Ethyl vinyl ether(EVE) and n-butyl vinyl ether(nBVE) were polymerized by HI/I₂ catalyst under living polymerization conditions, and the tacticities of the obtained polymers were determined by carbon-13 NMR spectroscopy. The tacticity result was analyzed and compared with reported data which were obtained from nonliving polymerization systems catalyzed by BF₃OEt₂ or SbCl₅. Sequence distribution of a polymer obtained with HI/I₂ catalyst did not follow Bernoullian statistics, whereas that of the polymer obtained from BF₃OEt₂ catalyst system followed the random statistics. As the polymerization temperature decreased, the isotacticity of the polymer obtained increased, and the deviation from random statistics became larger.

리빙 중합조건하에서 HI/I₂ 촉매에 의하여 합성된 poly(ethyl vinyl ether)와 poly(n-butyl vinyl ether)의 tactility를 탄소 핵자기 공명을 이용하여 분석하였으며, 그 분석결과를 BF₃OEt₂나 SbCl₅가 사용된 리빙 중합이 아닌 중합계에서 얻어진 고분자의 분석결과와 비교하였다. HI/I₂ 촉매에 의하여 얻어진 polymer의 sequence distribution은 Bernoullian 통계를 따르지 않았고 반면에 BF₃OE_t2를 사용하여 얻어진 것은 random statistics를 따르고 있었다. 중합온도가 감소할 때. 얻어진 고분자의 isotacticity는 증가하였고 random statistics로부터의 deviation은 증가하였다.

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