Article
  • Bio-based Epoxy Thermoset Containing Stilbene Structure with Ultrahigh Tg and Excellent Flame Retardancy

  • Guangming Lu*, **, ***, Xuezhen Wang**, Na Teng**, Jingyuan Hu**, Liyue Zhang**, Jinyue Dai**, ****,† , Yongjia Xu*,† , Sakil Mahmud**, and Xiaoqing Liu**

  • *School of Marine Sciences, Ningbo University, Ningbo 315820, PR China
    **Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, PR China
    ***Key Laboratory of Marine Materials and Related Technologies, Key Laboratory of Marine Materials and Protective Technologies of Zhejiang Province, Ningbo 315201, PR China
    ****University of Chinese Academy of Sciences, Beijing 100049, China

  • Stilbene 구조를 지닌 바이오 기반 에폭시 열경화성 수지의 높은 Tg 및 난연성

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

Abstract

Bio-based epoxy resins with an ultrahigh glass transition temperature (Tg) and excellent flame retardancy are critical for developing sustainable polymers. Herein, a novel trifunctional epoxy monomer triglycidyl ether of resveratrol (TGER) was synthesized from renewable resveratrol. The chemical structure of TGER was confirmed by Fourier transform infrared (FTIR), 1H, and 13C nuclear magnetic resonance (NMR) spectroscopy which was then reacted with 4,4'-diaminodiphenylmethane (DDM) to form resin. The obtained resin was evaluated in terms of flame retardance and thermal properties. The resultant TGER-DDM 240 resin shows excellent flame-retardant properties, presenting a residual char of 42.5% at 800 °C, limiting oxygen index (LOI) of 31.2%, and flammability rating of V-0 in UL94 test. Moreover, the resin possesses an ultrahigh Tg at 294 °C. This work provides a facile method for preparing high-performance flame-retardant epoxy resin from a renewable resource.


Keywords: bio-based, stilbene structure, flame retardancy, epoxy resin.

  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2021; 45(4): 581-591

    Published online Jul 25, 2021

  • 10.7317/pk.2021.45.4.581
  • Received on Mar 4, 2021
  • Revised on Apr 4, 2021
  • Accepted on Apr 6, 2021

Correspondence to

  • Jinyue Dai**, **** , Yongjia Xu*

  • *School of Marine Sciences, Ningbo University, Ningbo 315820, PR China
    **Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, PR China
    ****University of Chinese Academy of Sciences, Beijing 100049, China

  • E-mail: daijinyue@nimte.ac.cn, xuyongjian@nbu.edu.cn