Article
  • Polymerization Behavior and Thermal Properties of PPS and Poly( arylene sulfide)s
  • Lee SC, Park LS
  • PPS와 Poly(arylene sulfide)s의 중합반응 특성 및 열적성질
  • 이수창, 박이순
Abstract
Poly(p-phenylene sulfide), PPS and related polymers such as poly(p-phenylene sulfide sulfone), PPSS and poly(p-phenylene sulfide ketone), PPSK were prepared from sodium sulfide (SS) and three different comonomers p-dichlorobenzene (DCB), 4-chlorophenylsulfone(CPS) and 4,4'-dichlorobenzophenone(DCBP), respectively, employing N-methyl pyrrolidinone (NMP) as solvent under high temperature (250∼290 ℃) and pressure (120∼180 psi). The molecular weight of polymers were determined by high temperature (210℃) GPC with 1-chloronaphthalene as eluent against polystyrene standards. The thermal transition temperatures and thermal stability of polymers, were studied by DSC and TGA. PPS showed maximum yield at 250℃ of reaction temperature, whereas PPSS and PPSK which have electron-withdrawing groups gave maximum yield at 200℃. As for the stoichiometry of comonomers, PPS exhibited highest yield of 83% in the range of [SS]/[DCB]=0.75/1∼1.25/1. The yield of PPSK and especially PPSS were highly sensitive to stoichiometric ratio of [SS]/[DCBP] and [SS]/[CPS] decreased sharply. As for the content of water as additive in the reaction mixture, PPS and PPSK showed maximum yield at [H2O]/[Na2S]=9/1. PPSS could not be obtained under [H2O]/[Na2S]=4.5/1, but the maximum yield was shown at [H2O]/[Na2S]=13.5/1. From the DSC study, PPS and PPSK were crystalline materials with Tm=279 and Tm=344℃, respectively. PPSS was amorphous material with only Tg being detected at 210℃.

Sodium sulfide nonahydrate(SS)를 p-dichlorobenzene (DCB)과 중합시켜 poly(p-phenylene sulfide), PPS를 그리고 4-chlorophenylsulfone (CPS) 또는 4,4'-dichlorobenzophenone (DCBP)와 중합시켜 poly(p-phenylene sulfide sulfone), PPSS 및 poly(p-phenylene sulfide ketone), PPSK를 각각 합성하고 중합온도, 단량체 몰비, 중합계내 물의 함량 등이 중합체들의 수율 및 분자량에 미치는 영향을 비교 조사하였다. 이들 중합체의 분자량은 1-chloronaphthalene을 이동상으로 고온(210℃) GPC를 사용하여 측정하였고, 열적 성질은 DSC 및 TGA로 조사하였다. 먼저 중합온도에 있어서는 PPS가 250℃에서 최고 수율을 보인 반면, PPSS 및 PPSK는 200℃에서 최대 수율을 나타내었다. 단량체 몰비에 있어서는 [SS]/[DCB]의 몰비가 0.75/1∼1.25/1로 변하여도 83% 이상의 높은 수율을 나타낸 PPS의 경우와는 달리, PPSK(특히 PPSS)는 매우 민감하게 수율이 변하였다. 또 첨가제로서 물 함량이 변함에 따라 PPS 및 PPSK는 크게 수율이 변하지 않았지만 PPSS는 [H2O]/[SS]=4.5/1 이하에서는 중합체가 얻어지지 않았으며 13.5/1에서 최고 분자량을 보였다. DSC 열분석으로부터 PPSK(Tm=344℃)는 PPS(Tm=279℃)와 마찬가지로 결정성 고분자이었고 PPSS(Tg=201℃)는 무정형 고분자였다.

Keywords: poly(p-phenylene sulfide); poly(arylene sulfide)s; reaction conditions; thermal properties

  • Polymer(Korea) 폴리머
  • Frequency : Bimonthly(odd)
    ISSN 0379-153X(Print)
    ISSN 2234-8077(Online)
    Abbr. Polym. Korea
  • 2023 Impact Factor : 0.4
  • Indexed in SCIE

This Article

  • 1995; 19(6): 867-874

    Published online Nov 25, 1995

  • 10.7317/pk.
  • Received on Nov 30, -0001
  • Revised on Nov 30, -0001
  • Accepted on Nov 30, -0001

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