Article
  • Effects of Nucleating Agents on the Scratch and Gloss Properties of Polypropylene Composites
  • A Rom Oh, Gyeong Cheol Yu*, Jeong Jin Park**, Dae Sik Kim, Kyung Min Yu, Sun Young Lee**, Jae Min Lee***, and Seung Goo Lee*,†

  • Research & Development Division, Hyundai Motor Company, Hwaseong, 18280, Korea
    *Department of Applied Organic Materials Engineering, Chungnam National University, Daejeon 34134, Korea
    **Applied Chemistry and Biological Engineering, Chungnam National University, Daejeon 34134, Korea
    ***Samyang Chemical R&D center, Daejeon 34055, Korea

  • 핵제가 폴리프로필렌 복합재의 스크래치와 광택 특성에 미치는 영향
  • 오아롬 · 유경철* · 박정진* · 김대식 · 유경민 · 이선영** · 이재민*** · 이승구*,†

  • 현대자동차 연구개발본부, *충남대학교 유기응용재료공학과, **충남대학교 바이오응용화학연구소, ***삼양사 화학연구소

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

Abstract

Polypropylene (PP) composites are widely employed in automotive interior materials but are prone to surface scratches that adversely affect gloss. This study investigated the impact of crystallographic properties on the scratch resistance of PP composites with the incorporation of nucleating agents. The effects were comprehensively analyzed; scratch and mechanical properties are analyzed using techniques such as differential scanning calorimetry (DSC), X-ray diffraction analysis (XRD), confocal laser microscopy, glossmetry, and mechanical testing. Isothermal crystallization experiments revealed that β nucleating agents delayed both crystallization initiation and termination. Avrami constant, n falls within the range of 3 < n < 4, indicating three-dimensional crystal growth. Consequently, the application of β nucleating agents significantly minimizes changed in gloss properties following scratches, attributed to reduced surface roughness alterations. This study underscored the pivotal role of nucleating agents in enhancing the scratch resistance and preserving the surface quality of PP composites for automotive interiors.


자동차 내장재로 사용되는 폴리프로필렌 복합재는 표면 스크래치가 발생하기 쉬우며, 이는 광택에 악영향을 미친다. 이번 연구에서는 PP 복합재에 첨가한 핵 형성제에 따라 결정학적 특성이 스크래치 저항성에 미치는 영향을 조사하였다. 시차주사열량분석(DSC), X-선 회절분석(XRD), 공초점 레이저현미경, 광택측정기, 기계적 물성 시험 등을 사용하여 스크래치 및 기계적 특성을 종합적으로 분석하였다. 등온결정화 실험을 통해 β 핵제가 결정화의 시작과 종료를 모두 지연시킨다는 사실을 확인하였다. Avrami 상수 'n'은 3 < 'n' < 4 범위 내에 속하며, 이는 PP 복합재의 3차원 결정 성장을 나타낸다. β 핵제를 적용하면 표면거칠기 감소로 인해 스크래치 후 광택특성의 변화를 크게 최소화할 수 있었다.


Keywords: nucleating agent, scratch, Avrami constant, crystallization, polypropylene composites, automobile material.

  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2024; 48(2): 171-178

    Published online Mar 25, 2024

  • 10.7317/pk.2024.48.2.171
  • Received on Sep 27, 2023
  • Revised on Dec 7, 2023
  • Accepted on Dec 21, 2023

Correspondence to

  • Seung Goo Lee
  • Department of Applied Organic Materials Engineering, Chungnam National University, Daejeon 34134, Korea

  • E-mail: lsgoo@cnu.ac.kr