Article
  • Effect of rGO on the Electromagnetic Interference Shielding Performance of Epoxy Composites Incorporating MXene/rGO Fillers

  • Seong Wook Lee, Ji-Soo Kang, Mu Jin Kim, and Keun-Byoung Yoon†

  • Department of Polymer Science and Engineering, Kyongpook National University, Daegu 41566, Korea

  • MXene/rGO 필러를 사용한 에폭시 복합체의 전자기파 차폐 성능에 미치는 rGO의 영향

  • 이승욱 · 강지수 · 김무진 · 윤근병†

  • 경북대학교 고분자공학과

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Liang, C.; Hamidinejad, M.; Ma, L.; Wang, Z.; Park, C. B. Light-weight and Flexible Graphene/SiC-nanowires/Poly(vinylidene fluoride) Composites for Electromagnetic Interference Shielding and Thermal Management. Carbon 2020, 156, 58-66.
  •  
  • 2. Xing, D.; Lu, L.; Xie, Y.; Tang, Y.; Teh, K. S. Highly Flexible and Ultra-thin Carbon-fabric/Ag /Waterborne Polyurethane Film for Ultra-efficient EMI Shielding. Mater. Des. 2020, 185, 108227.
  •  
  • 3. Li, Y.; Liu, J.; Wang, S.; Zhang, L.; Shen, B. Self-templating Graphene Network Composites by Flame Carbonization for Excellent Electromagnetic Interference Shielding. Compos. Pt. B-Eng. 2020, 182, 107615.
  •  
  • 4. Munalli, D.; Dimitrakis, G.; Chronopoulos, D.; Greedy, S.; Long, A. Electromagnetic Shielding Effectiveness of Carbon Fibre Reinforced Composites. Compos. Pt. B-Eng. 2019, 173, 106906.
  •  
  • 5. Shen, B.; Zhai, W.; Zheng, W. Ultrathin Flexible Graphene Film: An Excellent Thermal Conducting Material with Efficient EMI Shielding. Adv. Funct. Mater. 2014, 24, 4542-4548.
  •  
  • 6. Qian, K.; Wu, H.; Fang, J.; Yang, Y.; Miao, M.; Cao, S.; Shi, L.; Feng, X. Yarn-ball-shaped CNF/ MWCNT Microspheres Intercalating Ti3C2Tx MXene for Electromagnetic Interference Shielding Films, Carbohydr. Polym. 2021, 254, 117325.
  •  
  • 7. Miao, M.; Liu, R.; Thaiboonrod, S.; Shi, L.; Cao, S.; Zhang, J.; Fang, J.; Feng, X. Silver Nanowires Intercalating Ti3C2Tx MXene Composite Films with Excellent Flexibility for Electromagnetic Interference Shielding. J. Mater. Chem. C 2020, 8, 3120.
  •  
  • 8. Bao, S.; Zhang, M.; Jiang, Z.; Xie, Z.; Zheng, L. Advances in Microwave Absorbing Materials with Broad-bandwidth Response. Nano Res. 2023, 16, 11054-11083.
  •  
  • 9. Luckham, P. F.; Rossi, S. The Colloidal and Rheological Properties of Bentonite Suspensions. Adv. Colloid Interface Sci. 1999, 82, 43-92.
  •  
  • 10. Wu, Q.; Sjåstad, A. O.; Vistad, Ø. B.; Roots, Jr. K. D.; Pedersen, J. S.; Norby, P. Characterization of Exfoliated Layered Double Hydroxide (LDH, Mg/Al =3) Nanosheets at High Concentrations in Formamide. J. Mater. Chem. 2007, 17, 965-971.
  •  
  • 11. Maleski, K.; Mochalin, V. N.; Gogotsi, Y.; Dispersions of Two-Dimensional Titanium Carbide MXene in Organic Solvents. Chem. Mater. 2017, 29, 1632-1640.
  •  
  • 12. Shahzad, F.; Alhabeb, M.; Hatter, C. B.; Anasori, B.; Hong, S. M.; Koo, C.M.; Gogotsi, Y. Electro-magnetic Interference Shielding with 2D Transition Metal Carbides (MXenes). Science 2016, 253, 1137-1140.
  •  
  • 13. Sun, R.; Zhang, H. B.; Liu, J.; Xie, X.; Yang, R.; Li, Y.; Hong, S.; Yu, Z. Z. Highly Conductive Transition Metal Carbide/Carbonitride (MXene)@ Polystyrene Nanocomposites Fabricated by Electro- static Assembly for Highly Efficient Electromagnetic Interference Shielding. Adv. Funct. Mater. 2017, 27, 1702807.
  •  
  • 14. Liu, J.; Zhang, H. B.; Sun, R.; Liu, Y.; Liu, Z.; Zhou, A.; Yu, Z. Z. Hydrophobic, Flexible, and Lightweight MXene Foams for High-Performance Electromagnetic-interference Shielding. Adv. Mater. 2017, 29, 1702367.
  •  
  • 15. Naguib, M.; Kurtoglu, M.; Presser, V.; Lu, J.; Niu, J.; Heon, M.; Hultman, L.; Gogotsi, Y.; Barsoum, M. W. Two-dimensional Nano-crystals Produced by Exfoliation of Ti3AlC2. Adv. Mater. 2011, 23, 4248-4253.
  •  
  • 16. Mani, V.; Chen, S.-M.; Lou, B.-S. Three- dimensional Graphene Oxide-Carbon Nanotubes and Graphene-Carbon Nanotubes Hybrids. Int. J. Electrochem. Sci. 2013, 8, 11641-11660.
  •  
  • 17. Liu, Y.; Li, J.; Ge, X.; Yi, S.; Wang, H.; Liu, Y.; Luo, J. Macroscale Superlubricity Achieved on the Hydrophobic Graphene Coating with Glycerol. ACS Appl. Mater. Interfaces 2020, 12, 18859-18869.
  •  
  • 18. Sun, X.; Sun, H.; Li, H.; Peng, H. Developing Polymer Composite Materials: Carbon Nanotubes or Graphene. Adv. Mater. 2013, 25, 5153-5176.
  •  
  • 19. Liang, J.; Wang, Y.; Huang, Y.; Ma, Y.; Liu, Z.; Cai, J.; Zhang, C.; Gao, H.; Chen, Y. Electromagnetic Interference Shielding of Graphene/Epoxy Composites. Carbon 2009, 47, 922-925.
  •  
  • 20. Oliveira, F. M.; Luxa, J.; Bouša, D.; Sofer, Z.; Gusmäo, R. Electromagnetic Interference Shielding by Reduced Graphene Oxide Foils. ACS Appl. Nano Mater. 2022, 5, 6792-6800.
  •  
  • 21. Jovanović, S.; Huskić, M.; Kepić, D.; Yasir, M.; Haddadi, K. A Review on Graphene and Graphene Composites for Application in Electromagnetic Shielding. Graphene 2D Mater. 2023, 8, 59-80.
  •  
  • 22. Shen, B.; Li, Y.; Yi, D.; Zhai, W.; Wei, X.; Zheng, W. Microcellular Graphene Foam for Improved Broadband Electromagnetic Interference Shielding. Carbon 2016, 102, 154-160.
  •  
  • 23. Shi, H.; Zhang, C.J.; Lu, P.; Dong, Y.; Wen, P.; Wu, Z.-S. Conducting and Lithiophilic MXene/ Graphene Framework for High-Capacity Dendrite-free lithium-metal Anodes. ACS Nano 2019, 13, 14308-14318.
  •  
  • 24. Zhou, Y.; Maleski, K.; Anasori, B.; Thostenson, J. O.; Pang, Y.; Feng, Y.; Zeng, K.; Parker, C. B.; Zauscher, S.; Gogotsi, Y.; Glass, J. T.; Cao, C. Ti3C2Tx MXene-reduced Graphene Oxide Composite Electrodes for Stretchable Supercapacitors. ACS Nano 2020, 14, 3576-3586.
  •  
  • 25. Lee, S. H.; Eom, W.; Shin, H.; Ambade, R. B.; Bang, J. H.; Kim, H. W.; Han, T. H. Room-temperature, Highly Durable Ti3C2Tx MXene/Graphene Hybrid Fibers for NH3 Gas Sensing. ACS Appl. Mater. Interfaces 2020, 12, 10434-10442.
  •  
  • 26. Zhao, S.; Zhang, H.-B.; Luo, J.-Q.; Wang, Q.-W.; Xu, B.; Hong, S.; Yu, Z.-Z. Highly Electrically Conductive Three-dimensional Ti3C2Tx MXene/ Reduced Graphene Oxide Hybrid Aerogels with Excellent Electromagnetic Interference Shielding Performances. ACS Nano 2018, 12, 11193-11202.
  •  
  • 27. Liu, J.; Liu, Z.; Zhang, H.-B.; Chen, W.; Zhao, Z.; Wang, Q.-W.; Yu, Z.-Z. Ultrastrong and Highly Conductive MXene-based Films for High-Perfor-mance Electromagnetic Interference Shielding. Adv. Electron. Mater. 2020, 6, 1901094.
  •  
  • 28. Zhang, Y.; Gao, Q.; Zhang, S.; Fan, X.; Qin, J.; Shi, X.; Zhang, G. rGO/MXene Sandwich-Structured Film at Spunlace Non-woven Fabric Substrate: Application to EMI Shielding and Electrical Heating. J. Colloid Interface Sci. 2022, 614, 194-204.
  •  
  • 29. Chen, Z.; Asif, M.; Wang, R.; Li, Y.; Zeng, X.; Yao, W.; Sun, Y.; Liao, K. Recent Trends in Synthesis and Applications of Porous MXene Assemblies: A Topical Review. Chem. Rec. 2022, 22, e20210026.
  •  
  • 30. Song, P.; Qiu, H.; Wang, L.; Liu, X.; Zhang, Y.; Zhang, J.L.; Kong, J.; Gu, J. W. Honeycomb Structural rGO-MXene/Epoxy Nanocomposites for Superior Electromagnetic Interference Shielding Performance. Sustain. Mater. Technol. 2020, 24, 200153.
  •  
  • 31. Ren, F.; Zhu, G. M.; Xie, J. Q.; Wang, K.; Cui, X. P. Cyanate Ester Filled with Graphene Nanosheets and Multi-walled Carbon Nanotubes as a Microwave Absorber. J. Polym. Res. 2015, 22, 89.
  •  
  • 32. Meng, F. B.; Wang, H. G.; Huang, F.; Guo, Y. T.; Wang, Z. Y.; Hui, D.; Zhou, Z. Graphene-Based Microwave Absorbing Composites: A Review and Prospective. Compos. Pt. B-Eng. 2018, 137, 260-277.
  •  
  • 33. Wei, Y.; Zhang, P.; Soomro, R. A.; Zhu, Q.; Xu, B. Advances in the Synthesis of 2D MXenes. Adv. Mater. 2021, 33, 2103148.
  •  
  • 34. Hummers Jr., W. S.; Offeman, R. E. Preparation of Graphitic Oxide, J. Am. Chem. Soc. 1958, 80, 1339.
  •  
  • 35. Liu, W.; Speranza, G. Tuning the Oxygen Content of Reduced Graphene Oxide and Effects on Its Properties. ACS Omega 2021, 6, 6195-6205.
  •  
  • 36. Wu, X.; Han, B.; Zhang, H. B.; Xie, X.; Tu, T.; Zhang, Y.; Yu, Z. Z. Compressible, Durable and Conductive Polydimethylsiloxane-coated MXene Foams for High-Performance Electromagnetic Interference Shielding. Chem. Eng. J. 2020, 381, 122622.
  •  
  • 37. Manobalan, S.; Suryasarathi, B.; Sumangala, T. P. Effect of Thickness on the EMI Shielding Effectiveness of Epoxy Composites with Cobalt Ferrite and Graphene. Mater. Today: Proc. 2023, 90, 128-132.
  •  
  • 38. Gudarzi, M. M. Colloidal Stability of Graphene Oxide: Aggregation in Two Dimensions. Langmuir 2016, 32, 5058-5068.
  •  
  • 39. Deville, S.; Saiz, E.; Nalla, R.K.; Tomsia, A. P. Freezing as a Path to Build Complex Composites. Science 2006, 311, 515-518.
  •  
  • 40. Plata-Gryl, M.; Castro-Munoz, R.; Boczkaj, G. Chemically Reduced Graphene Oxide Based Aerogels-Insight on the Surface and Textural Functionalities Dependent on Handling the Synthesis Factors. Colloid Surface A 2023, 675, 132005.
  •  
  • 41. Chen, W.; Yan, L. In Situ Self-Assembly of Mild Chemical Reduction Graphene for Three- Dimensional Architectures. Nanoscale 2011, 3, 3132-3137.
  •  
  • 42. Xu, Z.; Zhang, Y.; Li, P.; Cao, C. Strong, Conductive, Lightweight, Neat Graphene Aerogel Fibers with Aligned Pores. ACS Nano 2012, 6, 7103-7113.
  •  
  • 43. García-Bordejé, E.; Victor-Román, S.; Sanahuja-Parejo, O.; Benito, A. M.; Maser, W. K. Control of the Microstructure and Surface Chemistry of Graphene Aerogels via pH and Time Manipulation by a Hydrothermal Method. Nanoscale 2018, 10, 3526.
  •  
  • 44. Gao, C.; Dong, Z.; Hao, X.; Guo, S. Preparation of Reduced Graphene Oxide Aerogel and Its Adsorption for Pb(II). ACS Omega 2020, 5, 9903-9911.
  •  
  • 45. Yuan, X.; Wei, Y.; Chen, S.; Wang, P.; Liu, L. Bio-based Graphene/Sodium Alginate Aerogels for Strain Sensors. RSC Adv. 2016, 6, 64056-64064.
  •  
  • 46. Liu, J.; Yu, M.-Y.; Yu, Z.-Z.; Nicolosi, V. Design and Advanced Manufacturing of Electro-magnetic Interference Shielding Materials. Mater. Today2023, 66, 245-272.
  •  
  • 47. Li, C.-B.; Li, Y.-J.; Zhao, Q.; Luo, Y.; Yang, G.-Y.; Hu, Y.; Jiang, J.-J. Electromagnetic Interference Shielding of Graphene Aerogel with Layered Microstructure Fabricated via Mechanical Compression. ACS Appl. Mater. Interfaces 2020, 12, 30686-30694.
  •  
  • 48. Cheng, Z.; Wang, R.; Wang, Y.; Cao, Y.; Shen, Y.; Huang, Y.; Chen, Y. Recent Advances in Graphene Aerogels as Absorption-dominated Electromagnetic Interference Shielding Materials. Carbon 2023, 205, 112-137.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2024; 48(4): 403-412

    Published online Jul 25, 2024

  • 10.7317/pk.2024.48.4.403
  • Received on Mar 12, 2024
  • Revised on Apr 27, 2024
  • Accepted on Apr 27, 2024

Correspondence to

  • Keun-Byoung Yoon

  • Department of Polymer Science and Engineering, Kyongpook National University, Daegu 41566, Korea

  • E-mail: kbyoon@knu.ac.kr