Article
  • Free Radical Copolymerization of Diphenylvinylphosphine Oxide with Acrylonitrile and Vinyl Acetate
  • Jin JI, Shim HK
  • 디페닐비닐산화포스핀과 아크릴로니티릴 및 초산비닐의 자유라디칼 공중합
  • 진정일, 심홍구
Abstract
Free radical-initiated copolymerization of diphenylvinylphosphine oxide(DPVPO) with acrylonitrile(AN) and vinyl acetate (VAc) were studie& The monomer reactivity ratios for the monomer pairs determined at 70℃ using benzoyl peroxide as an initiator were: r1(AN)=3.8, r2(DPVPO)=0.16 and r1(VAc)=0.38, r12/sub>(DPVPO)=1.7. The values of the Alfrey-Price constants, Q and e, for DPVPO were calculated to be 0.068 and 0.49, respectively, from the AN-DPVPO system, and 0.059 and 0.44, respectively, from VAc-DPVPO pair. The reduced viscosity of copolymers decreased as the content of DPVPO units increased for both systems.

  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 1985; 9(4): 301-306

    Published online Aug 25, 1985