Article
  • Analysis of Foaming Characteristics and Physical Properties of Polyurethane Foam according to Foaming Agents

  • Wan Hee Yun and Sang Bum Kim†

  • Department of Chemical Engineering, Kyonggi University, Suwon 16227, Korea

  • 발포제에 따른 폴리우레탄 폼의 발포 특성 및 물성 분석

  • 윤완희 · 김상범†

  • 경기대학교 화학공학과

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Woods, G. The ICI Polyurethane Book; 2nd ed.; Wiley: New York, USA, 1990; pp 5.
  •  
  • 2. Edwards, K. N.; Gum, W. F.; Johnson, J. E.; Bailey, F. E.; Graff, R. S.; Glasser, W. G.; Klempner, D.; Frisch, K. C. Urethane Chemistry and Applications; ACS: Washington D.C., USA, 1981.
  •  
  • 3. Nazeran, N.; Moghaddas, J. Synthesis and Characterization of Silica Aerogel Reinforced Rigid Polyurethane Foam for Thermal Insulation Application. J. Non-Cryst. Solids 2017, 461, 1-11.
  •  
  • 4. Wang, H.; Wang, Q. S.; He, J. J.; Mao, Z. L.; Sun, J. H. Study on the Pyrolytic Behaviors and Kinetics of Rigid Polyurethane Foams. Procedia Eng. 2013, 52, 377-385.
  •  
  • 5. Lee, Y. B.; Baek, K. H.; Choe, K. H.; Han, C. H. Development of Mass Production Type Rigid Polyurethane Foam for Lng Carrier Using Ozone Depletion Free Blowing Agent. Cryogenics 2016, 80, 44-51.
  •  
  • 6. Park, S. B.; Choi, S. W.; Kim, J. H.; Bang, C. S. Effect of the Blowing Agent on the Low-temperature Mechanical Properties of CO2-and HFC-245fa-blown Glass-fiber-reinforced Polyurethane Foams. Composites Part B 2016, 93, 317-327.
  •  
  • 7. Lee, Y. B.; Choi, S. H.; Choi, G. H. Characteristics of Rigid Polyurethane Foams Blown by HFCs for LNG Storage Tank. J. Korean Instit. Gas 2005, 9, 16-20.
  •  
  • 8. Son, Y. J.; Kwon, S. K.; Koh, S. H.; Kim, Y. H.; Kim, S. B.; Lee, Y. B.; Choe, K. H.; Kim, W. N. Effect of the Polyol and Blowing Agent Upon Manufacture of Rigid Polyurethane Foam. Proceedings of ‘01 KIGAS Autumn Conference, 2001;10, 77-86.
  •  
  • 9. Wu, J.; Dillon, D. Polyurethane Expo 2001; CRC Press: Boca Raton, 2001; pp 339-341.
  •  
  • 10. Han, M. S.; Choi, S. J.; Kim, J. M.; Kim, Y. H.; Kim, Y. N.; Lee, H. S.; Sung, J. Y. Effects of Silicone Surfactant on the Cell Size and Thermal Conductivity of Rigid Polyurethane Foams by Environmentally Friendly Blowing Agents. Macromol. Res. 2009, 17, 44-50.
  •  
  • 11. Kang, J. W.; Kim, J. M.; Kim, M. S.; Kim, Y. H.; Kim, W. N.; Jang, W.; Shin, D. S. Effects of Nucleating Agents on the Morphological, Mechanical and Thermal Insulating Properties of Rigid Polyurethane foams. Macromol. Res. 2009, 17, 856-862.
  •  
  • 12. Kang, M. J.; Kim, Y. H.; Park, G. P.; Han, M. S.; Kang, M. J. Liquid Nucleating Additives for Improving Thermal Insulating Properties and Mechanical Strength of Polyisocyanurate Foams. J. Mater. Sci. 2010, 45, 5412-5419.
  •  
  • 13. Wirpsza, Z. The Problem of Replacing Chlorofluorocarbons in the Production of Polyurethane Foams. Int. Polym. Sci. Technol. 1995, 22, 92.
  •  
  • 14. Rossitto, F. C.; Adam, N. Evaluation of HFC-245fa and Pentanes in Polyisocyanurate and Polyurethane Laminated Panel Rigid Foam Formulations. J. Cell. Plast. 1998, 34, 467-482.
  •  
  • 15. Lee, Y. B.; Yang, Y. C. In Properties of Polyurethane Foam Blown by Environment Friendly Blowing Agent. The 28th International Ocean and Polar Engineering Conference, Sapporo, Japan, 2018.
  •  
  • 16. Morais, A. R. C.; Simoni, L. D.; Scurto, A. M.; Shiflett, M. B. Solubilities and Diffusivities of HFC and HFO Refrigerants in a Synthetic Polyol Ester Lubricant Oil. SHRAE. Trans. 2019, 125, 70-72.
  •  
  • 17. Berardi, U.; Madzarevic, J. Microstructural Analysis and Blowing Agent Concentration in Aged Polyurethane and Polyisocyanurate Foams. Appl. Therm. Eng. 2020, 164, 11444.
  •  
  • 18. Jung, H. C.; Ryu, S. C.; Kim, W. N.; Lee, Y. B.; Choe, K. H.; Kim, S. B. Properties of Rigid Polyurethane Foams Blown by HCFC 141B and Distilled Water. J. Appl. Polym. Sci. 2001, 81, 486-493.
  •  
  • 19. Zipfel, L.; Borner, K.; Krucke, W.; Barthelemy, P. HFC-365mfc: A Versatile Blowing Agent for Rigid Polyurethane Foams. J. Cell. Plast. 1999, 35, 328-344.
  •  
  • 20. Suzuki, K.; Youn, S. W.; Hiroshima, H. Bubble-free Patterning with Low Line Edge Roughness by Ultraviolet Nanoimprinting Using Trans-1,3,3,3-tetrafluoropropene Condensable Gas. Jpn. J. Appl. Phys. 2016, 55, 76502.
  •  
  • 21. Huo, E.; Liu, C.; Xu, X.; Dang, C. ReaxFF-based Molecular Dynamics Study of the Pyrolysis Mechanism of HFO 1336mzz(Z). Int. J. Refrig. 2017, 83, 118-130.
  •  
  • 22. Seo, W. J.; Jung, H. C.; Kim, Y. H.; Kim, W. N.; Choe, K. H.; Lee, Y. B.; Choi, S. H. Properties of Rigid Polyurethane Foams Synthesized from 4,4'-Diphenylnethane Diisocyanate and Polyester Polyol. Polym. Korea 2002, 26, 185-192.
  •  
  • 23. Lee, H. I.; Lee, K. Y. Change of Mechanical Property in Rigid Polyurethane Foam by Various Types and Contents of Gelling Catalysts. Polym. Korea 2015, 39, 529-536.
  •  
  • 24. Seymour, R. W.; Cooper, S. L. Thermal Analysis of Polyurethane Block Polymers. Macromol. 1973, 6, 48-53.
  •  
  • 25. Koh, S. H.; Kim, S. B. Physical Properties of Rigid Polyurethane Foams Prepared by Co-Blowing Agents. J. Korean Inst. Gas 2004, 8, 1-7.
  •  
  • 26. Jin, J. F.; Chen, Y. L.; Wang, D. N.; Hu, C. P.; Zhu, S.; Vanoverloop, L.; Randall, D. Structures and Physical Properties of Rigid Polyurethane Foam Prepared with Rosin-based Polyol. J. Appl. Polym. Sci. 2002, 84, 598-604.
  •  
  • 27. Prociak, A.; Pielichowske, J.; Sterzynske, T. Thermal Diffusivity of Rigid Polyurethane Foams Blown with Different Hydrocarbons. Polym. Test. 2002, 19, 705-712.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2021; 45(3): 406-413

    Published online May 25, 2021

  • 10.7317/pk.2021.45.3.406
  • Received on Dec 8, 2020
  • Revised on Jan 12, 2021
  • Accepted on Feb 1, 2021

Correspondence to

  • Sang Bum Kim

  • Department of Chemical Engineering, Kyonggi University, Suwon 16227, Korea

  • E-mail: ksb@kyonggi.ac.kr