Article
  • Physical and Physico-mechanical Properties of Elastomers Based on Urethane Oligomers with Terminal Epoxy Groups as Affected by the Structure of Diisocyanates and Diamines

  • Anna V. Savchuk*,† , Aleksey I. Slobodinyuk , Valery Yu. Senichev , and Vladimir N. Strelnikov

  • Institute of Technical Chemistry of Ural Branch of the RAS as Affiliated Branch of Perm Federal Research Center of Ural Branch of the RAS Acad., Korolev St. 3, 614013 Perm, Russian Federation

  • Diisocyanate와 Diamine의 구조가 미치는 Epoxy 말단을 갖는 우레탄 올리고머 기반 탄성체의 물리적 특성 연구

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

Abstract

There were investigated physical and physico-mechanical properties of elastomers based on three series of epoxy-terminated oligomers based on differently structured diisocyanates and diamines. The use of 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate enabled better strength properties to be obtained owing to the implementation of the strengthening effect. Also, there was elicited a positive influence of an increase in the content of 3-aminomethyl-3,5,5-trimethylcyclohexylamine in a mixture of hardeners on the strength of elastomers; it was associated with enhancing polarity of a polymer chain, therewith giving rise to changes in the phase separation degree.


Keywords: hard segments, soft segments, Fourier transform infrared spectrum, swelling, polyurethane, oligoetherurethane diepoxide, network density, glass transition temperature, physical and mechanical properties, phase separation.

  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2022; 46(6): 766-774

    Published online Nov 25, 2022

  • 10.7317/pk.2022.46.6.766
  • Received on Jun 24, 2022
  • Revised on Aug 22, 2022
  • Accepted on Aug 24, 2022

Correspondence to

  • Anna V. Savchuk

  • Institute of Technical Chemistry of Ural Branch of the RAS as Affiliated Branch of Perm Federal Research Center of Ural Branch of the RAS Acad., Korolev St. 3, 614013 Perm, Russian Federation

  • E-mail: ataraksa@mail.ru