Zeyneb Hamadi*,**,† , Rabah Chaid*, Mohammed Kebir**,***,
Siham Amirou****, Hisham Essawy*****, and Antonio Pizzi****
*Faculty of
engineering, Research Unit Materials, Processes and Environment URMPE,
University M’hamed Bougara of Boumerdes/FSI, Frantz Fanon City, Indépendance
Avenue 35000 Boumerdes, Algeria
**Research Unit
on Analysis and Technological Development in Environment (URA-DTE/ CRAPC),
BP 384, 42000 Bou-Ismail, Tipaza. Algeria
***Laboratory of
Reaction Engineering, FGMGP/USTHB, BP 32, 16111 Algiers, Algeria
****LERMAB,
University of Lorraine, EA 4370, 27 rue Philippe Séguin, BP 21042, 88051 Epinal
cedex 9, France
*****Department of Polymers and Pigments, National Research Centre, Dokki 12622,
Cairo, Egypt
In this study, new adsorbent
tannin foam was prepared from Algerian natural pinus halepensis tannin (APTF).
The prepared material has been used as an efficient and environmentally
friendly adsorbent to remove chromium (Cr(VI)), which is considered as the most
toxic pollutant in wastewater. The different features of the adsorbent in terms
of the structural and morphological characteristics were studied. The impact of
different factors on the adsorption process, such as pH, adsorbent mass,
initial Cr(VI) concentration, and temperature, was investigated. The data
obtained from the Cr(VI) adsorption revealed an improvement of the removal
efficiency with increasing the adsorbent dose, the pH had a notable effect on
Cr(VI) adsorption capacity, whereas the effectiveness decreased by rising the
initial metal concentration. In addition, it was observed that adsorption
efficiency enhanced with increasing temperature, indicating that the adsorption
was endothermic and spontaneous in nature. Moreover, the results were best
represented by the pseudo-second order kinetic model and the Langmuir isotherm
model (qm = 400 mg·g-1) at
293 °K and pH ~2.
Keywords: adsorption, foam, Cr(VI), isotherms, kinetics
2020; 44(4): 425-435
Published online Jul 25, 2020
*Faculty of engineering, Research Unit Materials, Processes and Environment URMPE, University M’hamed Bougara of Boumerdes/FSI, Frantz Fanon City, Indépendance Avenue 35000 Boumerdes, Algeria
**Research Unit on Analysis and Technological Development in Environment (URA-DTE/ CRAPC),
BP 384, 42000 Bou-Ismail, Tipaza. Algeria