Article
  • Study on Properties for SSBR/ENR Blend Filled with Silica
  • Sun Ho Jang*, Xiang Xu Li*, Qingyuan Li*, Dam Hee Lee*, and Ur Ryong Cho*,**,†

  • *School of Energy, Materials and Chemical Engineering, Korea University of Technology and Education, Cheonan, Chungnam 31253, Korea
    **Research Center of Eco-friendly & High performance Chemical Materials, Cheonan, Chungnam 31253, Korea

  • 실리카로 보강된 SSBR/ENR 블렌드의 물성 연구
  • 장선호* · 리시앙수* · 리칭위안* · 이담희* · 조을룡*,**,†

  • *한국기술교육대학교 에너지, 신소재, 화학공학부, **친환경고성능화학소재연구소

Abstract

Solution styrene-butadiene rubber (SSBR) and epoxidized natural rubber (ENR) blends reinforced by silica had been compounded over the two-roll mill. The crosslinking characterization, morphology, tensile strength, elastic and viscos characterizations, and thermodynamic properties of blends had been investigated after processing. With the ratio of ENR increasing, the crosslinking rate and density of blends had increased. Also, the epoxy groups in blends had been also increased which will cause influence on silica dispersion and Payne effect of blends. They had been characterized by SEM and RPA. The S75/E25 blend and S50/E50 blend showed two peaks about glass transition temperature (Tg) in dynamic mechanical analysis (DMA), but the blend whose ratio was S25/E75 showed only one peak. It meant S25/E75 blend would be a good miscibility rubber material due to the larger wet grip, better tensile strength and higher elastic rate. And as for thermal stability of blends, with the ratio of ENR increased, the initial decomposition temperature of blends decreased gradually.


실리카로 보강한 솔루션-스티렌-부타디엔 고무(SSBR)와 에폭시화 천연고무(ENR)를 다양한 조성으로 블렌드를 제조하여 조성에 따른 가교특성, 모폴로지, 인장특성, 동적점탄성 그리고 열적 특성을 조사하였다. ENR의 함량이 증가할수록 가교속도가 빨라지는 모습을 보였으며 블렌드 조성물의 경우 가교도가 증가하는 모습을 보였다. ENR의 함량이 증가함에 따라 에폭시기의 영향으로 실리카 분산성의 향상을 전자현미경(SEM)과 Payne effect를 통해 확인하였다. S75/E25, S50/E50에서는 두 개의 유리전이온도(Tg)가 나타났으며 S25/E75에서는 하나의 유리전이 온도(Tg)가 나타났고 젖은 노면의 제동 특성과 인장강도, 탄성률이 높아서 S25/E75 조성물에서 가장 상용성이 높은 것으로 판단되었다. 열적 안정성은 ENR의 함량이 증가함에 따라 초기 분해 온도가 감소함을 알 수 있었다.


Keywords: solution styrene-butadiene rubber, epoxidized natural rubber, blend, silica, properties

  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2022 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 2018; 42(1): 106-111

    Published online Jan 25, 2018

  • 10.7317/pk.2018.42.1.106
  • Received on Jul 27, 2017
  • Revised on Aug 9, 2017
  • Accepted on Sep 8, 2017

Correspondence to

  • Ur Ryong Cho
  • *School of Energy, Materials and Chemical Engineering, Korea University of Technology and Education, Cheonan, Chungnam 31253, Korea
    **Research Center of Eco-friendly & High performance Chemical Materials, Cheonan, Chungnam 31253, Korea

  • E-mail: urcho@koreatech.ac.kr