Article
  • Cure Kinetics and Chemorheology of Epoxy/Clay Nanocomposites for Outdoor Use with Various Nanoclays
  • Sangmook Lee

  • Division of Chemical Engineering, Dankook University, 126 Jukjeon-dong, Suji-gu, Gyeonggi-do 16890, Korea

  • 나노충전제의 종류에 따른 옥외용 에폭시 나노복합체의 경화속도론 및 화학유변학
  • 이상묵

  • 단국대학교 화학공학과

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Kavitha, D.; Balachandran, M. XLPE-layered Silicate Nanocomposites for High Voltage Insulation Applications: Dielectric Characteristics, Treeing Behavior and Mechanical Properties. IET Sci. Meas. Technol. 2019, 13, 1019-1025.
  •  
  • 2. Ashok, N.; Balachandran, M.; Lawrence, F. Organo-modified Layered Silicate Nanocomposites of EPDM–chlorobutyl Rubber Blends for Enhanced Performance in γ Radiation and Hydrocarbon Environment. J. Compos. Mater. 2018, 52, 3219-3231.
  •  
  • 3. Kong, J.; Li, Z.; Cao, Z.; Han, C.; Dong, L. The Excellent Gas Barrier Properties and Unique Mechanical Properties of Poly (propylene carbonate)/Organo-montmorillonite Nanocomposites. Polym. Bull. 2017, 74, 5065-5082.
  •  
  • 4. Rahmaoui, F. E. Z.; Mederic, P.; Hocine, N. A.; Saada, A. A.; Poirot, N.; Belaidi, I. Contribution of the Organo-montmorillonite/Graphene Pair to the Rheological and Mechanical Properties of Polyethylene Matrix Based Nanocomposites. Appl. Clay Sci. 2017, 150, 244-251.
  •  
  • 5. Ismail, N. H. C.; Akil, H. M.; Salim, Z. A. S. A. Thermal and Morphological Properties of ABS/Muscovite Layered Silicate Composites. Mater. Sci. Forum 2019, 947, 185-189.
  •  
  • 6. Scarfato, P.; Incarnato, L.; Maio, L. D.; Dittrich, B.; Schartel, B. Influence of a Novel Organo-silylated Clay on the Morphology, Thermal and Burning Behavior of Low Density Polyethylene Composites. Compos. Part B: Eng. 2016, 98, 444-452.
  •  
  • 7. Peng, S.; Yang, X.; Yang, Y.; Wang, S.; Zhou, Y.; Hu, J.; Li, Q.; He, Direct Detection of Local Electric Polarization in the Interfacial Region in Ferroelectric Polymer Nanocomposites. J. Adv. Mater. 2019, 31, 1807722.
  •  
  • 8. Zhang, D.-Li.; Zha, J.-W.; Li, C.-Q.; Li, W.-K.; Wang, S.-J.; Wen, Y.; Dang, Z.-M. High Thermal Conductivity and Excellent Electrical Insulation Performance in Double-percolated Three-phase Polymer Nanocomposites. Compos. Sci. Technol. 2017, 144, 36-42.
  •  
  • 9. Al-Saleh, M. H. Clay/Carbon Nanotube Hybrid Mixture to Reduce the Electrical Percolation Threshold of Polymer Nanocomposites. Compos. Sci. Technol. 2017, 149, 34-40.
  •  
  • 10. Dhatarwal, P.; Sengwa, R. J.; Choudhary, S. Effect of Intercalated and Exfoliated Montmorillonite Clay on the Structural, Dielectric and Electrical Properties of Plasticized Nanocomposite Solid Polymer Electrolytes. Compos. Commun. 2017, 5, 1-7.
  •  
  • 11. Rana, A. S.; Vamshi, M. K.; Naresh, K.; Velmurugan, R.; Sarathi, R. Mechanical, Thermal, Electrical and Crystallographic Behaviour of EPDM Rubber/Clay Nanocomposites for Out-door Insulation Applications, Advances in Materials and Processing Technologies. Adv. Mater. Process. Technol. 2020, 6, 54-74.
  •  
  • 12. Arya, A.; Sharma, A. L. Investigation on Enhancement of Electrical, Dielectric and Ion Transport Properties of Nanoclay-based Blend Polymer Nanocomposites. Polym. Bull. 2020, 77, 2965-2999.
  •  
  • 13. Nakamura, S.; Kumada, A.; Hidaka, K.; Hirai, H.; Imai, T.; Nakamura, T.; Yoshimitsu, T. Effects of Temperature on Electrical Treeing and Partial Discharges in Epoxy/Silica Nanocomposites. IEEE Trans. Dielectr. Electr. Insul. 2020, 27, 1169-1177.
  •  
  • 14. Wen, H.; Zhang, X.; Xia, R.; Hu, G.; Wu, Y. Decomposition Characteristics of SF6 under Flashover Discharge on the Epoxy Resin Surface. Materials 2019, 12, 1408.
  •  
  • 15. Lee, S.; Jin, B. S.; Lee, J. W. Thermal Degradation Kinetics of Antimicrobial Agent, Poly(hexamethylene guanidine) Phosphate. Macromol. Res. 2006, 14, 491-498.
  •  
  • 16. Rath, S. K.; Ishack, A. M.; Suryavansi, U. G.; Chandrasekhar, L.; Patri, M. Phase Morphology and Surface Properties of Moisture Cured Polyurethane-urea (MCPU) Coatings: Effect of Catalysts. Prog. Org. Coat. 2008, 62, 393-399.
  •  
  • 17. Burel, F.; Feldman, A.; Bunel, C. Hydrogenated Hydroxy-functionalized Polyisoprene (H-HTPI) and Isocyanurate of Isophorone Diisocyanates (I-IPDI): Reaction Kinetics Study Using FTIR Spectroscopy. Polymer 2005, 46, 15-25.
  •  
  • 18. Seo, Y.; Lee, S. M.; Kim, D. Y.; Kim, K. U. Kinetic Study of the Imidization of a Poly(ester amic acid) by FT-Raman Spectroscopy. Macromolecules 1997, 30, 3747-3753.
  •  
  • 19. Nagle, D. J.; Celina, M.; Rintoul, I.; Frederics, P. M. Infrared Microspectroscopic Study of the Thermo-oxidative Degradation of Hydroxy-terminated Polybutadiene/Isophorone Diisocyanate Polyurethane Rubber. Polym. Degrad. Stabil. 2007, 92, 1446-1454.
  •  
  • 20. Lee, S.; Choi, C. H.; Hong, I.-K.; Lee, J. W. Curing Behavior of Polyurethane as a Binder for Polymer-bonded Explosives. J. Ind. Eng. Chem. 2015, 21, 980-985.
  •  
  • 21. Lee, S.; Choi, C. H.; Hong, I.-K.; Lee, J. W. Polyurethane Curing Kinetics for Polymer Bonded Explosives: HTPB/IPDI Binder. Korean J. Chem. Eng. 2015, 32, 1701-1706.
  •  
  • 22. Hong, I.-K.; Lee, S. Cure Kinetics and Modeling the Reaction of Silicone Rubber. J. Ind. Eng. Chem. 2013, 19, 42-47.
  •  
  • 23. Young, R. J.; Lowell, P. A. Introduction to Polymers; 2nd ed.; CRC Press: Great Britain, 2000.
  •  
  • 24. Sahoo, S. K.; Mohanty, S.; Nayak, S. K. Study of Thermal Stability and Thermo-mechanical Behavior of Functionalized Soybean Oil Modified Toughened Epoxy/organo Clay Nanocomposite. Prog. Org. Coat. 2015, 88, 263-271.
  •  
  • 25. Xidas, P. I.; Triantafyllidis, K. S. Effect of the Type of Alkylammonium Ion Clay Modifier on the Structure and Thermal/Mechanical Properties of Glassy and Rubbery Epoxy–clay Nanocomposites. Eur. Polym. J. 2010, 46, 404-417.
  •  
  • 26. Park, J.; Jana, S. C. Adverse Effects of Thermal Dissociation of Alkyl Ammonium Ions on Nanoclay Exfoliation in Epoxy–clay Systems. Polymer 2004, 45, 7673-7679.
  •  
  • 27. Kissinger, H. E. Reaction Kinetics in Differential Thermal Analysis. Anal. Chem. 1957, 29, 1702-1706.
  •  
  • 28. Gheno, G.; Ganzerla, R.; Bortoluzzi, M.; Paganica, R. Determination of Degradation Kinetics of Two Polyester Thermosetting Powder Coatings Using TGA and Colorimetric Analysis. Prog. Org. Coat. 2015, 78, 239-243.
  •  
  • 29. Sheng, X.; Akinc, M.; Kessler, M. Cure Kinetics of Thermosetting Bisphenol E Cyanate Ester. J. Therm. Anal. Calorim. 2008, 93, 77-85.
  •  
  • 30. Horie, K.; Hiura, H.; Sawada, M.; Kambe, H. Calorimetric Investigation of Polymerization Reactions. III. Curing Reaction of Epoxides with Amines. J. Polym. Sci. A-1 1970, 8, 1357-1372.
  •  
  • 31. Ozawa, T. Kinetic analysis of derivative curves in thermal analysis. J. Therm. Anal. 1970, 2, 301-324.
  •  
  • 32. Kamal, M. R.; Ryan, M. E. The Behavior of Thermosetting Compounds in Injection Molding Cavities. Polym. Eng. Sci. 1980, 20, 859-867.
  •  
  • 33. Rabearison, N.; Jochum, Ch.; Grandidier, J. C. A Cure Kinetics, Diffusion Controlled and Temperature Dependent, Identification of the Araldite LY556 Epoxy. J. Mater. Sci. 2011, 46, 787-796.
  •  
  • 34. Perrin, F. X.; Nguyen, T. M. H.; Vernet, J. L. Chemico-diffusion Kinetics and TTT Cure Diagrams of DGEBA–DGEBF/Amine Resins Cured with Phenol Catalysts. Eur. Polym. J. 2007, 43, 5107-5120.
  •  
  • 35. Macan, J.; Brnardic, L.; Ivankovic, M.; Mencer, H. J. DSC Study of Cure Kinetics of DGEBA-based Epoxy Resin with Poly (oxypropylene) Diamine. J. Therm. Anal. Calorim. 2005, 81, 369-373.
  •  
  • 36. Standard Test Method For Plastics: Dynamic Mechanical Properties: Cure Behavior. ASTM D4473 -08, 2016.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2021; 45(2): 219-227

    Published online Mar 25, 2021

  • 10.7317/pk.2021.45.2.219
  • Received on Oct 4, 2020
  • Revised on Dec 20, 2020
  • Accepted on Dec 28, 2020

Correspondence to

  • Sangmook Lee
  • Division of Chemical Engineering, Dankook University, 126 Jukjeon-dong, Suji-gu, Gyeonggi-do 16890, Korea

  • E-mail: sangmooklee@dankook.ac.kr