Appl. Polym. Sci. 2007, 150, 1551-1558.
18. Chen, K. S.; Tsai, J. C.; Chou, C. W.; Yang, M. R.; Tang, J. M. Effects of Additives on the Photo-induced Grafting Polymeri- zation of N-isopropylacrylamide Gel onto PET Film and PP Nonwoven Fabric Surface. Mater. Sci. Eng. C 2002, 20, 203-208.
19. Chen, J. P.; Chiang, Y. P. Surface Modification of Non-woven Fabric by DC Pulsed Plasma Treatment and Graft Polymerization with Acrylic Acid. J. Membr. Sci. 2006, 270, 212-220.
20. Chern, C. S. Emulsion Polymerization Mechanisms and Kinetics. Prog. Polym. Sci. 2006, 31, 443-486.
21. Omichi, M.; Ueki, Y.; Seko, N.; Maekawa, Y. Development of a Simplified Radiation-Induced Emulsion Graft Polymerization Method and Its Application to the Fabrication of a Heavy Metal Adsorbent. Polymers 2019, 11, 1373.
22. Madrid, J. F.; Ueki, Y.; Seko, N. Abaca/polyester Nonwoven Fabric Functionalization for Metal Ion Adsorbent Synthesis Via Electron Beam-induced Emulsion Grafting. Radiat. Phys. Chem. 2013, 90, 104-110.
23. Madrid, J. F.; Lopez, G. E. P.; Abad, L. V. Application of Full-factorial Design in the Synthesis of Polypropylene-g-polyglycidyl Methacrylate Functional Material for Metal Ion Adsorption. Radiat. Phys. Chem. 2017, 136, 54-63.
24. Sekine, A.; Seko, N.; Tamada, M.; Suzuki, Y. Biodegradable Metal Adsorbent Synthesized by Graft Polymerization onto Nonwoven Cotton Fabric. Radiat. Phys. Chem. 2010, 79, 16-21.
25. Liu, X.; Liu, H.; Ma, H.; Cao, C.; Yu, M.; Wang, Z.; Deng, B.; Wang, M.; Li, J. Adsorption of the Uranyl Ions on an Amidoxime-based Polyethylene Nonwoven Fabric Prepared by Preirradiation-induced Emulsion Graft Polymerization. Ind. Eng. Chem. Res. 2012, 51, 15089-15095.
26. Mohamed, N. H.; Tamada, M.; Ueki, Y.; Seko, N. Effect of Partial Delignification of Kenaf bast Fibers for Radiation Graft Copolymerization. J. Appl. Polym. Sci. 2013, 127, 2891-2895.
27. Madrid, J. F.; Abad, L. V.; Yamanobe, T.; Seko, N. Effects of Chain Transfer Agent on the Electron Beam-induced Graft Polymerization of Glycidyl Methacrylate in Emulsion Phase. Colloid. Polym. Sci. 2017, 295, 1007-1016.
28. Yu, M.; Zhang, B.; Deng, B.; Yang, X.; Sheng, K.; Xie, L. Preirradiation-induced Emulsion Graft Polymerization of Glycidyl Methacrylate onto Polyvinylidene Fluoride Powder. J. Appl. Polym. Sci. 2010, 117, 3575-3581.
29. Nasef, M. M.; Hegazy, E. S. A. Preparation and Applications of Ion Exchange Membranes by Radiation-induced Graft Copoly- merization of Polar Monomers onto Non-polar Films. Prog. Polym. Sci. 2004, 29, 499-561.
30. Seko, N.; Bang, L. T.; Tamada, M. Syntheses of Amine-type Adsorbents with Emulsion Graft Polymerization of Glycidyl Methacrylate. Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms. 2007, 265, 146-149.
31. Wang, L.; Li, F.; Yao, M.; Qiu, T.; Jiang, W.; Fan, L. J. Atom Transfer Radical Polymerization of Glycidyl Methacrylate Followed by Amination on the Surface of Monodispersed Highly Crosslinked Polymer Microspheres and the Study of Cation Adsorption. React. Funct. Polym. 2014, 82, 66-71.
32. Zhang, B.; Hu, N.; Wang, Y.; Wang, Z.; Wang, Y.; Kong, E. S.; Zhang, Y. Polyglycidyl methacrylates-grafted Zinc Oxide Nano- wire by Surface-initiated Atom Transfer Radical Polymerization. Nano-Micro Lett. 2010, 2, 285-289.
33. Jeun, J. P.; Hua, Z. J.; Kang, P. H.; Nho, Y. C. Electron Beam Radiation-induced Grafting of Scrylonitrile onto Polypropylene Fibers: Influence of the Synthesis Conditions. J. Appl. Polym. Sci. 2010, 115, 222-228.
34. Nasef, M. M. Effect of Solvents on Radiation-induced Grafting of Styrene onto Fluorinated Polymer Films. Polym. Int. 2011, 50, 338-346.
35. Uddin, M. D. Z.; Watanabe, M.; Shirai, H.; Hirai, T. Effects of Plasticizers on Novel Electromechanical Actuations with Different Polyvinyl Chloride Gels. J. Polym. Sci. Pt. B-Polym. Phys. 2003, 41, 2119-2127.
36. Sun, J.; Chen, Z.; Ge, M.; Xu, L.; Zhai, M. Selective Adsorption of Hg(II) by γ-radiation Synthesized Silica-graft-vinyl Imidazole Adsorbent. J. Hazard. Mater. 2013, 244-245, 94-101.
37. Zhang, S.; Wang, W.; Wang, H.; Qi, W.; Yu, L.; Ye, Q. Synthesis and Characterisation of Starch Grafted Superabsorbent Via10 MeV Electron-beam Irradiation. Carbohydr. Polym. 2014, 101, 798-803.
38. Sherazi, T. A.; Sohn, J. Y.; Lee, Y. M.; Guiver, M. D. Polyethylene-based Radiation Grafted Anion-exchange Membranes for Alkaline Fuel Cells. J. Membr. Sci. 2013, 441, 148-157.
39. Lv, X.; Song, W.; Ti, Y.; Qu, L.; Zhao, Z.; Zheng, H. Gamma Radiation-induced Grafting of Acrylamide and Dimethyl Diallyl Ammonium Chloride onto Starch. Carbohydr. Polym. 2013, 92, 388-393.
40. Mu, L.; Zhao, M.; Yang, B.; Zhao, H.; Cui, C.; Zhao, Q. Effect of Ultrasonic Treatment on the Graft Reaction between Soy Protein Isolate and Gum Acacia and on the Physicochemical Properties of Conjugates. J. Agric. Food Chem. 2010, 58, 4494-4499.
41. Yang, Y.; Li, H.; Chen, S.; Zhao, Y.; Li, Q. Preparation and Characterization of a Solid Amine Adsorbent for Capturing CO₂ by Grafting Allylamine onto PAN Fiber. Langmuir 2010, 26, 13897-13902.
42. Thakur, V. K.; Thakur, M. K.; Gupta, R. K. Development of Functionalized Cellulosic Biopolymers by Graftcopolymerization. Int. J. Biol. Macromol. 2013, 62, 44-51.
43. Tseng, C. H.; Wang, C. C.; Chen, C. Y. Polypropylene Fibers Modified by Plasma Treatment for Preparation of Ag Nanoparticles. J. Phys. Chem. B 2006, 110, 4020-4029.
44. Ni, Q. L.; Fan, J. Q.; Niu, H.; Dong, J. Y. Enhancement of Graft Yield and Control of Degradation During Polypropylene Maleation in the Presence of Polyfunctional Monomer. J. Appl. Polym. Sci. 2011, 121, 2512-2517.
45. Madrid, J. F.; Ueki, Y.; Abad, L. V.; Yamanobe, T.; Seko, N. RAFT-mediated Graft Polymerization of Glycidyl Methacrylate in Emulsion from Polyethylene/Polypropylene Initiated with c-radiation. J. Appl. Polym. Sci. 2017, 134, 45270.
46. Xu, T.; Wu, Q.; Chen, S.; Deng, M. Preparation of Polypropylene Based Hyperbranched Absorbent Fibers and the Study of Their Adsorption of CO₂. RSC Adv. 2015, 5, 32902-32908.
47. Zheng, Y. Q.; Deng, S.; Niu, L.; Xu, F. J.; Chai, M. Y.; Yu, G. Functionalized Cotton Via Surface-initiated Atom Transfer Radical Polymerization for Enhanced Sorption of Cu(Ⅱ) and Pb(Ⅱ). J. Hazard. Mater. 2011, 192, 1401-1408.
48. Moawia, R. M.; Nasef, M. M.; Mohamed, N. H.; Ripin, A. Modification of Flax Fibres by Radiation Induced Emulsion Graft Copolymerization of Glycidyl Methacrylate. Radiat. Phys. Chem. 2016, 122, 35-42.
49. Gao, Q.; Hu, J.; Li, R.; Xing, Z.; Xu, L.; Wang, M.; Guo, X.; Wu, G. Radiation Synthesis of a New Amidoximated UHMWPE Fibrous Adsorbent with High Adsorption Selectivity for Uranium over Vanadium in Simulated Seawater. Radiat. Phys. Chem. 2016, 122, 1-8.
50. Liu, C.; Lei, X.; Liang, X.; Jia, J.; Wang, L. Visible Sequestration of Cu²⁺ Ions Using Amino-Functionalized Cotton Fiber. RSC Adv. 2017, 7, 9744-9753.
51. Zhao, K.; Kong, L.; Yang, W.; Huang, Y.; Li, H.; Ma, S.; Lv, W.; Hu, J.; Wang, H.; Liu, H. Hooped Amino-Group Chains in Porous Organic Polymers for Enhancing Heavy Metal Ion Removal. ACS Appl. Mater. Interfaces 2019, 11, 44751-44757.

Polymer(Korea) 폴리머
Frequency : Bimonthly(odd)
ISSN 0379-153X(Print)
ISSN 2234-8077(Online)
Abbr. Polym. Korea
2023 Impact Factor : 0.4
Indexed in SCIE

This Article

2021; 45(5): 764-774

Published online Sep 25, 2021
10.7317/pk.2021.45.5.764
Received on May 10, 2021
Revised on Jun 9, 2021
Accepted on Jun 9, 2021

Services

Shared

Correspondence to

Chan-Hee Jung
Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, Jeongeup, Jeollabuk-do 56212, Korea
E-mail: jch@kaeri.re.kr