Article
  • Synthesis of Cyclohexanedimethanol Pitch Based Plasticizer and Its Application to Poly(vinyl chloride) Fabrication
  • Young-Kwang Han, Min-Chul Cho, Kyung-Hyun No, Sujin Kim, and Jin-Young Bae

  • Department of Polymer Science and Engineering, Sungkyunkwan University, 300 Chunchun-dong, Jangan-gu, Suwon, Gyeonggi-do 16419, Korea

  • Cyclohexanedimethanol Pitch 기반 가소제 합성 및 PVC 적용 연구
  • 한영광 · 조민철 · 노경현 · 김수진 · 배진영

  • 성균관대학교 고분자공학과

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Montero de Espinosa, L.; Gevers, A.; Woldt, B.; Graß, M.; Meier, M. A. R. Sulfur-containing Fatty Acid-based Plasticizers via Thiol–ene Addition and Oxidation: Synthesis and Evaluation in PVC Formulations. Green Chem. 2014, 16, 1883-1896.
  •  
  • 2. Chiellini, F.; Ferri, M.; Morelli, A.; Dipaola, L.; Latini, G. Perspectives on Alternatives to Phthalate Plasticized Poly(vinyl chloride) in Medical Devices Applications. Prog. Polym. Sci. 2013, 38, 1067-1088.
  •  
  • 3. Soong, S. Y.; Cohen, R. E.; Boyce, M. C. Polyhedral Oligomeric Silsesquioxane as a Novel Plasticizer for Poly(vinyl chloride). Polymer. 2007, 48, 1410-1418.
  •  
  • 4. Rahman, M.; Brazel, C. Review: An Assessment of Traditional Plasticizers and Research Trends for Development of Novel Plasticizers. Prog. Polym. Sci. 2004, 29, 1223-1248.
  •  
  • 5. Tüzüm Demir, A.; Ulutan, S. Migration of Phthalate and Non-phthalate Plasticizers Out of Plasticized PVC Films Into Air. J. Appl. Polym. Sci. 2013, 128, 1948-1961.
  •  
  • 6. Jeon, S.; Kim, K.-T.; Choi, K. Migration of DEHP and DINP Into Dust From PVC Flooring Products at Different Surface Temperature. Sci. Total Environment. 2016, 547, 441-446.
  •  
  • 7. Ventrice, P.; Ventrice, D.; Russo, E.; De Sarro, G. Phthalates: European Regulation, Chemistry, Pharmacokinetic and Related Toxicity. Environ. Toxicol. Pharmacol. 2013, 36, 88-96.
  •  
  • 8. Kumar, S. Recent Developments of Biobased Plasticizers and Their Effect on Mechanical and Thermal Properties of Poly(vinyl chloride): a Review. Industrial & Eng. Chem. Res. 2019, 58, 11659-11672.
  •  
  • 9. Bueno-Ferrer, C.; Garrigós, M.; Jiménez, A. Characterization and Thermal Stability of Poly(vinyl chloride) Plasticized with Epoxidized Soybean Oil for Food Packaging. Polym. Degrad. Stab. 2010, 95, 2207-2212.
  •  
  • 10. Kastner, J.; Cooper, D. G.; Marić, M.; Dodd, P.; Yargeau, V. Aqueous Leaching of di-2-ethylhexyl Phthalate and “green” Plasticizers from Poly(vinyl chloride). Sci. Total Environment. 2012, 432, 357-364.
  •  
  • 11. Pyeon, H. B.; Park, J. E.; Suh, D. H. Non-phthalate Plasticizer from Camphor for Flexible PVC with a Wide Range of Available Temperature. Polym. Test. 2017, 63, 375-381.
  •  
  • 12. Jamarani, R.; Erythropel, H. C.; Nicell, J. A.; Leask, R. L.; Marić, M. How Green is Your Plasticizer?. Polymers 2018, 10, 834.
  •  
  • 13. Silva, M. J.; Jia, T.; Samandar, E.; Preau Jr, J. L.; Calafat, A. M. Environmental Exposure to the Plasticizer 1,2-cyclohexane Dicarboxylic Acid, Diisononyl Ester (DINCH) in US Adults (2000-2012). Environ. Res. 2013, 126, 159-163.
  •  
  • 14. SK chemicals. Chromium-free Catalyst and Method for Preparing Cyclohexanedimethanol Using the Same. Kr Patent 10-2021-0091174, 2021.
  •  
  • 15. Turner, S. R. Development of Amorphous Copolyesters Based on 1,4-cyclohexanedimethanol. J. Polym. Sci. Part A: Polym. Chem. 2004, 42, 5847-5852.
  •  
  • 16. Kasmi, N.; Majdoub, M.; Papageorgiou, G. Z.; Bikiaris, D. N. Synthesis and Crystallization of New Fully Renewable Resources-based Copolyesters: Poly(1,4-cyclohexanedimethanol-co-isosorbide 2, 5-furandicarboxylate). Polym. Degrad. Stab. 2018, 152, 177-190.
  •  
  • 17. SK Chemicals. Heat Shrinkable Film Comprising Copolymer Polyester Resin. KR Patent 10-2014-0072810, 2014.
  •  
  • 18. WIZCHEM. A Preparative Method for 1,4-disubstituted Cyclohexane Derivatives. KR Patent 10-2009-0093521, 2009.
  •  
  • 19. Huinnovation. Cyclohexanedimethanol Pitch-based Plasticizer and Resin Composition Comprising the Same. KR Patent 10-2018-0068570, 2018.
  •  
  • 20. Kim, D. H.; Kim, Y. W.; No, K. H.; Han, Y. K.; Bae, J. Y. Synthesis of 1,4-Cyclohexanedimethanol Bis(aliphatic carboxylate) Plasticizers and Its Application to Poly(vinyl chloride) Fabrication. Polym. Korea 2021, 45, 179-184.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2023; 47(6): 737-743

    Published online Nov 25, 2023

  • 10.7317/pk.2023.47.6.737
  • Received on Jun 21, 2023
  • Revised on Sep 5, 2023
  • Accepted on Sep 30, 2023

Correspondence to

  • Jin-Young Bae
  • Department of Polymer Science and Engineering, Sungkyunkwan University, 300 Chunchun-dong, Jangan-gu, Suwon, Gyeonggi-do 16419, Korea

  • E-mail: b521@skku.edu