Article
  • N-type Photoanodes for Photoelectrochemical Water Splitting Using a Newly Synthesized Conjugated Polymer as an Additive

  • Mingi Sung, Taehong Kim, Hyo-Jin Ahn*,† , and Junghoon Lee†

  • Division of Chemical Engineering, Dongseo University, Busan 47011, Korea
    *LSTME Busan, Busan 46742, Korea

  • 전도성 고분자를 첨가제로 사용한 광전기화학 물 분해용 n-type 광양극

  • 성민기 · 김태홍 · 안효진*,† · 이정훈†

  • 동서대학교 화학공학부, *LSTME Busan

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

References
  • 1. Perera, F. Pollution from Fossil-Fuel Combustion is the Leading Environmental Threat to Global Pediatric Health and Equity: Solutions Exist. Int. J. Environ. Res. Public Heal. 2018, 15, 1-17.
  •  
  • 2. Bang, G.-W. Problems in Hydrogen Economy and the Need for the Development of New Energy Source. J. Korean Soc. Jungshin Sci. 2009, 13, 73-80.
  •  
  • 3. Martins, F.; Felgueiras, C.; Smitkova, M.; Caetano, N. Analysis of Fossil Fuel Energy Consumption and Environmental Impacts in European Countries. Energies 2019, 12, 694-705.
  •  
  • 4. Tarasco, J.-M.; Gratzel, M. Materials for Sustainable Energy; Dusastre, V., Ed.; Nature Publishing Croup: Singapole, 2011.
  •  
  • 5. Ahmed, M.; Dincer, I. A Review on Photoelectrochemical Hydrogen Production Systems: Challenges and Future Directions. Int. J. Hydrogen Energy 2019, 44, 2474-2507.
  •  
  • 6. Jang, Y. J.; Lee, J. S. Photoelectrochemical Water Splitting with P-Type Metal Oxide Semiconductor Photocathodes. ChemSusChem 2019, 12, 1835-1845.
  •  
  • 7. Al-Resayes, S. I.; Chen, B.; Fu, L.; Fu, L.; Gao, L.; Ji, L.; Li, C.; Liu, X.; Liu, Z.; Nehdi, I. A.; Soltani, S.; Strunk, J.; Uchino, K.; Ree, T.; Wang, P.; Wang, J.; Wang, F.; Wang, Y.; Zhu, Y. Metal Oxides in Energy Technologies: Y. Wu; Amsterdam, Netherlands; 2018.
  •  
  • 8. Yao, T.; An, X.; Han, H.; Chen, J. Q.; Li, C. Photoelectrocatalytic Materials for Solar Water Splitting. Adv. Energy Mater. 2018, 8, 1800210-1800246.
  •  
  • 9. Steier, L.; Holliday, S. A Bright Outlook on Organic Photo- electrochemical Cells for Water Splitting. J. Mater. Chem. A 2018, 6, 21809-20826.
  •  
  • 10. Barroso, M.; Pendlebury, S. R.; Cowan, A. J.; Durrant, J. R. Charge Carrier Trapping, Recombination and Transfer in Hematite (α-Fe2O3) Water Splitting Photoanodes. Chem. Sci. 2013, 4, 2724-2734.
  •  
  • 11. Ahn, H. J.; Yoon, K. Y.; Kwak, M. J.; Jang, J. H. A Titanium-Doped SiOx Passivation Layer for Greatly Enhanced Performance of a Hematite-Based Photoelectrochemical System. Angew. Chem. Int. Ed. 2016, 55, 9922-9926.
  •  
  • 12. Tsao, H. N.; Cho, D.; Andreasen, J. W.; Rouhanipour, A.; Breiby, D. W.; Pisula, W.; Müllen, K. The Influence of Morphology on High-Performance Polymer Field-Effect Transistors. Adv. Mater. 2009, 21, 209-212.
  •  
  • 13. Bai, Y.; Hippalgaonkar, K.; Sprick, R. S. Organic Materials as Photocatalysts for Water Splitting. J. Mater. Chem. A 2021, 9, 16222-16232.
  •  
  • 14. Dai, C.; Pan, Y.; Liu, B. Conjugated Polymer Nanomaterials for Solar Water Splitting. Adv. Energy Mater. 2020, 10, 2002474-2002481.
  •  
  • 15. Namsheer, K.; Rout, C. S. Conducting Polymers: A Comprehen- sive Review on Recent Advances in Synthesis, Properties and Applications. RSC Adv. 2021, 10, 5659-5697.
  •  
  • 16. Günes, S.; Neugebauer, H.; Sariciftci, N. S. Conjugated Polymer-Based Organic Solar Cells. Chem. Rev. 2007, 107, 1324-1338.
  •  
  • 17. Yang, J.; Zhao, Z.; Wang, S.; Guo, Y.; Liu, Y. Insight into High-Performance Conjugated Polymers for Organic Field-Effect Transistors. Chem. 2018, 12, 2748-2785.
  •  
  • 18. Anthony, J. E.; Facchetti, A.; Heeney, M.; Marder, S. R.; Zhan, X. N-Type Organic Semiconductors in Organic Electronics. Adv. Mater. 2010, 22, 3876-3892.
  •  
  • 19. Quinn, J. T. E.; Zhu, J.; Li, X.; Wang, J.; Li, Y. Recent Progress in the Development of n-Type Organic Semiconductors for Organic Field Effect Transistors. J. Mater. Chem. C 2017, 5, 8654-8681.
  •  
  • 20. Zhao, X.; Zhan, X. Electron Transporting Semiconducting Polymers in Organic Electronics. Chem. Soc. Rev. 2011, 40, 3728-3743.
  •  
  • 21. Griggs, S.; Marks, A.; Bristow, H.; McCulloch, I. N-Type Organic Semiconducting Polymers: Stability Limitations, Design Considerations and Applications. J. Mater. Chem. C 2021, 9, 8099-8128.
  •  
  • 22. Jia, H.; Lei, T. Emerging Research Directions for N-Type Conjugated Polymers. J. Mater. Chem. C 2019, 7, 12809-12821.
  •  
  • 23. Wang, S.; Sun, H.; Erdmann, T.; Wang, G.; Fazzi, D.; Lappan, U.; Puttisong, Y.; Chen, Z.; Berggren, M.; Crispin, X.; Kiriy, A.; Voit, B.; Marks, T. J.; Fabiano, S.; Facchetti, A. A Chemically Doped Naphthalenediimide-Bithiazole Polymer for n-Type Organic Thermoelectrics. Adv. Mater. 2018, 30, 1801898-1801903.
  •  
  • 24. Wang, Y.; Nakano, M.; Michinobu, T.; Kiyota, Y.; Mori, T.; Takimiya, K. Naphthodithiophenediimide-Benzobisthiadiazole-Based Polymers: Versatile n-Type Materials for Field-Effect Transistors and Thermoelectric Devices. Macromolecules 2017, 50, 857-864.
  •  
  • 25. Grenier, F.; Berrouard, P.; Pouliot, J.-R.; Tseng, H.-R.; Heeger, A. J.; Leclerc, M. Synthesis of New n-Type Isoindigo Copolymers. Polym. Chem. 2013, 4, 1836-1841.
  •  
  • 26. Wang, E.; Mammo, W.; Andersson, M. R. 25th Anniversary Article: Isoindigo-Based Polymers and Small Molecules for Bulk Heterojunction Solar Cells and Field Effect Transistors. Adv. Mater. 2014, 26, 1801-1826.
  •  
  • 27. Yan, X.; Xiong, M.; Li, J. T.; Zhang, S.; Ahmad, Z.; Lu, Y.; Wang, Z. Y.; Yao, Z. F.; Wang, J. Y.; Gu, X.; Lei, T. Pyrazine-Flanked Diketopyrrolopyrrole (DPP): A New Polymer Building Block for High-Performance n-Type Organic Thermoelectrics. J. Am. Chem. Soc. 2019, 141, 20215-20221.
  •  
  • 28. Yan, H.; Chen, Z.; Zheng, Y.; Newman, C.; Quinn, J. R.; Dötz, F.; Kastler, M.; Facchetti, A. A High-Mobility Electron-Transporting Polymer for Printed Transistors. Nature 2009, 457, 679-686.
  •  
  • 29. Zhu, Z.; Chueh, C. C.; Zhang, G.; Huang, F.; Yan, H.; Jen, A. K. Y. Improved Ambient-Stable Perovskite Solar Cells Enabled by a Hybrid Polymeric Electron-Transporting Layer. ChemSusChem 2016, 9, 2586-2591.
  •  
  • 30. Hou, W.; Xiao, Y.; Han, G.; Lin, J. Y. The Applications of Polymers in Solar Cells: A Review. Polymers 2019, 11, 143-188.
  •  
  • 31. Morin, P.-O.; Bura, T.; Leclerc, M. Realizing the Full Potential of Conjugated Polymers: Innovation in Polymer Synthesis. Mater. Horizons 2016, 3, 11-20.
  •  
  • 32. Zhang, M.; Tsao, H. N.; Pisula, W.; Yang, C.; Mishra, A. K.; Müllen, K. Field-Effect Transistors Based on a Benzothiadiazole-Cyclopentadithiophene. J. Am. Chem. Soc. 2007, 129, 3472-3473.
  •  
  • 33. Wu, W.; Liu, Y.; Zhu, D. π-Conjugated Molecules with Fused Rings for Organic Field-Effect Transistors: Design, Synthesis and Applications. Chem. Soc. Rev. 2010, 39, 1489-1502.
  •  
  • 34. Nketia-Yawson, B.; Lee, H.-S.; Seo, D.; Yoon, Y.; Park, W.-T.; Kwak, K.; Son, H. J.; Kim, B.; Noh, Y.-Y. A Highly Planar Fluorinated Benzothiadiazole-Based Conjugated Polymer for High-Performance Organic Thin-Film Transistors. Adv. Mater. 2015, 27, 3045-3052.
  •  
  • 35. Yum, S.; An, T. K.; Wang, X.; Lee, W.; Uddin, M. A.; Kim, Y. J.; Nguyen, T. L.; Xu, S.; Hwang, S.; Park, C. E.; Woo, H. Y. Benzotriazole-Containing Planar Conjugated Polymers with Noncovalent Conformational Locks for Thermally Stable and Efficient Polymer Field-Effect Transistors. Chem. Mater. 2014, 26, 2147-2154.
  •  
  • 36. Liu, X.; Sun, Y.; Hsu, B. B. Y.; Lorbach, A.; Qi, L.; Heeger, A. J.; Bazan, G. C. Design and Properties of Intermediate-Sized Narrow Band-Gap Conjugated Molecules Relevant to Solution-Processed Organic Solar Cells. J. Am. Chem. Soc. 2014, 136, 5697-5708.
  •  
  • 37. Zhang, Y.; Chien, S.-C.; Chen, K.-S.; Yip, H.-L.; Sun, Y.; Davies, J. A.; Chen, F.-C.; Jen, A. K.-Y. Increased Open Circuit Voltage in Fluorinated Benzothiadiazole-Based Alternating Conjugated Polymers. Chem. Commun. 2011, 47, 11026-11028.
  •  
  • 38. Ying, L.; Hsu, B. B. Y.; Zhan, H.; Welch, G. C.; Zalar, P.; Perez, L. A.; Kramer, E. J.; Nguyen, T. Q.; Heeger, A. J.; Wong, W. Y.; Bazan, G. C. Regioregular Pyridal[2,1,3]Thiadiazole π-Conjugated Copolymers. J. Am. Chem. Soc. 2011, 133, 18538-18541.
  •  
  • 39. Lee, W.; Lee, C.; Yu, H.; Kim, D. J.; Wang, C.; Woo, H. Y.; Oh, J. H.; Kim, B. J. Side Chain Optimization of Naphthalenediimide-Bithiophene-Based Polymers to Enhance the Electron Mobility and the Performance in All-Polymer Solar Cells. Adv. Funct. Mater. 2016, 26, 1543-1553.
  •  
  • 40. Sharma, S.; Kolhe, N. B.; Gupta, V.; Bharti, V.; Sharma, A.; Datt, R.; Chand, S.; Asha, S. K. Improved All-Polymer Solar Cell Performance of n-Type Naphthalene Diimide-Bithiophene P(NDI2OD-T2) Copolymer by Incorporation of Perylene Diimide as Coacceptor. Macromolecules 2016, 49, 8113-8125.
  •  
  • 41. Liu, Q.; Surendran, A.; Feron, K.; Manzhos, S.; Jiao, X.; McNeill, C. R.; Bottle, S. E.; Bell, J.; Leong, W. L.; Sonar, P. Diketopyrrolopyrrole Based Organic Semiconductors with Different Numbers of Thiophene Units: Symmetry Tuning Effect on Electronic Devices. New J. Chem. 2018, 42, 4017-4028.
  •  
  • 42. Vasimalla, S.; Senanayak, S. P.; Sharma, M.; Narayan, K. S.; Iyer, P. K. Improved Performance of Solution-Processed n-Type Organic Field-Effect Transistors by Regulating the Intermolecular Interactions and Crystalline Domains on Macroscopic Scale. Chem. Mater. 2014, 26, 4030-4037.
  •  
  • 43. Nketia-Yawson, B.; Lee, H. S.; Seo, D.; Yoon, Y.; Park, W. T.; Kwak, K.; Son, H. J.; Kim, B.; Noh, Y. Y. A Highly Planar Fluorinated Benzothiadiazole-Based Conjugated Polymer for High-Performance Organic Thin-Film Transistors. Adv. Mater. 2015, 27, 3045-3052.
  •  
  • 44. Lee, J.; Kang, S.-H.; Lee, S. M.; Lee, K. C.; Yang, H.; Cho, Y.; Han, D.; Li, Y.; Lee, B. H.; Yang, C. An Ultrahigh Mobility in Isomorphic Fluorobenzo[c][1,2,5]Thiadiazole-Based Polymers. Angew. Chem. Int. Ed. 2018, 57, 13629-13634.
  •  
  • 45. Wang, M.; Ford, M.; Phan, H.; Coughlin, J.; Nguyen, T.-Q.; Bazan, G. C. Fluorine Substitution Influence on Benzo[2,1,3]- Thiadiazole Based Polymers for Field-Effect Transistor Applications. Chem. Commun. 2016, 52, 3207-3210.
  •  
  • 46. Yum, S.; An, T. K.; Wang, X.; Lee, W.; Uddin, M. A.; Kim, Y. J.; Nguyen, T. L.; Xu, S.; Hwang, S.; Park, C. E.; Woo, H. Y. Benzotriazole-Containing Planar Conjugated Polymers with Noncovalent Conformational Locks for Thermally Stable and Efficient Polymer Field-Effect Transistors. Chem. Mater. 2014, 26, 2147-2154.
  •  
  • 47. Zhou, H.; Yang, L.; Stuart, A. C.; Price, S. C.; Liu, S.; You, W. Development of Fluorinated Benzothiadiazole as a Structural Unit for a Polymer Solar Cell of 7%  Efficiency. Angew. Chem. Int. Ed. 2011, 50, 2995-2998.
  •  
  • 48. K, N.; Rout, C. S. Conducting Polymers: A Comprehensive Review on Recent Advances in Synthesis, Properties and Applications. RSC Adv. 2021, 11, 5659-5697.
  •  
  • 49. McCullough, R. D. The Chemistry of Conducting Polythiophenes. Adv. Mater. 1998, 10, 93-116.
  •  
  • 50. Li, J.; Du, J.; Xu, J.; Chan, H. L. W.; Yan, F. The Influence of Gate Dielectrics on a High-Mobility n-Type Conjugated Polymer in Organic Thin-Film Transistors. Appl. Phys. Lett. 2012, 100, 33301-33304.
  •  
  • 51. Kosco, J.; Moruzzi, F.; Willner, B.; McCulloch, I. Photocatalysts Based on Organic Semiconductors with Tunable Energy Levels for Solar Fuel Applications. Adv. Energy Mater. 2020, 10, 2001935-20011950.
  •  
  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2022; 46(3): 409-417

    Published online May 25, 2022

  • 10.7317/pk.2022.46.3.409
  • Received on Feb 21, 2022
  • Revised on Mar 15, 2022
  • Accepted on Mar 15, 2022

Correspondence to

  • yo-Jin Ahn* , and Junghoon Lee

  • Division of Chemical Engineering, Dongseo University, Busan 47011, Korea

  • E-mail: hyo-jin.ahn@lstme.org, junghoonlee@gdsu.dongseo.ac.kr