Department of Chemical Engineering, Firat University, 23279, Elazig, Turkey
Acrylamide-based hydrogels
were used to remove cationic Basic Blue 3 (BB3) dye from aqueous solutions, in
this study. First, acrylamide-based hydrogel was synthesized and characterized
using SEM, FTIR and swelling analysis. The effects of various parameters were
investigated to determine the removal of the BB3 dye from aqueous solutions.
The sorption yield of BB3 dye of the hydrogel was determined to be 99%. The
desorption efficiency was found to be above 90%. The sorption experimental data
were evaluated using applying the Langmuir, Freundlich, Temkin, and
Dubinin-Radushkevich (D-R) isotherm models. It was determined that the Langmuir
was more suitable for isotherm the process. The maximum sorption capacity was
calculated as 28.3 mg/g. Pseudo first order, pseudo second order,
intraparticle diffusion, and Endovich kinetic models were used to calculate the
kinetic parameters. It was concluded that the pseudo second-order kinetic model
was described by the adsorption data very well.
Keywords: hydrogel, swelling ratios, sorption, kinetic and thermodynamic evaluation
2020; 44(1): 49-60
Published online Jan 25, 2020
Department of Chemical Engineering, Firat University, 23279, Elazig, Turkey