Article
  • Properties and Application of Poly (acrylamidoxime) Chelate Resin
  • Kim WY, Maeng KS
  • Poly(acrylamidoxime) Chelate Resin의 성질과 응용
  • 김완영, 맹기석
Abstract
Complexation properties of a divinylbenzene crosslinked poly (acrylamidoxime) resin for Li, B, La(Ⅲ), Ce(Ⅳ) and Nd(Ⅲ) were investigated by inductively coupled plasma-atomic emission spectroscopy. The resin was found to be effective for the sequestering of La(Ⅲ), Ce(Ⅳ) and Nd(Ⅲ) from aqueous solutions. The resin exhibited no affinity for Li and B cations. Recovers of trace levels of metals sequestered on the resin was achieved by elution with either 1:1 nitric acid-water or 1:1 hydrochloric acid-water. The application of trace concentation levels of impurities in high purity aluminum was examined.

Divinylbenzene으로 Crosslink한 Poly(acrylamidoxime) 수지의 Li, B, La(Ⅲ), Ce(Ⅳ), Nd(Ⅲ)에 대한 complexation property를 ICP-AES를 사용하여 연구하였다. 이 수지는 La(Ⅲ), Ce(Ⅳ) 및 Nd(Ⅲ)과는 complex 화합물을 효과적으로 생성하나 Li과 B와는 complex화합물을 생성하지 않았다. 수지에 흡착한 미량의 금속은 1:1-HNO3-물의 혼합물에 의하여 추출 회수되었다. 이 수지의 응용으로서 거의 순수한 알미늄 시료중에 함유되어있는 불순물을 column 법에 의하여 정량하였다.

Keywords:

  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 1982; 6(2): 119-126

    Published online Apr 25, 1982

  • 10.7317/pk.
  • Received on Nov 30, -0001
  • Revised on Nov 30, -0001
  • Accepted on Nov 30, -0001

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