Article
  • Core-Shell Copolymer as Highly Effective Additive for Epoxy Adhesives
  • Junsoo Moon# , Yoon Huh# , Youngson Choe*,† , and Joona Bang

  • Department of Chemical and Biological Engineering, Korea University, Seoul 02841, Korea
    *Department of Chemical Engineering, Pusan National University, Pusan 46241, Korea

  • 코어쉘 공중합체 첨가제 도입을 통한 에폭시 접착제 물성 향상
  • 문준수# ·허 윤# ·최영선*,† ·방준하

  • 려대학교 화공생명공학과, *부산대학교 화공생명공학부

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Kinloch, A. Toughening Epoxy Adhesives to Meet Today's Challenges. MRS Bull. 2003, 28, 445-448.
  •  
  • 2. Marques, J.; Barbosa, A.; da Silva, C.; Carbas, R.; da Silva, L. An Overview of Manufacturing Functionally Graded Adhesives-Challenges and Prospects. J. Adhes. 2021, 97, 172-206.
  •  
  • 3. Dillard, D. A. Advances in Structural Adhesive Bonding. Elsevier: Amsterdam, 2010.
  •  
  • 4. Marouf, B. T.; Mai, Y.-W.; Bagheri, R.; Pearson, R. A. Toughening of Epoxy Nanocomposites: Nano and Hybrid Effects. Polym. Rev. 2016, 56, 70-112.
  •  
  • 5. Bagheri, R.; Marouf, B.; Pearson, R. Rubber-toughened Epoxies: A Critical Review. Polym. Rev. 2009, 49, 201-225.
  •  
  • 6. Hsieh, T.; Kinloch, A.; Masania, K.; Lee, J. S.; Taylor, A.; Sprenger, S. The Toughness of Epoxy Polymers and Fibre Composites Modified with Rubber Microparticles and Silica Nanoparticles. J. Mater. Sci. 2010, 45, 1193-1210.
  •  
  • 7. Pruksawan, S.; Samitsu, S.; Fujii, Y.; Torikai, N.; Naito, M. Toughening Effect of Rodlike Cellulose Nanocrystals in Epoxy Adhesive. ACS Appl. Polym. Mater. 2020, 2, 1234-1243.
  •  
  • 8. Pang, V.; Thompson, Z. J.; Joly, G. D.; Bates, F. S.; Francis, L. F. Adhesion Strength of Block Copolymer Toughened Epoxy on Aluminum. ACS Appl. Polym. Mater. 2019, 2, 464-474.
  •  
  • 9. Dean, J. M.; Verghese, N. E.; Pham, H. Q.; Bates, F. S. Nano- structure toughened epoxy resins. Macromolecules 2003, 36, 9267-9270.
  •  
  • 10. Lipic, P. M.; Bates, F. S.; Hillmyer, M. A. Nanostructured Thermosets from Self-Assembled Amphiphilic Block Copolymer/Epoxy Resin Mixtures. J. Am. Chem. Soc. 1998, 120, 8963-8970.
  •  
  • 11. Liu, J.; Thompson, Z. J.; Sue, H.-J.; Bates, F. S.; Hillmyer, M. A.; Dettloff, M.; Jacob, G.; Verghese, N.; Pham, H. Toughening of Epoxies with Block Copolymer Micelles of Wormlike Morphology. Macromolecules 2010, 43, 7238-7243.
  •  
  • 12. Wu, J.; Thio, Y. S.; Bates, F. S. Structure and Properties of PBO-PEO Diblock Copolymer Modified Epoxy. J. Polym. Sci. Pt. B-Polym. Phys. 2005, 43, 1950-1965.
  •  
  • 13. Liu, J. D.; Sue, H.-J.; Thompson, Z. J.; Bates, F. S.; Dettloff, M.; Jacob, G.; Verghese, N.; Pham, H. Strain Rate Effect on Tough- ening of Nano-Sized PEP-PEO Block Copolymer Modified Epoxy. Acta Mater. 2009, 57, 2691-2701.
  •  
  • 14. Hillmyer, M. A.; Lipic, P. M.; Hajduk, D. A.; Almdal, K.; Bates, F. S. Self-Assembly and Polymerization of Epoxy Resin-Amphiphilic Block Copolymer Nanocomposites. J. Am. Chem. Soc. 1997, 119, 2749-2750.
  •  
  • 15. Grubbs, R. B.; Broz, M. E.; Dean, J. M.; Bates, F. S. Selectively Epoxidized Polyisoprene-Polybutadiene Block Copolymers. Macromolecules 2000, 33, 2308-2310.
  •  
  • 16. Declet-Perez, C.; Redline, E. M.; Francis, L. F.; Bates, F. S. Role of Localized Network Damage in Block Copolymer Toughened Epoxies. ACS Macro Lett. 2012, 1, 338-342.
  •  
  • 17. Thio, Y. S.; Wu, J.; Bates, F. S. Epoxy Toughening Using Low Molecular weight Poly(hexylene oxide)-Poly(ethylene oxide) Diblock Copolymers. Macromolecules 2006, 39, 7187-7189.
  •  
  • 18. Declet-Perez, C.; Francis, L. F.; Bates, F. S. Deformation Processes in Block Copolymer Toughened Epoxies. Macromolecules 2015, 48, 3672-3684.
  •  
  • 19. Qian, J. Y.; Pearson, R. A.; Dimonie, V. L.; El‐Aasser, M. S. Synthesis and Application of Core-Shell Particles as Toughening Agents for Epoxies. J. Appl. Polym. 1995, 58, 439-448.
  •  
  • 20. Fröhlich, J.; Kautz, H.; Thomann, R.; Frey, H.; Mülhaupt, R. Reactive Core/Shell Type Hyperbranched Blockcopolyethers as New Liquid Rubbers for Epoxy Toughening. Polymer 2004, 45, 2155-2164.
  •  
  • 21. Sue, H.-J.; Garcia-Meitin, E.; Pickelman, D.; Yang, P. Optimization of Mode-I Fracture Toughness of High-Performance Epoxies by Using Designed Core-Shell Rubber Particles. American Chemical Society: Washington, D.C., 1993.
  •  
  • 22. Kinloch, A.; Shaw, S.; Tod, D.; Hunston, D. Deformation and Fracture Behaviour of a Rubber-Toughened Epoxy: 1. Micro- structure and Fracture Studies. Polymer 1983, 24, 1341-1354.
  •  
  • 23. Ning, N.; Liu, W.; Hu, Q.; Zhang, L.; Jiang, Q.; Qiu, Y.; Wei, Y. Impressive Epoxy Toughening by a Structure-Engineered Core/shell Polymer Nanoparticle. Compos. Sci. Technol. 2020, 199, 108364.
  •  
  • 24. Naguib, M.; Grassini, S.; Sangermano, M., Core/Shell PBA/PMMA‐PGMA Nanoparticles to Enhance the Impact Resistance of UV‐Cured Epoxy Systems. Macromol. Mater. Eng. 2013, 298, 106-112.
  •  
  • 25. Bécu‐Longuet, L.; Bonnet, A.; Pichot, C.; Sautereau, H.; Maazouz, A. Epoxy Networks Toughened by Core-Shell Particles: Influence of the Particle Structure and Size on the Rheological and Mechanical Properties. J. Appl. Polym. 1999, 72, 849-858.
  •  
  • 26. Herzberger, J.; Niederer, K.; Pohlit, H.; Seiwert, J.; Worm, M.; Wurm, F. R.; Frey, H. Polymerization of Ethylene Oxide, Propylene Oxide, and Other Alkylene Oxides: Synthesis, Novel Polymer Architectures, and Bioconjugation. Chem. Rev. 2016, 116, 2170-2243.
  •  
  • 27. Kim, S.; Yoo, M.; Baettig, J.; Kang, E.-H.; Koo, J.; Choe, Y.; Choi, T.-L.; Khan, A.; Son, J. G.; Bang, J. Perpendicularly Oriented Block Copolymer Thin Films Induced by Neutral Star Copolymer Nanoparticles. ACS Macro Lett. 2015, 4, 133-137.
  •  
  • 28. Gao, H.; Tsarevsky, N. V.; Matyjaszewski, K. J. M. Synthesis of Degradable Miktoarm Star Copolymers via Atom Transfer Radical Polymerization. Macromolecules 2005, 38, 5995-6004.
  •  
  • 29. Moon, J.; Huh, Y.; Park, J.; Kim, H. W.; Choe, Y.; Huh, J.; Bang, J. Adhesion Behavior of Catechol-Incorporated Silicone Elastomer on Metal Surface. ACS Appl. Polym. Mater. 2020, 2, 2444-2451.
  •  
  • 30. Pang, V.; Thompson, Z. J.; Joly, G. D.; Bates, F. S.; Francis, L. F. Adhesion Strength of Block Copolymer Toughened Epoxy on Aluminum. ACS Appl. Polym. Mater. 2019, 2, 464-474.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2021; 45(5): 757-763

    Published online Sep 25, 2021

  • 10.7317/pk.2021.45.5.757
  • Received on May 5, 2021
  • Revised on May 28, 2021
  • Accepted on May 31, 2021

Correspondence to

  • Youngson Choe* and Joona Bang
  • Department of Chemical and Biological Engineering, Korea University, Seoul 02841, Korea
    *Department of Chemical Engineering, Pusan National University, Pusan 46241, Korea

  • E-mail: choe@pusan.ac.kr ,joona@korea.ac.kr