Article
  • Enhanced Flame Retardancy of Polymer-Carbon Nanotube Multi-Layer Coatings
  • Kyungwho Choi, Tae-Soon Kwon*, Jinhong Kim**, Sehui Yun**, Jung Sang Cho***, Yong Tae Park****,† , Jihyun Ryu**,† , and Chungyeon Cho**,†

  • School of Aerospace and Mechanical Engineering, Korea Aerospace University, Gyeonggi-do 10540, Korea
    *Korea Railroad Research Institute, Gyeonggi-do 16105, Korea
    **Department of Carbon Convergence Engineering, Wonkwang University, Iksan 54538, Korea
    ***Department of Engineering Chemistry, Chungbuk National University, Chungbuk-do 28644, Korea
    ****Department of Mechanical Engineering, Myongji University, Gyeonggi-do 17058, Korea

  • 탄소나노튜브 기반 다층박막코팅의 난연성 향상 분석
  • 최경후 · 권태순* · 김진홍** · 윤세희** · 조중상*** · 박용태****,† · 류지현**,† · 조충연**,†

  • 한국항공대학교 항공우주 및 기계공학부, *한국철도기술연구원, **원광대학교 창의공학대학 탄소융합공학과,
    ***충북대학교 화학공학과, ****명지대학교 기계공학과

References
  • 1. Alongi, J.; Carosio, F.; Frache, A.; Malucelli, G.; Layer by Layer Coatings Assembled through Dipping, Vertical or Horizontal Spray for Cotton Flame Retardancy. Carbohydr. Polym. 2013, 92, 114-119.
  •  
  • 2. Laoutid, F.; Bonnaud, L.; Alexandre, M.; Lopez-Cuesta, J.-M.; Dubois, Ph. New Prospects in Flame Retardant Polymer Materials: from Fundamentals to Nanocomposites. Mater. Sci. Eng. R Rep. 2009, 63, 100-125.
  •  
  • 3. Li, Q. L.; Wang, X. L.; Wang, D. Y.; Wang, Y. Z.; Feng, X. N.; Zheng, G. H. Durable Flame Retardant Finishing of PET/Cotton Blends Using a Novel PVA‐based Phosphorus‐nitrogen Polymer. J. Appl. Polym. Sci. 2011, 122, 342-353.
  •  
  • 4. Hwang, S.; Kim, Y.; Choi, K.; Jin, S. H.; Baeck, S. H.; Shim, S. E. Thermal Stability and Mechanical Properties of Silicone Rubber Composites Filled with Wollastonite/Mineral Fiber Hybrid Fire-proof Fillers. Polym. Korea 2019, 43, 965-971.
  •  
  • 5. Joo, A. R.; Lee, J. H.; Park, Y. G.; Lee, S. H. Thermal Stability of Polyurethane Foams Infused with Melamine-phosphate Coated Inorganic Flame Retardants. Polym. Korea 2018, 42, 288-297.
  •  
  • 6. Gu, J.; Lv, Z.; Wu, Y.; Guo, Y.; Tian, L.; Qiu, H.; Li, W.; Zhang, Q. Dielectric Thermally Conductive Boron Nitride/polyimide Composites with Outstanding Thermal Stabilities via In-situ Polymerization-electrospinning-hot Press Method. Compos. Part A Appl. Sci. Manuf. 2017, 94, 209-216.
  •  
  • 7. Yang, X.; Tang, L.; Guo, Y.; Liang, C.; Zhang, Q.; Kou, K.; Gu, J. Improvement of Thermal Conductivities for PPS Dielectric Nanocomposites via Incorporating NH2-POSS Functionalized nBN Fillers. Compos. Part A Appl. Sci. Manuf. 2017, 101, 237-242.
  •  
  • 8. Wang, J.; Zhang, D.; Zhang, Y.; Cai, W.; Yao, C.; Hu,Y.; Hu, W.; J. Construction of Multifunctional Boron Nitride Nanosheet Towards Reducing Toxic Volatiles (CO and HCN) Generation and Fire Hazard of Thermoplastic Polyurethane. Hazard. Mater. 2019, 362, 482-494.
  •  
  • 9. Decher, G.; Hong, J. D.; Schmitt, J. Buildup of Ultrathin Multilayer Films by a Self-assembly Process: III. Consecutively Alternating Adsorption of Anionic and Cationic Polyelectrolytes on Charged Surfaces. Thin Solid Films 1992, 210, 831-835.
  •  
  • 10. Park, S. J.; Yun, S. H.; Choi, W. K.; Cho, S.-K.; Lee, H. K.; Huh, K. M. Surface Modification of Polyethersulfone Hollow Fiber Membrane for Water Recovery Using Layer-by-Layer Nanocoating Method. Polym. Korea 2015, 39, 761-768.
  •  
  • 11. Iler, R. Multilayers of Colloidal Particles. J. Colloid Interface Sci. 1966, 21, 569-594.
  •  
  • 12. Cho, C.; Son, J. Organic Thermoelectric Multilayers with High Stretchiness. Nanomaterials 2019, 10, 41.
  •  
  • 13. Richardson, J. J.; Cui, J.; Bjornmalm, M.; Braunger, J. A.; Ejima, H.; Caruso, F. Innovation in Layer-by-Layer Assembly. Chem. Rev. 2016, 116, 14828-14867.
  •  
  • 14. An, Q.; Huang, T.; Shi, F. Covalent Layer-by-layer Films: Chemistry, Design, and Multidisciplinary Applications. Chem. Soc. Rev. 2018, 47, 5061-5098.
  •  
  • 15. Tiu, B. D. B.; Kernan, D. L.; Tiu, S. B.; Wen, A. M.; Zheng, Y.; Pokorski, J. K.; Advincula, R. C.; Steinmetz, N. F. Electrostatic Layer-by-layer Construction of Fibrous TMV Biofilms. Nanoscale 2017, 9, 1580-1590.
  •  
  • 16. Cho, C.; Song, Y.; Choi, K.; Grunlan, J. C. Improved Thermoelectric Power Factor in Completely Organic Nanocomposite Enabled by l-Ascorbic Acid. ACS Appl. Polym. Mater. 2019, 1, 1942-1947.
  •  
  • 17. Li, H.; Wang, X.; He, Y.; Peng, L. Facile Preparation of Fluorine-free Superhydrophobic/Superoleophilic Paper via Layer-by-layer Deposition for Self-cleaning and Oil/water Separation. Cellulose 2019, 26, 2055-2074.
  •  
  • 18. Vaterrodt, A.; Thallinger, B.; Daumann, K.; Koch, D.; Guebitz, G. M.; Ulbricht, M. Antifouling and Antibacterial Multifunctional Polyzwitterion/Enzyme Coating on Silicone Catheter Material Prepared by Electrostatic Layer-by-Layer Assembly. Langmuir 2016, 32, 1347-1359.
  •  
  • 19. Cho, C.; Song, Y.; Allen, R.; Wallace, K. L.; Grunlan, J. C. Stretchable Electrically Conductive and High Gas Barrier Nanocomposites. J. Mater. Chem. C 2018, 6, 2095-2104.
  •  
  • 20. Qiu, X.; Li, Z.; Li, X.; Zhang, Z. Flame Retardant Coatings Prepared Using Layer by Layer Assembly: A Review. Chem. Eng. J. 2018, 334, 108-122.
  •  
  • 21. Carosio, F.; Alongi, J. Ultra-Fast Layer-by-Layer Approach for Depositing Flame Retardant Coatings on Flexible PU Foams within Seconds. ACS Appl. Mater. Interfaces 2016, 8, 6315-6319.
  •  
  • 22. Patra, D.; Vangal, P.; Amanda, A. C.; Cho, C.; Regev, O.; Grunlan, J. C. Inorganic Nanoparticle Thin Film that Suppresses Flammability of Polyurethane with Only a Single Electrostatically-Assembled Bilayer. ACS Appl. Mater. Interfaces 2014, 6, 16903-16908.
  •  
  • 23. Lu, C.; Gao, X.-P.; Yao, H.-H.; Cao, C.-L.; Luo, Y.-J. Improving Flame Retardancy of Linear Low-density Polyethylene/Nylon 6 Blends via Controlling Localization of Clay and Intumescent Flame-retardant. Polym. Degrad. Stabil. 2018, 153, 75-87.
  •  
  • 24. Kim, H.; Park, J.-W.; Lee, J.-H.; Jang, S.-W.; Kim, H.-J.; Choi, Y.; Choy, J.-H.; Yang, J.-H. Clay-organic Intumescent Hybrid System for the Synergetic Flammability of Polymer Nanocomposites. J. Therm. Anal. Calorim. 2018, 132, 2009-2014.
  •  
  • 25. Hu, Y.; Wang, X.; Li, J. Regulating Effect of Exfoliated Clay on Intumescent Char Structure and Flame Retardancy of Polypropylene Composites. Ind. Eng. Chem. Res. 2016, 55, 5892-5901.
  •  
  • 26. Ryu, J. H.; Hong, S.; Lee, H. Bio-inspired Adhesive Catechol-conjugated Chitosan for Biomedical Applications: A Mini Review. Acta Biomater. 2015, 27, 101-115.
  •  
  • 27. Shang, S.; Zeng, W.; Tao, X. M. High Stretchable MWNTs/Polyurethane Conductive Nanocomposites. J. Mater. Chem. 2011, 21, 7274-7280.
  •  
  • 28. Cho, C.; Song, Y.; Allen, R.; Wallace, K. L.; Grunlan, J. C. Stretchable Electrically Conductive and High Gas Barrier Nanocomposites. J. Mater. Chem. C 2018, 6, 2095-2104.
  •  
  • 29. Luckham, P. F.; Rossi, S. The Colloidal and Rheological Properties of Bentonite Suspensions. Adv. Colloid Interface Sci. 1999, 82, 43-92.
  •  
  • 30. Etika, K. C.; Liu, L.; Cox, M. A.; Grunlan, J. C. Clay-mediated Carbon Nanotube Dispersion in poly(N-Isopropylacrylamide). Colloids Surf. A: Physicochem. Eng. Aspects 2016, 489, 19-26.
  •  
  • 31. Cho, C.; Culebras, M.; Wallace, K. L.; Song, Y.; Holder, K.; Hsu, J.-H.; Yu, C.; Grunlan, J. C. Stable n-type Thermoelectric Multilayer Thin Films With High Power Factor From Carbonaceous Nanofillers. Nano Energy 2016, 28, 426-432.
  •  
  • 32. Kharlampieva, E.; Sukhishvili, S. A. Hydrogen‐Bonded Layer‐ by‐Layer Polymer Films. J. Macromol. Sci.: Part C: Polym. Rev. 2006, 46, 377-395.
  •  
  • 33. Hsu, K. J.; McCarthy, S. L.; Versatile, T. J. Versatile Multilayer Thin Film Preparation Using Hydrophobic Interactions, Crystallization, and Chemical Modification of Poly(vinyl alcohol). Langmuir 2007, 23, 3260-3264.
  •  
  • 34. Choi, K.; Seo, S.; Kwon, H.; Kim, D.; Park, Y. T. Fire Protection Behavior of Layer-by-layer Assembled Starch–clay Multilayers on Cotton Fabric. J. Mater. Sci. 2018, 53, 11433-1143.
  •  
  • 35. Holder, K. M.; Cain, A. A.; Plummer, M. G.; Stevens, B. E.; Odenborg, P. K.; Grunlan, J. C. Carbon Nanotube Multilayer Nanocoatings Prevent Flame Spread on Flexible Polyurethane Foam. Macromol. Mater. Eng. 2016, 301, 665-673.
  •  
  • 36. Jang, W.; Chung, I. J.; Kim, J.; Seo, S.; Park, Y. T.; Choi, K. Improving Fire Resistance of Cotton Fabric through Layer-by-Layer Assembled Graphene Multilayer Nanocoating. J. Korean Phys. Soc. 2018, 72, 1052-1057.
  •  
  • 37. Son, B.; Hwang, T.-S.; Goo, D.-C. Fire-Retardation Properties of Polyurethane Nanocomposite by Filling Inorganic Nano Flame Retardant. Polym. Korea 2007, 31, 404-409.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2021; 45(1): 150-157

    Published online Jan 25, 2021

  • 10.7317/pk.2021.45.1.150
  • Received on Sep 18, 2020
  • Revised on Oct 13, 2020
  • Accepted on Oct 14, 2020

Correspondence to

  • Yong Tae Park**** , Jihyun Ryu** , and Chungyeon Cho **
  • **Department of Carbon Convergence Engineering, Wonkwang University, Iksan 54538, Korea
    ****Department of Mechanical Engineering, Myongji University, Gyeonggi-do 17058, Korea

  • E-mail: ytpark@mju.ac.kr, jhryu4816@wku.ac.kr, cncho37@wku.ac.kr