Article
  • Thermochromic Hybrid Nanoparticles Comprising a Tungsten-Doped Vanadium Dioxide Core and a Poly(N-isopropylacrylamide) Shell Structure
  • Sang Won Jung, Sang Hwi Park*, Jung Whan Yoo*, and Juhyun Park

  • Department of Intelligent Energy and Industry, School of Chemical Engineering and Materials Science, Institute of Energy-Converting Soft Materials, Chung-Ang University, Seoul 06974, Korea
    *KNW R&D Center, Donyu 2-ro 60, Paju-eup, Paju-city, Gyeonggi-do 10832, Korea

  • 텅스텐이 도핑된 바나듐산화물 코어와 폴리이소프로필아크릴아마이드 쉘 구조를 보유한 열변색 하이브리드 나노입자
  • 정상원 · 박상휘* · 유중환* · 박주현

  • 중앙대학교 지능형에너지산업학과, 화학신소재공학부, *KNW연구소

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Kamalisarvestani, M.; Saidur, R.; Mekhilef, S.: Javadi, F. S. Performance, Materials and Coating Technologies of Thermo-chromic Thin Film on Smart Windws. Renew. Sust. Energ. Rev. 2013, 26, 353-364.
  •  
  • 2. Ke, Y.; Zhou, C.; Zhou, Y.; Wang, S.; Chan, S. H.; Long, Y. Emerging Thermal-Responsive Materials and Intergrated Thechniques Trageting the Energy-Efficient Smart Window Application. Adv. Funct. Mater. 2018, 28, 1800113.
  •  
  • 3. Kanu, S. S.; Binions, R. Thin Films for Solar Control Applications. Proc. R. Soc. A 2010, 466, 19-44.
  •  
  • 4. Cui, Y.; Ke, Y.; Liu, C.; Chen, Z.; Wang, N.; Zhang, L.; Zhou, Y.; Wang, S.; Gao, Y.; Long, Y. Thermochromic VO2 for Energy-Efficient Smart Windows. Cell Press, Joule, Rev. 2018, 2, 1707-1746.
  •  
  • 5. Gao, Y.; Luo, H.; Zhang, Z.; Kang, L.; Chen, Z.; Du, J.; Kanehira, M.; Cao, C. Nanoceramic VO2 Thermochromic Smart Glass: A Review on Progress in Solution Processing. Nano energy 2012, 1, 221-246.
  •  
  • 6. Morin, F. J. Oxides Which Show a Metal-to-insulatior Transition at the Neel Temperature. Phys. Rev. Lett. 1959, 3, 34-36.
  •  
  • 7. Wang, Y.; Zhao, F.; Wang, J.; Khan, A. R.; Shi, Y.; Chen, Z.; Zhang, K.; Li, L.; Gao, Y.; Guo, X. VO2@SiO2/Poly(N-isopropyl-acrylamide) Hybrid Nanothermochromic Microgels for Smart Window. Ind. Eng. Chem. Res. 2018, 57, 12801-12808.
  •  
  • 8. Chen, Z.; Gao, Y.; Kang, L.; Cao, C.; Chen, S.; Luo, H. Fine crystalline VO2 Nanoparticles: Synthesis Abnormal Phase Transition Temperatures and Excellent Optical Properties of a Derived VO2 Nanocomposite Foil. J. Mater. Chem. A 2014, 2, 2718.
  •  
  • 9. Wang, Y.; Zhao, F.; Wang, J.; Li, L.; Zhang, K.; Shi, Y.; Gao, Y.; Guo, X. Tungsten-Doped VO2/Starch Derivative Hybrid Nanothermochromic Hydrogel for Smart Window. Nanomaterials 2019, 9, 970.
  •  
  • 10. Hu, L.; Tao, H.; Chen, G.; Pan, R.; Wan, M.; Xiong, D.; Zhao, X. Porous W-doped VO2 Films with Simultaneously Enhanced Visible Transparency and Thermochromic Properties. J. Sol-gel Technol. 2016, 77, 85-93.
  •  
  • 11. He, Q.; Wang, Y.; Zhou, Y.; He, M.; Xu, R.; Hu, S.; Wu, W.; Wang, R. PAM-PNIPAM/W-doped VO2 Thermochromic Hydrogel Film with High Solar Modulation Capability for Smart Windows Depolyment. Opt. Mater. 2019,97, 109367.
  •  
  • 12. Liang, S.; Shi, Q.; Zhu, H.; Peng, B.; Huang, W. One-Step Hydrothernmal Synthesis of W-doped VO2(M) Nanorods with a Tunable Phase-Transition Temperature for Infrared Smart Windows. ACS Omega 2016, 1, 1139-1148.
  •  
  • 13. Houska, J.; Kolenaty, D.; Vlcek, J.; Barta, T.; Rezek, J.; Cerstvy, R. Significant Improvement of the Performance of ZrO2/V1-xWxO2/ZrO2 Thermochromic Coatings by Utilizing a Second-order Interference. Sol. Energy Mater. Sol. Cells 2019,191, 365-371.
  •  
  • 14. Wang, M.; Gao, Y.; Cao, C.; Chen, K.; Wen, Y.; Fang, D.; Li, L.; Guo, X. Binary Solvent Colloids of Thermosensitive Poly(N-isopropylacrylamide) Microgel for Smart Windows. Ind. Eng. Chem. Res. 2014, 53, 18462-18472.
  •  
  • 15. Seeboth, A.; Schneider, J.; Patzak, A. Materials for Intelligent Sun Protecting Glazing. Sol. Energy Mater. Sol. Cells 2000, 60, 263-277.
  •  
  • 16. Kim, D. J.; Kang, S. M.; Kong, B. K.; Kim, W. J.; Paik, H. J.; Choi, H. O.; Choi, I. S. Formation of Thermoresponsive Gold Nanoparticle/PNIPAAm Hybrids by Surface-Initiated, Atom Transfer Radical Polymerization in Aqueous Media. Macromol. Chem. Phys. 2005, 206, 1941-1946.
  •  
  • 17. Zhou, Y.; Cai, Y.; Hu, X.; Long, Y. VO2/Hydrogel Hybrid Nanothermochromic Material with Ultra-high Solar Modulation and Luminous Transmission. J. Mater. Chem. 2015, 3, 1121-1126.
  •  
  • 18. Chen, T.; Zhang, S.; Hua, L.; Xu, Z.; Zhou, L.; Wang, J. Triphenylphosphine-Containing Thermo-Responsive Copolymers: Synthesis, Characterization and Catalysis Application. Macromol. Res. 2019, 27, 931-937.
  •  
  • 19. Xia, Y.; Wu, H.; Tang, D.; Gao, S.; Chen, B.; Zeng, Z.; Wang, S.; Cao, M.; Li, D. Graphene Oxide Nanosheet-Composited Poly(N-isopropylacrylamide) Hydrogel for Cell Sheet Recovery. Macromol. Res. 2019, 27, 679-685.
  •  
  • 20. Yang, S.-A.; Choi, S.; Jeon, S. M.; Yu, J. Silica Nanoparticle Stability in Biological Media Revisited. Sci. Rep. 2018, 8, 186.
  •  
  • 21. Jo, C. W.; Kim, H. J.; Yoo, J. W. Thermochromic Properties of W-Mo Co-Doped VO2(M) Nanoparticles According to Reaction Parameters. Nanosci. Nanotechnol. 2017, 17, 2923-2928.
  •  
  • 22. Zou, H.; Schlaad, H. Thermoresponsive PNIPAM/Silica Nanoparticles by Direct Photopolymerization in Aqueous Media. J. Polym. Sci., Part A: Polym. Chem. 2015,53, 1260-1267.
  •  
  • 23. Graf, C.; Vossen, D. L. J.; Imhof, A.; Blaaderen, A. V. A General Method To Coat Colloidal Particles with Silica. Langmuir 2003, 19, 6693-6700.
  •  
  • 24. Lee, J. C.; Choi, D. H.; Chou, J. Y.; Ha, C. S. Poly(lactic acid)/Functionalized Silica Hybrids by Reactive Extrusion: Thermal, Rheological, and Degradation Behavior. Macromol. Res.2020,28, 327-335.
  •  
  • 25. Ganguly, S.; Mondal, S.; Das, P.; Bhawal, P.; Das, T. K.; Ghosh, S.; Remanan, S.; Das, N. C. An Insight Into the Physico-Mechanical Signatures of Silylated Graphene Oxide in Poly(ethylene methyl acrylate) Copolymeric Thermoplastic Matrix. Macromol. Res. 2019, 27, 268-281.
  •  
  • 26. Xaiver, J. R. Experimental Investigation of the Hybrid Epoxy-Silane Coating for Enhanced Protection against the Corrosion of Aluminum Alloy AA7075 Frame in Solar Cells. Macromol. Res. 2020, 28, 501-509.
  •  
  • 27. Senkevich, J. J.; Mitchell, J.; Yang, G. R.; Lu, T. M. Surface Chemistry of Mercaptan and Growth of Pyridine Short-Chain Alkoxy Silane Molecular Layers. Langmuir 2002, 18, 1587-1594.
  •  
  • 28. Chem, W. H.; Tseng, Y. T.; Hsieh, S.; Liu, W. C.; Hsieh, C. W.; Wu, C. W.; Huang, C. H.; Lin, H. Y.; Chen, C. W.; Lin, P. Y.; Chau, L. K. Silanization of Solid Surfaces Viamercaptopropylsilatrane: A New Approach of Constructing Gold Colloid Monolayers. RSC. Adv. 2014, 4, 46527-46535.
  •  
  • 29. Abel, S. B.; Riberi, K.; Rivarola, C. R.; Molina, M.; Barbero, C. A. Synthesis of a Smart Conductive Block Copolymer Responsive to Heat and Near Infrared Light. Polymers 2019, 11, 1744.
  •  
  • 30. Zhu, D.; Lu, M.; Guo, J.; Liang, L.; Lan, Y. Effect of Adamantyl Methacrylate on the Thermal and Mechanical Properties of Thermosensitive Poly(N-isopropylacrylamide) Hydrogels. J. Appl. Polym. Sci. 2012,124, 155-163.
  •  
  • 31. ASTM G173-03 Standard Tables of Reference Solar Spectral Irradiances: Direct Normal and Hemispherical on a 37 of Energy Technology Evaluation and Planning(ublic of Korea. studied for better in subsequen Materials, Philadelphia, PA, USA, http://rredc.nrel.gov/solar/spectra/am1.5.
  •  
  • 32. Choi, Y. W.; Sim, D. M.; Hur, Y. H.; Han, H. J.; Jung, Y. S. Synthesis of Colloidal VO2 Nanoparticles for Thermochromic Applications. Sol. Energy Mater. Sol. Cells 2018, 176, 266-272.
  •  
  • 33. Zhang, H.; Xiao, X.; Lu, X.; Chai, G.; Sun, Y.; Zhan, Y.; Xu, G. A Cost-effective Method to Fabricate VO2 (M) Nanoparticles and Films with Excellent Thermochromic Properties. Alloys. Compd 2015, 636, 106-112.
  •  
  • 34. Lee, Y.; Jung, S. W.; Park, S. H.; Yoo, J. W.; Park, J. Synthesis of Tungsten-Doped Vanadium Dioxide Using a Modified Polyol Method Involving 1-Dodecanol. Materials 2020, 13, 5384.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2021; 45(2): 286-293

    Published online Mar 25, 2021

  • 10.7317/pk.2021.45.2.286
  • Received on Nov 3, 2020
  • Revised on Dec 14, 2020
  • Accepted on Dec 15, 2020

Correspondence to

  • Juhyun Park
  • Department of Intelligent Energy and Industry, School of Chemical Engineering and Materials Science, Institute of Energy-Converting Soft Materials, Chung-Ang University, Seoul 06974, Korea

  • E-mail: jpark@cau.ac.kr