Article
  • Thermal and Mechanical Properties of Polyesteramide Elastomer/PBT/Nylon 6 Blends
  • Jeong HM, Moon SW, Jho JY, Ahn TO
  • Polyesteramide 탄성체/PBT/Nylon6 블렌드의 열적 및 기계적 성질
  • 정한모, 문순원, 조재영, 안태완
Abstract
Polyesteramide(PEA) elastomer, whose soft segment was poly(butylene adipate) and whose hard segment was polyamide with some aromaticity, was partially miscible with poly(butylene terephthalate) (PET). The crystallization of PET was enhanced when small quantity of PEA elastomer was blended with PET. In PET/Nylon 6 blends, the PEA elastomer was preferentially dissolved into Nylon 6 phase, and the compatibility between PET phase and Nylon 6 phase was improved by the addition of PEA elastomer.

Soft segment가 poly(butylene adipate)이고 hard segment가 aromaticity를 갖는 폴리아미드인 polyesteramide (PEA) 탄성체는 poly(butylene terephthalate) (PBT)와 부분적 상용성을 가졌으며, PBT의 결정화는 소량의 PEA 탄성체의 첨가에 의해 촉진되었다. PBT/Nylon 6블렌드에 PEA 탄성체를 첨가하는 경우 부분적인 상용화 효과가 관찰되었으며, 이는 PEA 탄성체가 Nylon 6 영역으로 우선적으로 녹아들어가면서 Nylon 6 영역과 PBT 영역의 혼화성을 증대시키기 때문으로 생각되었다.

Keywords: Polyesteramide; PET; Nylon 6; Blend; Compatibility; Crystallization

References
  • 1. Petrovi ZS, Ferguson J, J. Prog. Polym. Sci., 16, 695 (1991)
  •  
  • 2. Gogolewski S, Colloid Polym. Sci., 267, 757 (1989)
  •  
  • 3. Hong J, Lillya CP, Chien JCW, Polymer, 33, 4347 (1992)
  •  
  • 4. Faruque HS, Lacabanne C, J. Mater. Sci., 22, 675 (1987)
  •  
  • 5. Otsuki T, Kakimoto M, Imai Y, J. Polym. Sci. A: Polym. Chem., 29, 611 (1991)
  •  
  • 6. Farrissey WJ, Rausch KW, Elastomerics, July, 22 (1988)
  •  
  • 7. Otsuki T, Kakimoto M, Imai Y, J. Appl. Polym. Sci., 40, 1433 (1990)
  •  
  • 8. Jeong HM, Moon SW, Jho JY, Ahn TO, Polymerin press
  •  
  • 9. Jeong HM, Moon SW, Jho JY, Ahn TO, Polym.(Korea), 20(5), 823 (1996)
  •  
  • 10. Otsuki T, Kakimoto M, Imai Y, Makromol. Chem. Rapid Commun., 8, 637 (1987)
  •  
  • 11. Kim BK, Lee YM, Jeong HM, Polymer, 34, 2075 (1993)
  •  
  • 12. Kim WN, Burns CM, Macromolecules, 20, 1876 (1987)
  •  
  • 13. Bourland LG, Braunstein DM, J. Appl. Polym. Sci., 32, 6131 (1986)
  •  
  • 14. Martuscelli E, Polym. Eng. Sci., 24, 563 (1984)
  •  
  • 15. Choi KJ, Lee GH, Ahn SJ, Shon KH, Kim I, Jeong HM, J. Appl. Polym. Sci., 59(3), 557 (1996)
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 1998; 22(1): 115-120

    Published online Jan 25, 1998