Article
  • Cationic Ring-opening Polymerization of Cyclic Dithiocarbonates Enhanced by a Neighboring Sulfur Atom

  • Jeong HyoJo and Jung Yun Do†

  • Department of Chemistry Education, Pusan National University, 2, Busandaehak-ro, 63beon-gil, Geumjeong-gu, Busan 46241, Korea

  • 고리형 디티오카보네이트의 양이온 개환 중합과 인접한 황에 의한 개환 유도 효과

  • 정효조 · 도정윤†

  • 부산대학교 화학교육과

  • Reproduction, stored in a retrieval system, or transmitted in any form of any part of this publication is permitted only by written permission from the Polymer Society of Korea.

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  • 7. Nakano, K.; Tatsumi, G.; Nozaki, K. Synthesis of Sulfur-Rich Polymers: Copolymerization of Episulfide with Carbon Disulfide by Using [PPN]Cl/(salph)Cr(III)Cl System. J. Am. Chem. Soc. 2007, 129, 15116.
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  • 8. Berti, C.; Celli, A.; Marianucci, E. Sulfur Containing Polymers. Aromatic Polydithiocarbonates and Polythiocarbonates: Synthesis and Thermal Properties. Eur. Polym. J. 2002, 38, 1281.
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  • 9. Wu, S.; Luo, M.; Darensbourg, D. J.; Zuo, X. Catalyst-Free Construction of Versatile and Functional CS2-Based Polythioureas: Characteristics from Self-Healing to Heavy Metal Absorption. Macromolecules 2019, 52, 8596.
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  • 10. Tian, T.; Hu, R.; Tang, B. Z. Room Temperature One-Step Conversion from Elemental Sulfur to Functional Polythioureas through Catalyst-Free Multicomponent Polymerizations. J. Am. Chem. Soc. 2018, 140, 6156.
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  • 11. Ochiai, B.; Endo, T. Synthesis of Polymers from Carbon Dioxide and Carbon Disulfide. Prog. Polym. Sci. 2005, 30, 183.
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  • 12. Kim, C. G.; Son, M. J.; Do, J. Y. Cationic Living Polymerization of Cyclic Dithiocarbonates involving Sulfide-Migration. Eur. Polym. J. 2021, 156, 110611.
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  • 13. Diebler, J.; Spannenberg, A.; Werner, T. Atom Economical Synthesis of Di- and Trithiocarbonates by the Lithium tert-Butoxide Catalyzed Addition of Carbon Disulfide to Epoxides and Thiiranes. Org. Biomol. Chem. 2016, 14, 7480.
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  • 14. Dodd, J. H.; Henry, J. R.; Rupert, K. C.; Bullington, J. L.; Hall, D. A. Oxathiepino[6,5-b]dihydropyridines, and Related Compositions and Methods. US Patent 6,476,022 B1, 2002.
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  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2022; 46(3): 377-381

    Published online May 25, 2022

  • 10.7317/pk.2022.46.3.377
  • Received on Jan 26, 2022
  • Revised on Mar 10, 2022
  • Accepted on Mar 17, 2022

Correspondence to

  • Jung Yun Do

  • Department of Chemistry Education, Pusan National University, 2, Busandaehak-ro, 63beon-gil, Geumjeong-gu, Busan 46241, Korea

  • E-mail: jydo@pusan.ac.kr