Invited Article

Synthesis of Novel Aromatic Polyimides
Shin GJ, Chi JH, Zin WC, Chang T, Ree M, Jung JC
새로운 방향족 폴리이미드의 합성
신교직, 지준호, 진왕철, 장태현, 이문호, 정진철

Abstract

In spite of excellent thermomechanical performance the majority of aromatic polyimides are so poor in processability due to their high backbone rigidity that their applications are greatly limited. The introduction of long side chains not only enhances their processiblity but also makes useful contribution to discovering new application fields. In this article, a variety of novel aromatic polyimides with flexible side chains were prepared either from new diamines or new dianhydrides to measure the influence of the side chains on structure and properties of the polymers and their new applications as liquid crystal alignment layers, photosensitive polymers, alternating multilayer nano-films and photoluminescent materials are discussed.

방향족 강직사슬 폴리이미드는 높은 주사슬 간의 인력으로 인해 유기용제에 용해되지 않고 상전이온도가 분해 온도보다 높아 응용분야에 많은 제한이 되고 있다. 방향족 폴리이미드의 가공성을 향상시키기 위해서 긴 곁사슬을 도입 하면 가공성 향상뿐만 아니라 곁사슬과 주사슬 사이에 독특한 구조를 가지게 됨으로써 새로운 응용분야를 개척할 수가 있다. 본 논문에서는 여러 가지 형태의 곁사슬을 가지는 방향족 폴리이미드의 합성과 화학구조에 따른 물성변화에 대해 논의하고 또한 폴리이미드의 액정배향막, 감광재료, 교대 다층박막, 발광재료 등으로의 응용특성에 관해서도 조감한다.

Keywords: polyimide; liquid crystal alignment layer; photosensitive polyimide; photoluminescent polyimide; aromatic polyimide

References

1. Borgert MT, Renshaw RR, J. Am. Chem. Soc., 30, 1135 (1908)
2. Cassidy PEThermally Stable Polymers Marcel Dekker inc., New York and Basel (1980)
3. Ghosh MK, Mittal KL, EdsPolyimides: Fundamentals and Applications, Marcel, Dekker, New York (1996)
4. Dine-Hart RA, Macromol. Chem., 153, 237 (1972)
5. Gibbs HH, Breder CV, Polym. Prepr., 15, 775 (1974)
6. Clare TL, Smith EN, Polym. Prepr., 17, 359 (1976)
7. Imai Y, Malder NN, Kakimoto MA, J. Polym. Sci. A: Polym. Chem., 22, 2189 (1993)
8. Korshak VV, Vinogradova SV, Vygidskii YS, J. Macromol. Sci., Rev. Macromol. Chem, 45, C11 (1974)
9. Harris FW, Sakaguchi YProc 3rd Int Conference in Polyimides, Ellenville, 25 (1988)
10. Harris FW, Norris SO, J. Polym. Sci. A: Polym. Chem., 11, 2143 (1973)
11. Scola DA, J. Polym. Sci. A: Polym. Chem., 31, 1993 (1997)
12. Edwards WM, Robinson IMUS Patents 2710853 (1955)
13. Trofimenko S, Auman BC, Macromolecules, 27(5), 1136 (1994)
14. Jung JC, Park SB, J. Polym. Sci. A: Polym. Chem., 34(3), 357 (1996)
15. Ballauf M, Schmidt GF, Macromol. Rapid Commun., 8, 93 (1984)
16. Lee KH, Jung JC, Polym. Bull., 40(4-5), 407 (1998)
17. Kricheldorf HREd. Adv. Polym. Sci., Progress in Polyimide Chemistry I, 140 (1999)
18. Nosova GI, Zhukova TI, Koton MM, Laius LA, Sazanov YN, Vysokomol. Soedin. Ser., A26, 998 (1984)
19. Nosova GI, Vysokomol. Soedin. Ser., A34, 7 (1992)
20. Williams FJ, Relles HMU.S. Pat. 4,297,474 (1981)
21. Mandal BK, Maiti S, J. Polym. Mater., 2, 115 (1985)
22. Maiti S, Mandal BK, Prog. Polym. Sci, 12, 111 (1986)
23. Im JKPh. D. Thesis, POSTECH, Korea (2000)
24. Im JK, Jung JC, Polym. Bull., 43(2-3), 157 (1999)
25. Im JK, Jung JC, J. Polym. Sci. A: Polym. Chem., 38(3), 402 (2000)
26. Im JK, Jung JC, J. Polym. Sci. A: Polym. Chem., 37(17), 3530 (1999)
27. Im JK, Jung JC, Polym. Bull., 41(4), 409 (1998)
28. Yang CP, Chen WT, Macromolecules, 26, 4865 (1993)
29. Ballauff M, Macromol. Rapid Commun., 7, 407 (1986)
30. Ballauff M, Schmidt GF, Mol. Cryst. Liq. Cryst., 147, 163 (1987)
31. Berger K, Ballauff M, Mol. Cryst. Liq. Cryst., 148, 109 (1988)
32. Ballauff M, Schmidt GF, Macromol. Rapid Commun., 8, 93 (1987)
33. Wenzel M, Ballauff M, Wegner G, Makromol. Chem., 188, 2865 (1987)
34. Schmitz L, Ballauff M, Polymer, 36(4), 879 (1995)
35. Choi KHPh. D. Thesis, POSTECH, Korea (2004)
36. Rodriguez PJM, Macromolecules, 22, 2507 (1989)
37. Ballauff M, Macromolecules, 19, 1366 (1986)
38. Kim H, Park SB, Jung JC, Zin WC, Polymer, 37(13), 2845 (1996)
39. Lee SJ, Jung JC, Lee SW, Ree M, J. Polym. Sci. A: Polym. Chem., 42(13), 3130 (2004)
40. Kim DH, Jung JC, Polym. Bull., 50(5-6), 311 (2003)
41. Jung JC, Park SB, J. Polym. Sci. A: Polym. Chem., 34(3), 357 (1996)
42. Kim YS, Jung JC, J. Polym. Sci. A: Polym. Chem., 40(11), 1764 (2002)
43. Lee KHPh. D.Thesis, POSTECH, Korea (1998)
44. Kim DHPh. D. Thesis, POSTECH, Korea (2003)
45. van Aerle NAJM, Tol AJW, Macromolecules, 27(22), 6520 (1994)
46. Chae B, Kim SB, Lee SW, Kim SI, Choi W, Lee B, Ree M, Lee KH, Jung JC, Macromolecules, 35(27), 10119 (2002)
47. Lee KW, Paek SH, Lien A, Durning C, Fukuro H, Macromolecules, 29(27), 8894 (1996)
48. Park JH, Sohn BH, Jung JC, Lee SW, Ree M, J. Polym. Sci. A: Polym. Chem., 39(10), 1800 (2001)
49. Park JH, Jung JC, Sohn BH, Lee SW, Ree M, J. Polym. Sci. A: Polym. Chem., 39(20), 3622 (2001)
50. Shin GJ, Thesis BSPOSTECH, Korea (2003)
51. Baur G, Wittwer V, Phys. Lett. A, 56A, 142 (1976)
52. Sugiyama T, Kuniyashi S, Seo DS, Hiroyoshi F, Kobayashi, Jpn. J. Appl. Phys., 37, 2909 (1990)
53. Arafune R, Sakamoto K, Ushioda S, Appl. Phys. Lett., 71, 2755 (1997)
54. Ban BS, Rim YN, Kim YB, Liq. Cryst., 27, 125 (2000)
55. Lee SW, Chae B, Lee B, Choi W, Kim SB, Kim IS, Park SM, Jung JC, Ree M, Chem. Mater., 15, 3105 (2003)
56. Chae B, Lee SW, Lee B, Choi WY, Kim SB, Jung YM, Jung JC, Lee KH, Ree M, Langmuir, 19(22), 9459 (2003)
57. Lee SW, Lee SJ, Hahm SG, Lee TJ, Lee B, Chae B, Kim SB, Jung JC, Zin WC, Sohn BH, Ree M, Macromolecules, 38(10), 4331 (2005)
58. Ree M, Lee SW, Choi W, Chae B, Kim SB, Lee KH, Jung JCAbstracts of Papers of the American Chemical Society 225,479-POLY Part 2 (2003)
59. Chae B, Lee SW, Lee B, Choi W, Kim SB, Jung YM, Jung JC, Lee KH, Ree M, J. Phys. Chem. B, 107(43), 11911 (2003)
60. Lee JKB.S. Thesis, POSTECH, Korea (2004)
61. Lee JK, Jung JC, Ree MSynthesis and Characterization of from 3-[4-(n-alkyloxy)phenyloxy]pyromellitic Dianhydrides and LC Alignment Properties, in preparation
62. Lee SBB.S. Thesis, POSTECH, Korea (2005)
63. Lee SJPh. D. Thesis, POSTECH, Korea (2004)
64. Matsumoto T, Kurosaki T, Macromolecules, 30(4), 993 (1997)
65. Matsumoto T, Kurosaki T, Macromolecules, 28, 5864 (1995)
66. Kim YS, Jung JC, Polym. Bull., 45(4-5), 311 (2000)
67. Kim YS, Jung JC, Polym. Bull., 46(4), 263 (2001)
68. Kim YSPh. D. Thesis, POSTECH, Korea (2001)
69. Ferreira M, Rubner MF, Macromolecules, 28(21), 7107 (1995)
70. Yanjing L, Anbo W, Richard OC, Appl. Phys. Lett., 71, 2265 (1977)
71. Decher G, Science, 277(5330), 1232 (1997)
72. Joly S, Kane R, Radzilowski L, Wang T, Wu A, Cohen RE, Thomas EL, Rubner MF, Langmuir, 16(3), 1354 (2000)
73. Choi KH, Jung JC, Kim HS, Sohn BH, Zin WC, Ree M, Polymer, 45, 1517 (2004)
74. Kotov BV, Russ. J. Phys. Chem., 62, 2709 (1988)
75. Kan L, Kao KC, J. Chem. Phys., 98, 3445 (1993)
76. Park SHB.S.Thesis, POSTECH, Korea (2004)
77. Horie K, Yamashita TEds., Photosensitive polyimides: Fundamentals and Applications, Technomic Publishing Co., Lancaster (1995)
78. Kubota S, Yamawaki Y, Ando T, Fukami A, Macromolecules, A24, 1497 (1987)
79. Kubota S, Yamawaki Y, Moriwaki T, Eto S, Polym. Eng. Sci., 29, 950 (1989)
80. Omote T, Yamaoka T, Polym. Eng. Sci., 32, 1632 (1992)
81. Takano K, Mikogami Y, Nakano Y, Hayase R, Hayase S, J. Appl. Polym. Sci., 40, 3715 (1992)
82. Pfeiffer J, Rhode OAdvences in Polyimide Science and Technology, Society of Plastic Engineering, New York, 336 (1987)
83. Higuchi H, Yamashita T, Horie K, Mita I, Chem. Mater., 3, 188 (1991)
84. Fukushima T, Hosokawa K, Oyama T, Iijima T, Tomoi M, Itatani H, J. Polym. Sci. A: Polym. Chem., 39(6), 934 (2001)
85. Morita K, Ebara K, Shibasaki Y, Ueda M, Goto K, Tamai S, Polymer, 44(20), 6235 (2003)
86. Choi KH, Jung JC, Kim KS, Polym. Adv. Technol., 16, 387 (2005)
87. Shin GJ, Jung JC, Kim KSNew Positive Type Photosensitive Polyimides Having o-Nitrobenzyl ether groups, in preparation
88. Maiti S, Mandal BK, Macromol. Rapid Commun., 6, 841 (1985)

Polymer(Korea) 폴리머
Frequency : Bimonthly(odd)
ISSN 0379-153X(Print)
ISSN 2234-8077(Online)
Abbr. Polym. Korea
2022 Impact Factor : 0.4
Indexed in SCIE

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2006; 30(2): 97-107

Published online Mar 25, 2006

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