Article
  • The Plasma-Initiated Polymerization of Acrylamide
  • Chung HS, Ahn JJ, Park SB, Kim BK, Shin YJ
  • Acrylamide의 플라즈마 개시 중합
  • 정희실, 안재준, 박상보, 김병규, 신영조
Abstract
The plasma-initiated polymerization of acrylamide in aqueous solution was investigated. The plasma initiation was carried out by a high-frequency generator and the polymer formation process follows the free-radical polymerization mechanism. Several factors which affect the polymerization such as monomer concentrations, plasma durations, post-polymerization temperatures and post-polymerization time were investigated. Dilatometer was used to measure the conversion and the rate of polymerization. The initial rate of polymerization was 10-4 mole/liter-sec to 10-6 mole/liter-sec under various reaction conditions.

고주파 발생장치(High-frequency generator)를 사용하여 발생되는 플라즈마(plasma)를 이용하여 acrylamide(AAM)수용액을 플라즈마 개시중합(plasma-initiated polymerization)하였다. 플라즈마 개시에 의한 중합은 free-radical기구에 의하여 진행되고, 중합에 영향을 미치는 인자인 단량체 농도, 플라즈마 조사시간, 후중합 온도 및 후중합 시간에 대하여 연구하였다. 고분자의 전환율을 이용한 전반응 속도를 측정하기 위하여 dilatometer를 사용하였고 여러가지 반응 조건하에서의 전반응 속도는 10-4mole/liter-sec에서 10-6mole/liter-sec의 값을 나타내었다.

References
  • 1. Osada Y, Bell AT, Shen M, J. Polym. Sci. C: Polym. Lett., 16, 309 (1978)
  •  
  • 2. Johnson DR, Osada Y, Bell AT, Shen M, Macromolecules, 14, 118 (1981)
  •  
  • 3. Osada Y, Shen M, Bell AT, J. Polym. Sci. C: Polym. Lett., 16, 669 (1978)
  •  
  • 4. Osada Y, Hashidzume M, Tsuchida E, Bell AT, Nature, 284, 693 (1979)
  •  
  • 5. Osada Y, Takase M, J. Polym. Sci. C: Polym. Lett., 21, 643 (1983)
  •  
  • 6. Osada Y, Takase M, Mizumoto A, J. Chem. Soc. Jpn., 10, 1685 (1984)
  •  
  • 7. Osada Y, Takase M, Iriyama Y, Polym. J., 15, 81 (1983)
  •  
  • 8. Osada Y, Iriyama Y, Takase M, Kobunshi Ronbunshu, 39, 629 (1981)
  •  
  • 9. Osada Y, Mizumoto A, Macromolecules, 18, 302 (1985)
  •  
  • 10. Allcock HR, Lampe FWContemporary Polymer Chemistry, Prentice-Hall Inc., New Jersey, 277-281 (1981)
  •  
  • 11. Sholten W, Makromol. Chem., 14, 169 (1954)
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 1991; 15(5): 606-613

    Published online Oct 25, 1991