Article
  • Synthesis and Photopolymerization of Discotic Liquid Crystals Containing Hydrogen Bondings and Two Polymerizable Groups
  • Lee JH, Lee SJ, Jang J, Jho JY
  • 두 종류의 중합기와 수소결합을 가지는 원반형 액정의 합성과 광중합
  • 이준협, 이승준, 장지선, 조재영
Abstract
Polymerizable discotic liquid crystals containing diacetylene and acryloyl groups were formed through hydrogen bonding between phloroglucinol core and polymerizable pyridine derivatives, and their photopolymerization behavior was investigated. The discotic complexes exhibited discotic columnar and rectangular columnar mesophases depending on the number of aromatic rings. Photopolymerization of the discotic complexes was carried out by UV irradiation in the liquid crystalline state. IR and UV-Vis spectroscopy affirmed that diacetylene and acryloyl groups were selectively polymerized, and that crosslinked polymers containing short conjugated diacetylene oligomers were produced by 1,4-addition. X-ray diffraction experiment showed that the columnar order in the discotic complex containing phenylpyridine moiety was maintained after photopolymerization, and that the rectangular columnar order in the discotic complex with biphenyl units was changed to the lamellar order.

플로로글루시놀과 중합가능한 피리딘 유도체의 수소결합을 이용해 디아세틸렌과 아크릴로일 그룹을 함유한 새로운 중합가능한 원반형 액정들을 제조하였고 제조된 액정들의 광중합 거동을 조사하였다. 합성된 원반형 액정 복합체들은 메소겐의 방향족 고리의 개수에 따라 원반형 컬럼상과 장방형 컬럼상을 형성하였다. 원반형 액정 복합체들의 광중합은 액정상에서 자외선을 조사하여 수행하였다. 자외선 조사 후 디아세틸렌과 아크릴로일 그룹이 선택적으로 중합되었으며, 짧은 공액구조의 디아세틸렌 올리고머를 가지는 가교 고분자들이 1,4-반응에 의해 형성됨을 적외선 분광법과 자외선-가시광선 분광분석을 통해 확인하였다. X-선 회절 실험 결과, 페닐피리딘을 함유한 원반형 액정 복합체의 컬럼상 질서는 광중합 후에도 유지되었고, 바이페닐 단위를 지닌 액정 복합체의 장방형 컬럼상 질서는 라멜라 질서로 변화됨을 확인하였다.

Keywords: discotic liquid crystal; hydrogen bonding; photopolymerization

References
  • 1. Gin DL, Gu W, Pindzola BA, Zhou WJ, Accounts Chem. Res., 34, 973 (2001)
  •  
  • 2. Favrenicolin CD, Lub J, Macromolecules, 29(19), 6143 (1996)
  •  
  • 3. Okazaki M, Kawata K, Nishikawa H, Negoro M, Polym. Adv. Technol., 11, 398 (2000)
  •  
  • 4. Theissen U, Zilker SJ, Pfeuffer T, Strohriegl P, Polym. Adv. Technol., 11, 398 (2000)
  •  
  • 5. Bacher A, Erdelen CH, Paulus W, Ringsdorf H, Schmidt HW, Schuhmacher P, Macromolecules, 32(14), 4551 (1999)
  •  
  • 6. Kim BG, Kim S, Seo J, Oh NK, Zin WC, Park SY, Chem. Commun., 2306 (2003)
  •  
  • 7. Cho HJ, Seo K, Lee CJ, Yun H, Chang JY, J. Mater. Chem., 13, 986 (2003)
  •  
  • 8. Chang JY, Baik JH, Lee CB, Han MJ, Hong SK, J. Am. Chem. Soc., 119(13), 3197 (1997)
  •  
  • 9. Chang JY, Yeon JR, Shin YS, Han MJ, Hong SK, Chem. Mater., 12, 1076 (2000)
  •  
  • 10. Hwang IH, Lee SJ, Chang JY, J. Polym. Sci. A: Polym. Chem., 41(13), 1881 (2003)
  •  
  • 11. Lee CH, Jeong HH, Nam KD, Kitamura T, J. Ind. Eng. Chem., 5(1), 40 (1999)
  •  
  • 12. Pindzola BA, Hoag BP, Gin DL, J. Am. Chem. Soc., 123(19), 4617 (2001)
  •  
  • 13. Hoag BP, Gin DL, Macromolecules, 33(23), 8549 (2000)
  •  
  • 14. Schultz JW, Chartoff RP, Polymer, 39(2), 319 (1998)
  •  
  • 15. Ukon M, Sugino T, Watanabe T, Monobe H, Shimizu Y, Macromol. Mater. Eng., 287, 698 (2002)
  •  
  • 16. Baxter BC, Gin DL, Macromolecules, 31(14), 4419 (1998)
  •  
  • 17. Boden N, Bushby RJ, Clements J, Jesudason MV, Knowles PF, Williams G, Chem. Phys. Lett., 152, 94 (1988)
  •  
  • 18. Feng XS, Pan CY, Chem. Phys. Chem., 3, 539 (2002)
  •  
  • 19. Hayashi T, Konishi M, Kobori Y, Kumada M, Higuchi T, Hirotsu K, J. Am. Chem. Soc., 106, 158 (1984)
  •  
  • 20. Sato A, Kato T, Uryu T, J. Polym. Sci. A: Polym. Chem., 34(3), 503 (1996)
  •  
  • 21. Barbera J, Gimenez R, Serrano JL, Chem. Mater., 12, 481 (2000)
  •  
  • 22. Zheng H, Lai CK, Swager TM, Chem. Mater., 12, 481 (2000)
  •  
  • 23. Barentsen HM, van Dijk M, Kimkes P, Zuilhof H, Sudholter EJR, Macromolecules, 32(6), 1753 (1999)
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2006; 30(5): 373-379

    Published online Sep 25, 2006

  • Received on Apr 11, 2005
  • Accepted on Sep 20, 2006