Article
  • Synthesis of Hydrogel Hollow Capsules on a Superhydrophobic Surface
  • Song M, Lee J, Seo KD, Kim DS, Chang ST
  • 초소수성 표면을 이용한 하이드로젤 중공 캡슐 제조
  • 송민영, 이지영, 서경덕, 김동성, 장석태
Abstract
A single-step synthetic method for preparing hydrogel hollow capsules on a superhydrophobic surface was successfully developed. Aqueous microdroplets of a mixture of hydrogel monomer and cross-linker solutions were deposited on the superhydrophobic surface, which was situated under the hydrocarbon oil layer containing photoinitiator. When exposed to UV light, the aqueous microdroplets were converted to hollow capsules with a polymerized hydrogel shell, formed due to the diffusion of photoinitiators at the oil/water interface. This method for producing hydrogel hollow capsules on superhydrophobic surfaces is simple and efficient, rendering easy encapsulation of colloidal nanoparticles, drugs, or biological cells.

초소수성 표면을 이용하여 간단하고 빠르게 하이드로젤 중공 캡슐을 제작하는 새로운 방법을 개발하였다. 광개시제를 포함하는 탄화수소 오일 층에 초소수성 성질을 가지는 기판을 위치시키고, 하이드로젤 단량체와 가교제를 함유한 마이크로 리터 부피의 droplet을 초소수성 표면에 형성하였다. UV light를 초소수성 표면에 조사하여 droplet 의 물과 오일 계면에서 광개시제의 확산으로 일어난 광중합반응을 통해 형성된 하이드로젤 중공 캡슐을 제조하였다. 이러한 간단하고 효과적인 초소수성 표면 위에서 하이드로젤 중공 캡슐을 제작하는 방법은 콜로이드 나노 입자, 약물, 또는 세포 등을 쉽게 캡슐화하는데 활용될 것으로 전망된다.

Keywords: hydrogel; superhydrophobic surface; hollow capsule; photopolymerization

References
  • 1. Chu LY, Yamaguchi T, Nakao S, Adv. Mater., 14(5), 386 (2002)
  •  
  • 2. Nayak S, Gan DJ, Serpe MJ, Lyon LA, Small, 1, 416 (2005)
  •  
  • 3. Sukhorukov G, Fery A, Mohwald H, Prog. Polym. Sci, 30, 885 (2005)
  •  
  • 4. Qianm J, Wu FP, Chem. Mater., 19, 5839 (2007)
  •  
  • 5. Choi CH, Jung JH, Kim DW, Chung YM, Lee CS, Lap Chip, 8, 1544 (2008)
  •  
  • 6. Lee CC, Lee J, Polym. Korea, 38(5), 626 (2014)
  •  
  • 7. Wang L, Ren J, Zhang X, Yang X, Yang W, Polym. Korea, 39(3), 359 (2015)
  •  
  • 8. Pyun DK, Lim YH, An JH, Kim D, Lee DS, Polym. Korea, 20(2), 335 (1996)
  •  
  • 9. Wicherle O, Lim D, Nature, 185, 117 (1960)
  •  
  • 10. Lim F, Sun AM, Science, 210, 908 (1980)
  •  
  • 11. Yun JP, Park YH, Lee S, Park KH, Lee CJ, Polym. Korea, 27(2), 159 (2003)
  •  
  • 12. Ono Y, Shikata T, J. Phys. Chem. B, 111(7), 1511 (2007)
  •  
  • 13. Wu C, Wang WH, Phys. Rev. Lett., 80, 4092 (1998)
  •  
  • 14. Khang G, Kim MS, Cho SH, Lee HB, Chang JH, Kim KJ, Polym. Sci. Technol., 14(4), 431 (2003)
  •  
  • 15. Yoon H, Lee J, Polym. Korea, 36(4), 455 (2012)
  •  
  • 16. Yuet KP, Hwang DK, Haghgooie R, Doyle PS, Langmuir, 26, 4281 (2009)
  •  
  • 17. Lee MH, Prasad V, Lee D, Langmuir, 26(4), 2227 (2010)
  •  
  • 18. Lee NR, Kim ST, Ko Y, Kim NH, Chang ST, Chem. Lett., 42(10), 1288 (2013)
  •  
  • 19. Kim B, Lee HS, Kim J, Kim SH, Chem. Commun., 49, 1865 (2013)
  •  
  • 20. Kim ST, Cho SR, Song M, Chang ST, Polym. Korea, 39(4), 588 (2015)
  •  
  • 21. Halldorsson S, Lucumi E, Gomez-Sjoberg R, Rleming RMT, Biosens. Bioelectron., 63, 218 (2015)
  •  
  • 22. Whitesides GM, Nature, 442, 368 (2006)
  •  
  • 23. Cheng CJ, Chu LY, Ren PW, Zhang H, Hu L, J. Colloid Interface Sci., 313(2), 383 (2007)
  •  
  • 24. Vladisavljevic GT, Schubert H, J. Membr. Sci., 225(1-2), 15 (2003)
  •  
  • 25. Rastogi V, Garcia AA, Marquez M, Velev OD, Macromol. Rapid Commun., 31(2), 190 (2010)
  •  
  • 26. Rastogi V, Melle S, Calderon OG, Garcia AA, Marquez M, Velev OD, Adv. Mater., 20(22), 4263 (2008)
  •  
  • 27. Jin MH, Feng XJ, Xi JM, Zhai J, Cho KW, Feng L, Jiang L, Macromol. Rapid Commun., 26(22), 1805 (2005)
  •  
  • 28. Anseth KS, Wang CM, Bowman CN, Polymer, 35(15), 3243 (1994)
  •  
  • 29. Otake K, Inomata H, Konno M, Saito S, Macromol. Rapid Commun., 23, 283 (1990)
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2016; 40(5): 781-785

    Published online Sep 25, 2016

  • 10.7317/pk.2016.40.5.781
  • Received on May 8, 2016
  • Accepted on May 21, 2016