Article
  • Shape-Stabilized Phase Change Materials: Preparation and Properties of Frozen Gels from Polypropylene and n-Eicosane for Latent Heat Storage
  • Son T, Lim H, Kim T, Ko JW
  • 형태안정성 PCM: 잠열저장을 위한 Polypropylene과 n-Eicosane으로 구성된 고화젤의 제조 및 특성
  • 손태원, 임학상, 김태훈, 고재왕
Abstract
Phase change materials based on polypropylene blended with n-eicosane were studied in this paper. In addition, this paper reviews recent studies on the preparation of shape stabilized phase change materials (SSPCM), such as SSPCM from polypropylenes and n-eicosane, their basic properties and possible applications to latent heat storage. The preparation methods used were the melting method and absorption methods. Shape stabilized PCM(SSPCM) prepared for DSC, WAXD, FTIR spectroscopy, ARES, results of the analysis of shape stability heat capacity to improve were identified.

본 연구에서는 상전이 온도가 36 ℃인 n-eicosnae을 열가소성 폴리올레핀 고분자인 폴리프로필렌과 블렌드 하였으며, 또한 최근의 형태안정성 PCM(SSPCM)의 연구검토를 통하여 폴리프로필렌과 n-eicosnae의 특성과 잠열저장체로서의 적용 가능성을 확인하였다. 상전이 온도가 36 ℃인 n-eicosane과 폴리프로필렌을 멜팅방법과 흡수방법을 이용하여 시료를 제조하였다. 제조된 형태안정성 PCM(SSPCM)을 DSC, WAXD, FTIR spectroscopy, ARES로 분석결과 형태안정성, 열용량의 향상을 확인하였다.

Keywords: phase change material(PCM); polypropylene; n-eicosanes; frozen gel; latent heat; SSPCM; melt index(melt flow index)

References
  • 1. Beginn U, Macromol. Mater. Eng., 288, 245 (2003)
  •  
  • 2. HIMRAN S, SUWONO A, MANSOORI GA, Energy Sources, 16(1), 117 (1994)
  •  
  • 3. Bo RH, Gustafsson EM, Setterwall F, Energy(Oxford), 24, 1015 (1995)
  •  
  • 4. Salyer IOUS Pat. 5,053,446 (1991)
  •  
  • 5. Salyer IOUS Pat. 5,885,475 (1999)
  •  
  • 6. Sari A, Energy Conv. Manag., 45(13-14), 2033 (2004)
  •  
  • 7. Bryant YG, Colvin DPUS Pat. 5499460 (1996)
  •  
  • 8. Cox R, Chem. Fibers Int., 48, 475 (1998)
  •  
  • 9. HIMRAN S, SUWONO A, MANSOORI GA, Energy Sources, 16(1), 117 (1994)
  •  
  • 10. Holmen A, J. Phys. Chem. A, 101(24), 4361 (1997)
  •  
  • 11. Mulligan JC, Colvin DP, Bryant YG, Spacecraft Rockets, 33, 278 (1996)
  •  
  • 12. Yamagishi Y, Takeuchi H, Pyatenko AT, Kayukawa N, AIChE J., 45(4), 696 (1999)
  •  
  • 13. Zhang Y, Jiang Y, Measurement and Science Technology, 10, 201 (1996)
  •  
  • 14. Zhang YP, Lin KP, Yang R, Di HF, Jiang Y, Energy Build., 38(10), 1262 (2006)
  •  
  • 15. Pushaw JUS Pat. 5,677,048 (1997)
  •  
  • 16. Krupa I, Mikova G, Luyt S, Eur. Polym. J., 43, 895 (2007)
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2010; 34(3): 261-268

    Published online May 25, 2010

  • Received on Jan 8, 2010
  • Accepted on Jan 27, 2010